Recycling of Proterozoic crust in the Andean Amazon foreland of Ecuador: implications for orogenic development of the Northern Andes

The retro‐arc foreland Andean Amazon Basin records sedimentary infill from the South American craton and the emerging Northern Andean chain from the middle Cretaceous until Present day. The U/Pb ages of detrital zircons indicate significant reworking of Archean‐Proterozoic (max. 2.9 Ga) and Paleozoic crust and sediments, which were eroded on both sides. Heavy mineral associations show that the material derived from Proterozoic craton was supplied by Cretaceous reworking of non‐metamorphosed (unannealed) Paleozoic and older sedimentary rocks, which cover the Amazon Craton. Following latest Cretaceous switch of the dominant sediment source to the Andean cordillera, the influx of Precambrian zircons persisted, and these zircons were derived from the metamorphosed basement and Paleozoic sediments of the Cordillera Real (Loja terrane). Re‐evaluation of existing detrital zircon fission‐track record proves that the rise of the Cordillera Real at the Cretaceous‐Tertiary transition was initiated by the collision of Caribbean Oceanic Plateau and associated arc elements from 75–65 Ma. A further important exhumation event also occurred in the Late Oligocene, which is correlated with the break‐up of the Farallon plate.     

PEPSI: The high‐resolution échelle spectrograph and polarimeter for the Large Binocular Telescope

PEPSI is the bench‐mounted, two‐arm, fibre‐fed and stabilized Potsdam Echelle Polarimetric and Spectroscopic Instrument for the 2×8.4 m Large Binocular Telescope (LBT). Three spectral resolutions of either 43 000, 120 000 or 270 000 can cover the entire optical/red wavelength range from 383 to 907 nm in three exposures. Two 10.3k×10.3k CCDs with 9‐µm pixels and peak quantum efficiencies of 94–96 % record a total of 92 échelle orders. We introduce a new variant of a wave‐guide image slicer with 3, 5, and 7 slices and peak efficiencies between 92–96 %. A total of six cross dispersers cover the six wavelength settings of the spectrograph, two of them always simultaneously. These are made of a VPH‐grating sandwiched by two prisms. The peak efficiency of the system, including the telescope, is 15 % at 650 nm, and still 11 % and 10 % at 390 nm and 900 nm, respectively. In combination with the 110 m² light‐collecting capability of the LBT, we expect a limiting magnitude of ≈20th mag in V in the low‐resolution mode. The R = 120 000 mode can also be used with two, dual‐beam Stokes IQUV polarimeters. The 270 000‐mode is made possible with the 7‐slice image slicer and a 100‐µm fibre through a projected sky aperture of 0.74″, comparable to the median seeing of the LBT site. The 43 000‐mode with 12‐pixel sampling per resolution element is our bad seeing or faint‐object mode. Any of the three resolution modes can either be used with sky fibers for simultaneous sky exposures or with light from a stabilized Fabry‐Pérot étalon for ultra‐precise radial velocities. CCD‐image processing is performed with the dedicated data‐reduction and analysis package PEPSI‐S4S. Its full error propagation through all image‐processing steps allows an adaptive selection of parameters by using statistical inferences and robust estimators. A solar feed makes use of PEPSI during day time and a 500‐m feed from the 1.8 m VATT can be used when the LBT is busy otherwise. In this paper, we present the basic instrument design, its realization, and its characteristics. Some pre‐commissioning first‐light spectra shall demonstrate the basic functionality. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Palomar and Table Mountain observations of 9P/Tempel 1 during the Deep Impact encounter: First results

We present the first results of the Palomar Adaptive Optics observations taken during the Deep Impact encounter with 9P/Tempel 1 in July 2005. We have combined the Palomar near-IR imaging data with our visual wavelength images obtained simultaneously at JPL's Table Mountain Observatory to cover the total wavelength range from 0.4 to 2.3 μm in the B, V, R, I, J, H, and K filter bands, spanning the dates from 2005 July 03-07. We also include in our overall analysis images taken on the pre-encounter dates of June 1 and June 15, 2005. The broad wavelength range of our observations, along with high temporal resolution, near-IR sensitivity, and spatial resolution of our imaging, have enabled us to place constraints on the temperature of the impact flash and incandescent plume of >700 K, and to provide mean dust velocities of order approximately 1.25 h after impact derived from our 1.64 μm observations. Our ejected dust mass estimates, as derived from our near-IR observations, are an order of magnitude less than those previously reported for visual wavelength observations.     

