Trace-element characteristics of different pyrite types in Mesoarchaean to Palaeoproterozoic placer deposits

A comparative in situ LA-ICP MS trace-element study on pyrite from three different, variably auriferous, Archaean to Palaeoproterozoic palaeoplacer deposits in the Ouro Fino Syncline (Quadrilátero Ferrífero; Brazil), the Elliot Lake area north of Lake Huron (SE Canada) and several deposits within the Witwatersrand Basin (South Africa) revealed systematic differences between morphologically different pyrite types and between the various palaeoplacer deposits. Especially the Ni and Au concentrations as well as Co/Ni and Mo/Ni ratios were found to be systematically different in detrital compact, detrital porous and post-sedimentary/hydrothermal pyrite grains from different source areas. High Co/Ni ratios and low Au concentrations are typical of post-sedimentary pyrite, which is hydrothermal in origin. In contrast, relatively low Co/Ni ratios and high Au contents characterise detrital porous banded and concentric pyrite grains (Au > 1 ppm), which are syn-sedimentary in origin. In the Elliot Lake area and the Witwatersrand Basin, detrital compact rounded pyrite is characterised by high Co/Ni ratios, which is in agreement with derivation from a hydrothermal source. Low Au concentrations in this pyrite type support the contention of the gold and the pyrite in these deposits coming from different source rocks. In contrast, derivation from an originally diagenetic pyrite is suggested for the detrital compact pyrite in the Ouro Fino Syncline because of low to intermediate Co/Ni ratios. High Au contents may indicate a genetic relationship between pyrite and gold there. Systematic differences exist between the three areas with respect to Au, Ni, Co, Mo and Cu distributions in detrital pyrite, which reflects differences in the provenance. A predominantly mafic/ultramafic source is indicated for the Ouro Fino, a felsic source for the Elliot Lake, and a mixed felsic–mafic provenance for the Witwatersrand pyrite populations. Independently of pyrite type, the higher Au endowment of the studied Witwatersrand and Ouro Fino conglomerates are also reflected by an overall higher Au concentration in the respective pyrite grains compared to the relatively Au-poor samples from Elliot Lake. In general, a strong positive correlation between Au and Pb levels in the various pyrite grains is noted. Analogous to Pb, which is well known for not being easily accommodated in the pyrite crystal lattice but occurring as discrete PbS phases, Au is considered to be present mainly in the form of discrete Au phases in minute pores and interstices of the pyrite grains rather than within the pyrite lattice.     

Post-depositional redistribution of trace metals in reservoir sediments of a mining/smelting-impacted watershed (the Lot River,SW France)

Mining/smelting wastes and reservoir sediment cores from the Lot River watershed were studied using mineralogical (XRD, SEM–EDS, EMPA) and geochemical (redox dynamics, selective extractions) approaches to characterize the main carrier phases of trace metals. These two approaches permitted determining the role of post-depositional redistribution processes in sediments and their effects on the fate and mobility of trace metals. The mining/smelting wastes showed heterogeneous mineral compositions with highly variable contents of trace metals. The main trace metal-bearing phases include spinels affected by secondary processes, silicates and sulfates. The results indicate a clear change in the chemical partitioning of trace metals between the reservoir sediments upstream and downstream of the mining/smelting activities, with the downstream sediments showing a 2-fold to 5-fold greater contribution of the oxidizable fraction. This increase was ascribed to stronger post-depositional redistribution of trace metals related to intense early diagenetic processes, including dissolution of trace metal-bearing phases and precipitation of authigenic sulfide phases through organic matter (OM) mineralization. This redistribution is due to high inputs (derived from mining/smelting waste weathering) at the water–sediment interface of (i) dissolved SO₄ promoting more efficient OM mineralization, and (ii) highly reactive trace metal-bearing particles. As a result, the main trace metal-bearing phases in the downstream sediments are represented by Zn- and Fe-sulfides, with minor occurrence of detrital zincian spinels, sulfates and Fe-oxyhydroxides. Sequestration of trace metals in sulfides at depth in reservoir sediments does not represent long term sequestration owing to possible resuspension of anoxic sediments by natural (floods) and/or anthropogenic (dredging, dam flush) events that might promote trace metal mobilization through sulfide oxidation. It is estimated that, during a major flood event, about 870 t of Zn, 18 t of Cd, 25 t of Pb and 17 t of Cu could be mobilized from the downstream reservoir sediments along the Lot River by resuspension-induced oxidation of sulfide phases. These amounts are equivalent to 13-fold (Cd), ∼6-fold (Zn), 4-fold (Pb) the mean annual inputs of the respective dissolved trace metals into the Gironde estuary.     

Deep solid-state equilibration and deep melting of plagioclase-free spinel peridotite from the slow-spreading Mid-Atlantic Ridge, ODP Leg 153

A petrological investigation of abyssal, plagioclase-free spinel peridotite drilled during ODP cruise 153 in the North Atlantic revealed that the peridotite represent refractory, partial residual mantle material that experienced depletion of incompatible trace elements during upper mantle melting. The degree of partial melting as estimated from spinel compositions was c. 12%. Fractionated middle and heavy rare earth elements imply polybaric melting, with c. 1–4% initial melting in the garnet peridotite stability field and subsequent partial melting of ~7–10% in the spinel peridotite stability field. Geothermobarometric investigations revealed that the solid-state equilibration of the spinel peridotite occurred at some 1,100–1,150°C and c. 20–23 kbar, corresponding to an equilibration depth of c. 70?±?5 km and an unusually low thermal gradient of some 11–17°C/km. A thermal re-equilibration of the peridotite occurred at ~850–1,000°C at similar depths. Naturally, the initial mantle melting in the garnet-peridotite stability field must have commenced at depths greater than 70?±?5 km. It is likely that the residual peridotite rose rapidly through the lithospheric cap towards the ridge axis. The exhumation of the abyssal peridotite occurred, at least in parts, via extensional detachment faulting. Given the shallow to moderate dip angles of the fault surfaces, the exhumation of the peridotite from its equilibration depth would imply an overall ridge-normal horizontal displacement of c. 50–160 km if tectonic stretching and detachment faulting were the sole exhumation mechanism.     

