Biomarker responses in Macoma nasuta (Bivalvia) exposed to sediments from northern San Francisco Bay

Our study investigates biomarker responses and survival of Macoma nasuta exposed to sediments collected from six locations in northern San Francisco Bay. Biomarkers analyzed were stress proteins (hsp70) in gill, mantle and digestive gland, lysosomal membrane damage and histopathologic lesions. Sediments and clam tissues were analyzed for a comprehensive suite of heavy metals and trace organic pollutants. Sediment grain size and organic carbon content were determined. Clams accumulated metals, polyaromatic hydrocarbons (PAHs) and organochlorine pesticides (aldrin and p,p(')-DDT and its metabolites p,p(')-DDD and p,p(')-DDE). Pearson and Spearman correlation analysis revealed that mortality, hsp70 in gill and histopathologic lesion scores in gonads, and lysosomal membrane damage were significantly correlated with tissue concentrations of DDT and/or its metabolites. Tissue concentrations of metals, in particular nickel, chromium, and copper, were associated with macrophage aggregates in digestive gland and germ cell necrosis. Cadmium was linked to mortality and lysosomal membrane damage.     

Vibration of finite water bodies with free surface

Summary The study deals with expansion waves in fluids, with particular reference to hydrodynamic earthquake effects. The current assumption of steady harmonic motion is compared with the assumption that the motion is discontinuous in the sense that it starts from the initial condition of rest. A numerical example shows that the impulsive start may have a considerable influence on the dynamic water pressure.     

On non-artesian groundwater flow

Summary The present paper deals with certain problems of non-artesian aquifers, with special reference to non-steady flow due to replenishment from the ground surface. Solutions are obtained by direct integration ofBoussinesq's differential equation (transformed), taking also the inclination of the groundwater surface and the slope of the bottom of the aquifer into account. — The study has some bearing on hydrological investigations. For example, it may be desired to find the location of a moving groundwater divide between two water courses, or to determine the quantity of groundwater passing between them. Problems of this nature are also often met with in water supply (artificial infiltration, etc.) and other fields of engineering practice.     

Über den Temperaturkoeffizienten der Empfindlichkeit galvanisch erzeugter Thermosäulen

Zusammenfassung Es wird gezeigt, daß es möglich ist, auf galvanischem Wege Thermosäulen zu erzeugen, deren Empfindlichkeit von der Bezugstemperatur unabhängig ist. Der galvanische Niederschlag muß hierbei eine bestimmte Stärke besitzen, die vom Querschnitt des Materials der Unterlage abhängt. Eine entsprechend dimensionierte Kupfer-Konstantan-Thermosäule besitzt eine um 23% geringere Empfindlichkeit als eine normale Thermosäule der gleichen Materialien und gleicher Gliederzahl; ihre Linearität wird durch dieses Verfahren verbessert.

---

Summary The possibility is shown to produce a thermopile by electroplating, the sensitivity of which is independent from the reference temperature. In this case the deposition must have a fixed thickness depending upon the cross section of the base wire. A copper-constantan-thermopile made in this way has a sensitivity being 23 per cent smaller than that of a normal thermopile of the same materials and with the same number of junctions; its linearity is improved by this process.

---

Résumé On montre qu'il est possible de construire une pile thermoélectrique par galvanoplastie dont la sensibilité est indépendante de la température de référence. Le dépôt galvanique doit avoir une certaine épaisseur en rapport avec la section du noyau. Une pile cuivre-constantan de cette nature a une sensibilité de 23% plus faible qu'une pile normale de même composition et du même nombre de soudures; le processus de fabrication indiqué rend plus linéaires ses indications.

