Numerical analysis of the hydrogeologic controls in a layered coastal aquifer system, Oahu, Hawaii, USA

 The coastal aquifer system of southern Oahu, Hawaii, USA, consists of highly permeable volcanic aquifers overlain by weathered volcanic rocks and interbedded marine and terrestrial sediments of both high and low permeability. The weathered volcanic rocks and sediments are collectively known as caprock, because they impede the free discharge of groundwater from the underlying volcanic aquifers. A cross-sectional groundwater flow and transport model was used to evaluate the hydrogeologic controls on the regional flow system in southwestern Oahu. Controls considered were: (a) overall caprock hydraulic conductivity; and (b) stratigraphic variations of hydraulic conductivity in the caprock. Within the caprock, variations in hydraulic conductivity, caused by stratigraphy or discontinuities of the stratigraphic units, are a major control on the direction of groundwater flow and the distribution of water levels and salinity. Results of cross-sectional modeling confirm the general groundwater flow pattern that would be expected in a layered coastal system. Groundwater flow is: (a) predominantly upward in the low-permeability sedimentary units; and (b) predominantly horizontal in the high-permeability sedimentary units. Received, October 1996 Revised, August 1997 Accepted, September 1997     

Influence of averaging interval on shear velocity estimates for aeolian transport modeling

Recent investigations of aeolian transport have focused on increasingly short time scales because of growing recognition that wind unsteadiness is a major factor in the dynamics of sediment transport. However, the statistical reliability of shear velocity (u_*) estimates becomes increasingly uncertain as averaging interval is decreased. This study provides an empirical assessment of the influence of averaging interval on the reliability of u_* estimates. The data consist of 15-min wind-speed profiles (1 Hz sampling) collected at four coastal sites. Each profile was subdivided into progressively shorter fixed-length time intervals, and estimates of u_* and the 95% confidence interval for u_* were determined for each time-block using standard statistical techniques.The logarithmic model accurately represents the measured wind-speed profiles, even with relatively brief averaging intervals. Mean r² values remain robust down to block lengths as short as 10–20 s, typically retaining better than 98% of the r² value found for the full-length data sets. Fewer than 2% of the individual 10-s blocks had r² values less than 0.9. However, mean confidence intervals typically expanded by 70–80% of the full-record value as block length decreased from 900 to 10 s. For highly log-linear profiles, this amounted to an absolute increase from about ±8% to only ±14% of u_*, so that the additional information gained through the use of shorter averaging intervals may outweigh the increase in statistical uncertainty. Nevertheless, given that rates of aeolian transport are generally modeled as a function of u_*³, this increase in uncertainty may be significant for transport modeling. Thus, very short averaging intervals should be used with caution when predicting aeolian sediment flux. It is proposed that transport modeling should incorporate the shear velocity confidence interval as an indicator of the potential error associated with this source of uncertainty.     

Defensive reactions of freshwater ecosystems against external influences

Eutrophication and toxic loading of freshwater occurred even in early geological epochs as a result of natural factors (e.g., large animals, volcanism), and nutrients and xenobiotics are more quickly integrated in material cycling in aquatic than in terrestrial systems. Therefore, aquatic ecosystems show many defensive mechanisms against organic and toxic loading. Many other defensive reactions can be described in addition to the well-known example of microbial self-purification.Freshwater ecosystems possess compartments which cooperate towards the function and protection of the whole system but, in opposition to these “euoecisms”, there are also “dysoecisms”. The defensive reactions of an ecosystem are founded largely on species-egoistic adaptations that have an (accidental) system-altruistic effect. The whole ecosystem reacts only seldom, and it is not clear whether there are selection processes which favour water bodies with a slow eutrophication and therefore slow silting-up, because the freshwaters are important for the global water balance.It is possible to compare organismic with ecosystemic defensive reactions but the origin of both reactions is very different.     