The 8.2 ka event: Evidence for seasonal differences and the rate of climate change in western Europe

Recent studies have drawn attention to differences in the seasonal impact of the 8.2 ka event, with longer cooler summers and shorter cooler/drier winters. However, there are no data available on the simultaneity or the rate of onset of the seasonal changes in Europe. Based on the microfacies and geochemical analyses of seasonally laminated varved sediments from Holzmaar, we present evidence of differences in duration and onset time of changes in summer temperature and winter rainfall during the 8.2 ka event. Since both summer and winter climate signals are co-registered within a single varve, there can be no ambiguity about the phasing and duration of the signals. Our data show that the onset and withdrawal of the 8.2 ka summer cooling occurred within a year, and that summer rains were reduced or absent during the investigated period. The onset of cooler summers preceded the onset of winter dryness by ca. 28 years. In view of the differences in nature and duration of the impact of the 8.2 ka event we suggest that a clearer definition of the 8.2 ka event (summer cooling or winter cooling/dryness) needs to be developed. Based on regional comparison and available modelling studies we also discuss the roles of solar variability, changes in North Atlantic Thermohaline circulation, and North Atlantic Circulation (NAO) during the period under consideration. Wavelet analyses of seasonal laminae indicates that the longer NAO cycles, linked to changes in the N. Atlantic temperatures, were more frequent during the drier periods.     

Precipitation: Measurement,remote sensing,climatology and modeling

This review paper deals with four aspects of precipitation: measurement, remote sensing, climatology and modeling. The measurement of precipitation is summarized in terms of the instruments that count and measure drop sizes (defined as disdrometers) and the instruments that measure an average quantity proportional to the integrated volume of an ensemble of raindrops (these instruments are normally called rain gauges). Remote sensing of precipitation is accomplished with ground based radar and from satellite retrievals and these two approaches are separately discussed. The climatology of precipitation has evolved through the years from the traditional rain gauge data analyses to the more sophisticated data bases that result from a coalescence of data and information on precipitation that is available from several sources into amalgamated products. Recently, rain observations from both ground and space have been assimilated into regional and global numerical weather prediction models aiming at improved moisture analysis and better forecasts of extreme weather events. The current status and the main outstanding issues related to precipitation forecasting are discussed, providing a basic structure for research coordination aimed at the improvement of modeling, observation and data assimilation applicable to global and regional scales.     

Li-bearing, disordered Mg-rich tourmaline from a pegmatite-marble contact in the Austroalpine basement units (Styria, Austria)

Pale-blue to pale-green tourmalines from the contact zone of Permian pegmatites to mica schists and marbles from different localities of the Austroalpine basement units (Rappold Complex) in Styria, Austria, are characterized. All these Mg-rich tourmalines have small but significant Li contents, up to 0.29 wt% Li₂O, and can be characterized as dravite, with FeO contents of ?~?0.9–2.7 wt%. Their chemical composition varies from ^X (Na_0.67Ca_0.19?K_0.02?_0.12) ^Y (Mg_1.26Al_0.97Fe²⁺ _0.36Li_0.19Ti⁴⁺ _0.06Zn_0.01?_0.15) ^Z (Al_5.31?Mg_0.69) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.66(OH)_0.34], with a?=?15.9220(3), c?=?7.1732(2) Å to ^X (Na_0.67Ca_0.24?K_0.02?_0.07) ^Y (Mg_1.83Al_0.88Fe²⁺ _0.20Li_0.08Zn_0.01Ti⁴⁺ _0.01?_0.09) ^Z (Al_5.25?Mg_0.75) (BO₃)₃ Si₆O₁₈ ^V (OH)₃? ^W [F_0.87(OH)_0.13], with a?=?15.9354(4), c?=?7.1934(4) Å, and they show a significant Al-Mg disorder between the Y and the Z sites (R1?=?0.013–0.015). There is a positive correlation between the Ca content and?<?Y-O?>?distance for all investigated tourmalines (r?≈?1.00), which may reflect short-range order configurations including Ca and Fe²⁺, Mg, and Li. The tourmalines have X_Mg (X_Mg?=?Mg/Mg?+?Fe_total) values in the range 0.84–0.95. The REE patterns show more or less pronounced negative Eu and positive Yb anomalies. In comparison to tourmalines from highly-evolved pegmatites, the tourmaline samples from the border zone of the pegmatites of the Rappold Complex contain relatively low amounts of total REE (~8–36 ppm) and Th (0.1–1.8 ppm) and have low La_N/Yb_N ratios. There is a positive correlation (r?≈?0.91) between MgO of the tourmalines and the MgO contents of the surrounding mica schists. We conclude that the pegmatites formed by anatectic melting of mica schists and paragneisses in Permian time. The tourmalines crystallized from the pegmatitic melt, influenced by the metacarbonate and metapelitic host rocks.     

Geological evolution of the Antongil Craton,NE Madagascar

The Antongil Craton, along with the Masora and Antananarivo cratons, make up the fundamental Archaean building blocks of the island of Madagascar. They were juxtaposed during the late-Neoproterozoic to early Palaeozoic assembly of Gondwana. In this paper we give a synthesis of the geology of the Antongil Craton and present previously published and new geochemical and U–Pb zircon analyses to provide an event history for its evolution.     