---

---

Mit 2 Textabbildungen     

Multi-proxy Reconstruction of Trophic State,Hypolimnetic Anoxia and Phototrophic Sulphur Bacteria Abundance in a Dimictic Lake in Northern Germany over the past 80 Years

During monthly investigations from 1996 to 2000, a hypolimnetic layer of phototrophic sulphur bacteria (Chromatium spp.) were observed in Lake Dudinghausen, a small dimictic lake in northern Germany. This paleolimnological study was initiated to detect if the occurrence of sulphur bacteria was related to cultural eutrophication or reflected natural conditions. Therefore, diatoms, algal pigments, okenone, geochemical proxies, and ²¹⁰Pb and ¹³⁷Cs were used in four sediment cores to investigate historical changes in trophic development, hypolimnetic redox conditions, anoxia and phototrophic sulphur bacteria abundances. Fossil diatoms, pigments, the ratio of chlorophyll derivatives to total carotenoids and the ratio of chlorophyll a to its derivatives suggest two phases of eutrophication coupled with hypolimnetic anoxia over the last ~80 years: a first phase from about 1923–1932 and a second from 1952 to 1982. In the first phase the ratios of Fe–Mn as well as Fe–Ca increased, suggesting seasonal anoxia. However, hypolimnetic anoxia was only weak because low levels of okenone suggest no mass development of sulphur bacteria. In contrast, sulphur bacteria increased during the early stages of the second eutrophication phase, suggesting increased temporal and spatial hypolimnetic anoxia. Surprisingly, the ratios of Fe–Mn as well as Fe–Ca decreased during this time. Possibly Fe, Mn and Ca were equally reduced through the intense anoxia. In the final stage, sulphur bacteria decreased again. As these bacteria need both anoxic conditions and a certain amount of light, the increased nutrient load probably led to low Secchi depth and therefore insufficient light conditions. In more recent years, diatoms and pigments suggest a decrease in nutrient levels. A second mass development of sulphur bacteria occurred, probably due to improved light conditions and continued anoxia in the upper hypolimnion. We conclude that the recent development of phototrophic sulphur bacteria do not represent natural conditions in Lake Dudinghausen. Furthermore, the upper sediments contain a completely new diatom flora that never occurred in older sediments of Lake Dudinghausen. Therefore, nutrient levels may eventually reach natural conditions, however they may not represent biological background reference conditions.     

Crustal Provenance and Cooling of the Basement Complexes of the Sierra de San Luis: An Insight Into the Tectonic History of the Pro to-Andean Margin of Gondwana

The Sierra de San Luis constitutes the southernmost tip of the Eastern Sierras Pampeanas. Its Palaeozoic metamorphic basement units define a key location for the understanding of the accretional history along the proto-Andean margin of Gondwana. Although, it is largely accepted that the polyphase accretional history of the Sierras Pampeanas is preluded by the docking of the Pampean Terrane followed by the Famatinian Orogenic Cycle that involves subduction along the margin of Gondwana and the accretion of the Precordillera (Cuyania) Terrane and finally ceased with the collision of the Chilenia terrane, a vast amount of controversial information concerning the timing and mode of collisions as well as the origin of the different involved crustal fragments within the Eastern Sierras Pampeanas is published. In this paper, those different hypothesis are presented and evaluated under the light of new isotopic data of the Sierra de San Luis. Nd-systematics of the metasedimentary sequences of the Sierra de San Luis indicate that the studied sequences were developed on the Pampean Terrane. An Amazonian origin of the Pampean Terrane that was probably detached from the Arequipa Antofalla Craton is proposed. Furthermore, the correlation of two low-grade phyllitic belts (San Luis Formation) with the widespread Puncoviscana Formation is not supported by Sm-Nd data. It is suggested that the sedimentary precursors of the Pringles Metamorphic Complex and the topping phyllites were sourced on the Pampean Orogen and accommodated in a newly formed back arc basin during the early Famatinian.

The cooling history of the basement complex is recorded by an extensive amount of K-Ar muscovite and biotite ages. A high variability in muscovite ages is only partly related to different intrusion times of two pegmatoid generations. Post Famatinian to Achalian crustal scale mylonite formation (-359 Ma) and a rotational exhumation of the central basement unit are causal for the observed K-Ar muscovite age pattern in the range from 395 Ma to 447 Ma. Therefore, the decrease in metamorphic degree from west to east is the result of the erosion level of a crustal profile from the mid lower crust to the upper crust. An even higher variability in K-Ar biotite cooling ages covering the range from 315 Ma to 418 Ma is related to the slow cooling after the Famatinian Orogenic Cycle or reheating during the Achalian Orogenic Cycle and consequent variable reset of the isotopic system. However, ages recorded by biotite booklets substantiate the hypothesis of a differential exhumation of the basement of the Sierra de San Luis.     