Using remote sensing to regionalize local precipitation recharge rates obtained from the Chloride Method

Water supply in semiarid Botswana is, to a large extent, based on groundwater. In the planning of a groundwater abstraction scheme, criteria for the sustainability of the abstraction with respect to both quantity and quality have to be satisfied. The most important parameter in the context of quantitative sustainability is the long-term average groundwater recharge together with its spatial distribution. A method is developed to calculate a recharge map that can be used in a groundwater model. The relative distribution of recharge is obtained from remotely sensed data and then calibrated with local values of recharge derived from the Chloride Method. The method was tested for two sites in Botswana, the Chobe Region and Ngamiland.     

Method for determining stable isotope ratios of dissolved organic carbon in interstitial and other natural marine waters

A procedure is described for the analysis of the stable carbon isotopic composition of dissolved organic carbon (DOC) in natural waters from marine and higher-salinity environments. Rapid (less than 5 min) and complete oxidation of DOC is achieved using a modification of previous photochemical oxidation techniques. The CO₂ evolved from DOC oxidation can be collected in less than 10 min for isotopic analysis. The procedure is at present suitable for oxidation and collection of 1–5 μmol of carbon and has an associated blank of 0.1–0.2 μmol of carbon.Complete photochemical oxidation of DOC standards was demonstrated by quantitative recovery of CO₂ as measured manometrically. Isotopic analyses of standards by photochemical and high-temperature sealed-tube combustion methods agreed to within 0.3.. Photochemical oxidation of DOC in a representative sediment pore-water sample was also quantitative, as shown by the excellent agreement between the photochemical and sealed-tube methods. The δ¹³C values obtained for pore-water DOC using the two methods of oxidation were identical, suggesting that the modified photochemical method is adequate for the isotopically non-fractionated oxidation of pore-water DOC.The procedure was evaluated through an analysis of DOC in pond and pore waters from a hypersaline microbial mat environment. Concentrations of DOC in the water column over the mat displayed a diel pattern, but the isotopic composition of this DOC remained relatively constant (average δ¹³C = −12.4.). Pore-water DOC exhibited a distinct concentration maximum in the mat surface layer, and δ¹³C of pore-water DOC was nearly 8. lighter at 1.5–2.0-cm depth than in the mat surface layer (0–0.5-cm depth). These results demonstrate the effectiveness of the method in elucidating differences in DOC concentration and δ¹³C over biogeochemically relevant spatial and temporal scales. Carbon isotopic analysis of DOC in natural waters, especially pore waters, should be a useful probe of biogeochemical processes in recent environments.     

Hydrochemistry and environmental isotopes of spring water and their relation to structure and lithology identified with remote sensing methods in Wadi Araba,Egypt

Springs located at the historical sites of Wadi Araba (Eastern Desert of Egypt) and emerging from the escarpments of the Northern and Southern Galala Plateaus were investigated. A combination of methods, including hydrochemistry, stable and radioisotope composition, and structural analyses based on satellite data, provided information about the structure of the subsurface and the derived groundwater flow paths. Satellite images reveal karst features within the northern plateau, e.g. conical landforms. Karstic caves were documented along both escarpments. Chemical analysis of floodwater from Wadi Araba indicates higher concentrations of terrestrial salts compared to floodwaters from central and southern parts of the desert. δ¹⁸O and δ²H signatures in spring waters resemble those of floodwater and fall on the global meteoric water line, confirming their fast infiltration with minor influence of evaporation. The aquifer feeding the springs of the Northern Galala Plateau has low retention and the springs dry out quickly, even after heavy rainfall. Contrastingly, ³H activities in springs emerging from the Southern Galala Plateau refer to much slower subsurface passage. With respect to ³H content (3.8 TU) in recent flood waters, the spring water at Southern Galala Plateau contains about 40% recently recharged groundwater. However, its largest spring—the St. Antony spring—discharges water with a radiocarbon age of about 15,000 years. In combination with this spring’s constant and high discharge over a period of several months, that age estimate suggests a large reservoir with moderate to high retention.