Groundwater use and policy in community water supply in Finland

Selection between ground and surface water in community water supply has been one of the key strategic questions in Finland since the early 1900s. After some cities failed to find reliable groundwater sources, many turned to surface waters. Since the 1950s the use of groundwater and artificial recharged groundwater have continuously increased. Presently their use is promoted by the government and European water policy through technical advice and financial support. It is obvious that the share of groundwater and artificial recharged groundwater will increase in the future. This requires active public response and transparency in decision-making.

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Resumen Desde el principio de 1900 una de las preguntas estratégicas clave en Finlandia es la selección entre agua subterranea y de superficie para el suministro de agua de la comunidad. Muchas ciudades renunciaron al agua de superficie luego de haber fracesado en encontrar fuentes de agua subterránea confiables. Desde 1950 el uso de agua subterránea y de agua subterránea recargada artificialmente ha aumentado continuamente. Actualmente los políticas de agua del gobierno y de Europa promueven su uso por medio de asesoría técnica y apoyo financiero. Es obvio que la participación del agua subterránea y del agua subterránea recargada artificialmente va a aumentar en el futuro. Esto requiere una respuesta activa pública y transparencia en el proceso de toma de decisiones.

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Resumé Le choix parmi lutilisation de leau de surface ou de leau souterraine comme source dapprovisionnement en eau potable est, depuis le début des années 1900, une question stratégique en Finlande. Suite à léchec de certaines villes à sapprovisionner en eau souterraine, plusieurs se sont tournées vers leau de surface. Depuis les années 1950, lutilisation de leau souterraine et la recharge artificielle des aquifères est en constante croissance. Actuellement, leur utilisation est encouragée par le Gouvernement ainsi que par la politique européenne de leau qui fournit une expertise technique et un soutient financier. Il est évident que les proportions occupées par lapprovisionnement en eau souterraine et la recharge artificielle vont augmenter avec le temps. Ceci requiert une participation active du public ainsi que de la transparence lors du processus décisionnel.

     

Impact of systematic errors on precise long-baseline kinematic GPS positioning

Many kinematic GPS applications rely on high accuracy, which usually requires the ambiguities to be fixed. Normally, a reference station in the rover’s vicinity is needed for successful ambiguity resolution. Alternatively, a network surrounding the rover and allowing one to derive area correction parameters is needed. Unfortunately, both approaches are not feasible in certain situations. This paper is a contribution to precise kinematic positioning over long baselines. Atmospheric refraction becomes critical in the error budget, but progress has been made to use numerical weather models to derive tropospheric corrections, for instance. The spatial correlation of both ionospheric and tropospheric propagation delays is investigated in this paper and special attention is paid on the systematic error behavior of tropospheric refraction. The principles developed are applied to an extended reliability test of the ambiguities. Finally, it is demonstrated in positioning experiments that kinematic positioning retrieval with fixed ambiguities is actually possible for baselines between 150 and 300 km with an accuracy of approximately 2 cm in post-mission processing.

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Spatial Size and Plasma Variables of RHESSI Flares

We have analysed 64 flares observed with GOES and RHESSI in the 3.1?–?24.8 keV band (0.5?–?4 Å). Flares were randomly chosen to represent different GOES classes, between B1 and M6. RHESSI was used to image the flaring region on the surface of the Sun. We derived the spatial area of the flare on the surface of the Sun from the imaging observations, scaled it dimensionally to volume, and used the spectroscopically derived emission measure to obtain several flare parameters. We experimented with several imaging methods and selected the use of 50% maximum image photon flux contours to define the flare area (F _50%). Most of the flares showed a single spherical loop-top source. The volume measurement for V, temperature T, and electron density N produced power indices that showed no correlation within the boundaries of error. Larger flares by loop-top source volume are thus neither hotter nor denser. The background-subtracted GOES flux?–?RHESSI Total Emission Measure (TEM _RHESSI) and TEM _GOES?–?TEM _RHESSI dependencies were in agreement with the instrument characteristics and earlier studies. Nonthermal flux was noticed to increase with thermal energy and TEM, which can be said to agree with the “Big Flare Syndrome,” with nonthermal photon flux being considered as one flare manifestation.     

Compound response of marine and terrestrial ecosystems to varying climate: pre-anthropogenic perspective from bivalve shell growth increments and tree-rings

Annual growth increments were examined from shells of the ocean quahog (Arctica islandica L.) from northwest Norway and from tree-ring samples of the Scots pine (Pinus sylvestris L.) from nearby coastal areas. The reconstructed annual growth increments were used to compare growth variability in marine and terrestrial ecosystems. Spatiotemporal comparison of the growth records showed statistically significant correlation during the 19th century A.D., indicative of ecosystem-independent response to pre-anthropogenic climate variations. Geographical correlation between marine and terrestrial records was only observed at the local scale. Years with particularly low winter or high summer North Atlantic Oscillation (NAO) indices showed the best synchronization of marine and terrestrial growth. Despite strong correlation during historical time, our palaeoecological evidence suggests that marine and terrestrial ecosystems may show dissimilar growth reaction to recently observed positive winter-NAO phases.     

Die gitter-, netz- und wabenförmige Verwitterung der Sandsteine

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Über die neogene Geosynklinale von Südsumatra und das Entstehen der Braunkohle

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