Benefits of dealing with uncertainty in greenhouse gas inventories: introduction

The assessment of greenhouse gases emitted to and removed from the atmosphere is high on the international political and scientific agendas. Growing international concern and cooperation regarding the climate change problem have increased the need for policy-oriented solutions to the issue of uncertainty in, and related to, inventories of greenhouse gas (GHG) emissions. The approaches to addressing uncertainty discussed in this Special Issue reflect attempts to improve national inventories, not only for their own sake but also from a wider, systems analytical perspective—a perspective that seeks to strengthen the usefulness of national inventories under a compliance and/or global monitoring and reporting framework. These approaches demonstrate the benefits of including inventory uncertainty in policy analyses. The authors of the contributed papers show that considering uncertainty helps avoid situations that can, for example, create a false sense of certainty or lead to invalid views of subsystems. This may eventually prevent related errors from showing up in analyses. However, considering uncertainty does not come for free. Proper treatment of uncertainty is costly and demanding because it forces us to make the step from “simple to complex” and only then to discuss potential simplifications. Finally, comprehensive treatment of uncertainty does not offer policymakers quick and easy solutions. The authors of the papers in this Special Issue do, however, agree that uncertainty analysis must be a key component of national GHG inventory analysis. Uncertainty analysis helps to provide a greater understanding and better science helps us to reduce and deal with uncertainty. By recognizing the importance of identifying and quantifying uncertainties, great strides can be made in ongoing discussions regarding GHG inventories and accounting for climate change. The 17 papers in this Special Issue deal with many aspects of analyzing and dealing with uncertainty in emissions estimates.     

Dependence of geostrophic drag on intensity of convection,baroclinicity, and acceleration

This paper examines the practical importance of stability, baroclinicity, and acceleration in the bulk ABL similarity formulations, in light of the random errors inherent in field measurements. This is done by propagating the measurement uncertainties through a theoretical model for the bulk ABL similarity functionsA ₀ andB ₀, under a range of assumed (but always unstable) conditions. It is shown that random measurement errors and acceleration effects may overwhelm most effects of baroclinicity and stability, once conditions are at least slightly unstable. Because of this, it is hard to discern a clear functional dependence ofA ₀ andB ₀ on degree of instability. Thus, for a given value ofh _i/z₀, whereh _i is the inversion height andz ₀ is the surface roughness, the geostrophic drag coefficient, which depends onA ₀ andB ₀, and weakly onh _i/z₀, may also be taken to be nearly independent of degree of instability.     

Distribution and activity of petroleum hydrocarbon degrading bacteria in the North Sea and Baltic Sea

Summary Data were collected in 1988 and 1989 on the distribution and activity of petroleum hydrocarbon degrading bacteria in the North Sea and Baltic Sea. Crude oil degrading bacteria and the number of bacteria which in particular degrade naphthalene were quantified using a modified dilution method (MPN). Crude oil degrading bacteria were present in all of about 100 water samples, with as many as 10³ ml^–1 in some samples. Numbers of naphthalene degrading bacteria were at least tenfold lower. There is obviously a greater connection between this bacteria group and petroleum hydrocarbon (PHC) contamination than between the more nonspecific group of crude oil degrading bacteria and PHC contamination. Data from the North Sea show an extremely high abundance of hydrocarbon degrading bacteria, even in winter, while in the southern Baltic Sea low numbers of bacteria were found and slower crude oil degradation was observed.

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Verteilung und Aktivität von erdölkohlenwasserstoffabbauenden Bakterien in Nord- und Ostsee

Zusammenfassung 1988 und 1989 wurden Daten über Verteilung und Aktivität von erdölkohlenwasserstoffabbauenden Bakterien in Nord- und Ostsee gesammelt. Rohölabbauende Bakterien und die Zahl von Bakterien, die insbesondere Naphthalen abbauen, wurden mit einer modifizierten Lösungsmethode (MPN) bestimmt. Rohölabbauende Bakterien wurden in allen ca. 100 Wasserproben nachgewiesen; in einigen Proben mit nicht weniger als 10³/ml. Die Zahl der naphthalenabbauenden Bakterien war mindestens um den Faktor 10 kleiner. Ein stärkerer Zusammenhang zwischen dieser Bakteriengruppe und der Belastung des Meerwassers durch Erdöl-Kohlenwasserstoffe als zwischen der eher unspezifischen Gruppe der rohölabbauenden Bakterien und dieser Belastung ist wahrscheinlich. Daten aus der Nordsee zeigen, selbst im Winter, eine sehr hohe Zahl von kohlenwasserstoffabbauenden Bakterien, während in der südlichen Ostsee eine niedrigere Anzahl von Bakterien bestimmt und ein langsamerer Rohölabbau beobachtet wurde.