     

Copper Adsorption by Chernozem Soils and Parent Rocks in Southern Russia

Laboratory data in Cu²⁺ adsorption by chernozems and parent rocks in Rostov region show that adsorption isotherms can be approximated by the Langmuir equation, whose parameters (K_l and C_∞) were calculated for all of the samples. The values of C_∞ show a strong negative correlation with the values of cationexchange capacity (CEC) (r =–0.88 at Р = 0.95), and K_l is correlated with the content of physical clay (particles <0.01 mm) (r = 0.78) and with clay (particles <0.001 mm) content in ordinary chernozem and southern chernozems of various particle size distribution (r = 0.80). Even stronger correlations were detected between these parameters in southern chernozems (r = 0.89 for the physical clay (PC) and r = 0.91 for the silt). However, none of the samples displays a significant correlation of C_∞ and K_l with the contents of physical clay and silt. This led us to conclude that the composition of the samples, for example, their organic matter, can affect Cu²⁺ adsorption by the soils and parent rocks. Acidification mechanisms of the equilibrium solutions during the Cu²⁺ adsorption by soils are discussed, as also are the reasons for the absence of balance between Cu²⁺ adsorbed by soils and exchangeable cations transferred into solution. Analysis of the fine structures of the XANES and EXAFS spectra suggests that Cu²⁺ can form coordinated chelate complex compounds with humic acids (HA) of soils and can substitute Al³⁺ at octahedral sites when interacting with clay minerals in soils.     

Structural framework of the Bashkirian anticlinorium, SW Urals

The Bashkirian anticlinorium of the southwestern Urals shows a much more complex structural architecture and tectonic evolution than previously known. Pre-Uralian Proterozoic extensional and compressional structures controlled significantly the Uralian tectonic convergence. A long-lasting Proterozoic rift process created extensional basement structures and a Riphean basin topography which influenced the formation of the western fold-and-thrust-belt with inversion structures during the Uralian deformation. A complete orogenic cycle during Cadomian times, including terrane accretion at the eastern margin of the East European platform, resulted in a high-level Cadomian basement complex, which controlled the onset of Uralian deformation, and resulted in intense imbrication and tectonic stacking in the subjacent footwall of the Main Uralian fault. The Uralian orogenic evolution can be subdivided into three deformation stages with differently oriented stress regimes. Tectonic convergence started in the Late Devonian with ophiolite obduction, tectonic accretion of basin and slope units and early flysch deposits (Zilair flysch). The accretionary complex prograded from the SE to the NW. Continuous NW/SE-directed convergence resulted finally in the formation of an early orogenic wedge thrusting the Cadomian basement complex onto the East European platform. The main tectonic shortening was connected with these two stages and, although not well constrained, appears to be of Late Devonian to Carboniferous age. In the Permian a final stage of E–W compression is observed throughout the SW Urals. In the west the fold-and-thrust-belt prograded to the west with reactivation of former extensional structures and minor shortening. In the east this phase was related to intense back thrusting. The East European platform was subducted beneath the Magnitogorsk magmatic arc during the Late Paleozoic collision. The thick and cold East European platform reacted as a stable rigid block which resulted in a narrow zone of intense crustal shortening, tectonic stacking and high strain at its eastern margin. Whereas the first orogenic wedge is of thick-skinned type with the involvement of crystalline basement, even the later west-directed wedge is not typically thin-skinned as the depth of the basal detachment appears below 15 km and the involvement of Archean basement can be assumed.     

Three Spaces of Spatial Cognition

As we move about and interact in the world, we keep track of different spaces, among them the space of navigation, the space immediately around the body, and the space of the body. We review research showing that these spaces are conceptualized differently. Knowledge of the space of navigation is systematically distorted. For example, people mentally rotate roads and land masses to greater correspondence with global reference frames, they mentally align roads and land masses, they overestimate distances near the viewpoint relative to those far from it. These and other distortions indicate that the space of navigation is schematized to elements and spatial relations relative to reference frames and perspective. The space around the body is organized into a mental framework consisting of extensions of the major axes of the body. Times to report objects around the body suggest that the relative accessibility of the axes depends on their perceptual and functional properties and the relation of the body to the world. Finally, times to verify named or depicted body parts indicate that body schemas depend on perceptual and functional significance. Thus, these spaces (and they are not the only ones important to human interaction) differ from one another and are not conceptualized as Euclidean. Rather they are schematized into elements and spatial relations that reflect perceptual and conceptual significance.