Aluminous granulites from the Pulur complex, NE Turkey: a case of partial melting, efficient melt extraction and crystallisation

In the Pulur complex, NE Turkey, a heterogeneous rock sequence ranging from quartz-rich mesocratic gneisses to silica- and alkali-deficient, Fe-, Mg- and Al-rich melanocratic rocks is characterized by granulite-facies assemblages involving garnet, cordierite, sillimanite, ilmenite, ±spinel, ±plagioclase, ±quartz, ±biotite, ±corundum, rutile and monazite. Textural evidence for partial melting in the aluminous granulites, particularly leucosomes, is largely absent or strongly obliterated by a late-stage hydrothermal overprint. However, inclusion relations, high peak P–T conditions, the refractory modes, bulk and biotite compositions of the melanocratic rocks strongly support a model of partial melting. The melt was almost completely removed from the melanocratic rocks and crystallised within the adjacent mesocratic gneisses which are silica-rich, bear evidence of former feldspar and show a large range in major element concentrations as well as a negative correlation of most elements with SiO₂. Peak conditions are estimated to be ≥800 °C and 0.7–0.8 GPa. Subsequent near-isothermal decompression to 0.4–0.5 GPa at 800–730 °C is suggested by the formation of cordierite coronas and cordierite–spinel symplectites around garnet and in the matrix. Sm–Nd, Rb–Sr and ⁴⁰Ar/³⁹Ar isotope data indicate peak conditions at 330 Ma and cooling below 300 °C at 310 Ma.     

Apophyllite (001) surface alteration in aqueous solutions studied by HAFM

Depending on pH and temperature, two different types of surface reactions occur on the apophyllite (001) surface in aqueous HCl-solutions at temperatures from 20 to 130 °C. At low pH, laterally spreading hillocks cover the surface. The hillocks are softer than the pristine surface, chemical analysis shows a depletion in Ca + K, and the spreading velocity of hillocks depends on pH. This indicates a change in chemical bond strength, non-stoichiometric dissolution and a mechanism involving protons. External disturbances such as the AFM scanning tip cause the upper surface layers to peel off revealing that the active sites of hillock formation are between the silicate layers of apophyllite. The observed process can therefore be described by a penetrative ion-replacement reaction which proceeds well below the surface monolayer. By this ion-replacement, the silicate layers eventually become destabilised. The observed reaction, therefore, is equivalent to an incongruent dissolution process. Despite structural similarities, this process is only superficially similar to the ion-exchange occurring in clay minerals or zeolites. In these minerals, the structural backbone is not destabilized. At a more neutral pH and high temperatures, step retreat and etch pit formation can be observed on the apophyllite (001) surface thus indicating a more congruent dissolution mechanism.     

Die Grödener Schichten (Perm,Südalpen). Sedimentologische und geochemische Untersuchungen zur Unterscheidung mariner und kontinentaler Sedimente

Within the sedimentation area of the Gröden formation two facies units have been observed: The attributes of one facies correspond with a deposition in continental environment. Kaolinitic weathering and fresh-water algae support this interpretation. The other facies is deposed in marine environment (supply of Mg for dolomitization and formation of chlorites, scarce forams). The transition facies shows characteristics of a costal region with marginal lagoons. Paleontological data (tetrapod traces, drifted cephalopods and forams) are in accordance with this model. The paleogeographical development during the Middle Permian is as follows: Continental sedimentation at the basis, marine transgression in the Carnic Alps and the western Karawanken during lower Gröden stage, progressiv transgression during the middle Gröden stage to the west with a coast line near Gröden valley and a coast line near River Etsch at the end of the Middle Permian.