Mobilization of arsenic and iron from Red River floodplain sediments, Vietnam

Sediments from the Red River and from an adjacent floodplain aquifer were investigated with respect to the speciation of Fe and As in the solid phase, to trace the diagenetic changes in the river sediment upon burial into young aquifers, and the related mechanisms of arsenic release to the groundwater. Goethite with subordinate amounts of hematite were, using Mössbauer spectroscopy, identified as the iron oxide minerals present in both types of sediment. The release kinetics of Fe, As, Mn and PO₄ from the sediment were investigated in leaching experiments with HCl and 10 mM ascorbic acid, both at pH 3. From the river sediments, most of the Fe and As was mobilized by reductive dissolution with ascorbic acid while HCl released very little Fe and As. This suggests As to be associated with an Fe-oxide phase. For oxidized aquifer sediment most Fe was mobilized by ascorbic acid but here not much As was released. However, the reduced aquifer sediments contained a large pool of Fe(II) and As that is readily leached by HCl, probably derived from an unidentified authigenic Fe(II)-containing mineral which incorporates As as well. Extraction with ascorbic acid indicates that the river sediments contain both As(V) and As(III), while the reduced aquifer sediment almost exclusively releases As(III). The difference in the amount of Fe(II) leached from river and oxidized aquifer sediments by ascorbic acid and HCl, was attributed to reductive dissolution of Fe(III). The reactivity of this pool of Fe(III) was quantified by a rate law and compared to that of synthetic iron oxides. In the river mud, Fe(III) had a reactivity close to that of ferrihydrite, while the river sand and oxidized aquifer sediment exhibited a reactivity ranging from lepidocrocite or poorly crystalline goethite to hematite. Mineralogy by itself appears to be a poor predictor of the iron oxide reactivity in natural samples using the reactivity of synthetic Fe-oxides as a reference. Sediments were incubated, both unamended and with acetate added, and monitored for up to 2 months. The river mud showed the fastest release of both Fe and As, while the effect of acetate addition was minor. This suggests that the presence of reactive organic carbon is not rate limiting. In the case of the river and aquifer sediments, the release of Fe and As was always stimulated by acetate addition and here reactive organic carbon was clearly the rate limiting factor. The reduced aquifer sediment apparently can sustain slower but prolonged microbially-driven release of As. The highly reactive pools of Fe(III) and As in the river mud could be due to reoxidation of As and Fe contained in the reducing groundwater from the floodplain aquifers that are discharging into the river. Deposition of the suspended mud on the floodplain during high river stages is proposed to be a major flux of As onto the floodplain and into the underlying aquifers.     

Analytical and numerical investigation of multicomponent multiphase WAG displacements

In this paper the ability of analytical solutions for four-component three-phase flow to predict displacement efficiency in water alternating gas (WAG) injection processes is studied. First analytical solutions for Riemann problems with injection compositions that are the average water and gas mixture for various WAG injection schemes are presented. These solutions are compared to numerical calculations with variable slug sizes and used to explore the effect of slug size, injecting water vs gas first, and the average injection composition on displacement efficiency in compositional WAG schemes. The example model is partially miscible WAG injection of water and CO₂ into an oil reservoir containing C₁₀ and CH₄ with and without a mobile aqueous phase present initially. The trailing end of the water and gas profiles are sensitive to whether water or gas is injected first, but the magnitude of the oil bank and the breakthrough time of the injected fluids are accurately predicted by the analytical solutions, even for displacements where large water and gas slugs are injected. Fluctuations in the saturation and composition profiles resulting from the alternating injection sequence in the WAG simulations appear as super-imposed on top of the sequence of rarefaction and shock waves predicted by analytical solutions. As the number of slugs increases, the effect of alternating boundary conditions diminishes and the displacements predicted by numerical calculations converge to the analytical solutions.     

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.     

A new physically based stochastic event catalog for hail in Europe

Hailstorms represent one of the major sources of damage and insurance loss to residential, commercial, and agricultural assets in several parts of Central Europe. However, there is little knowledge of hail risk across Europe beyond local historical damage reports due to the relative rarity of severe hail events and the lack of uniform detection methods. Here we present a new stochastic catalog of hailstorms for Europe. It is based on satellite observations of overshooting cloud tops (OT) that indicate very strong convective updrafts and hail reports from the European Severe Weather Database (ESWD). Historic hail events are defined based on OT detections from satellite infrared brightness temperatures between 2004 and 2011 for the warm seasons (April–September). The satellite-based historical event properties are complemented by hailstone observations from ESWD to stochastically simulate more than 1 million individual events with an event footprint resolution of 10 km. The final hail event catalog presented in this paper is the first one with a spatial event distribution that is based on a single homogeneous observation source over Europe. Areas of high hail probability or hail risk are found over Central and Southern Europe, including mountainous regions such as the Alps or the Pyrenees. Another region of relatively high hail risk is present over central Eastern Europe.     

Mutual Potential of Homogeneous Polyhedra

The mutual gravitational potential between a pair of homogeneous polyhedra is expressed using an infinite series. The nested volume integrals are evaluated analytically and result in simple tensor expressions containing no special functions. However, complexity increases as O(6 ⁿ ), where n is the term degree. An alternate formulation due to Liebenthal is also presented.     

The myth of the brackish Sarmatian Sea

The biota of the 1.5 Ma period of the Middle Miocene Sarmatian of the Central Paratethys lack stenohaline components. This was the reason to interpret the Sarmatian stage as transitional between the marine Badenian and the lacustrine Pannonian stages. However, our new data indicate that brackish water conditions could not have prevailed. Sarmatian foraminifera, molluscs, serpulids, bryozoans, dasycladacean and corallinacean algae as well as diatoms clearly indicate normal marine conditions for the entire Sarmatian. During the Lower Sarmatian, however, a sea-level lowstand forced the development of many marginal marine environments. During the Late Sarmatian a highly productive carbonate factory of oolite shoals, mass-occurrences of thick-shelled molluscs and larger foraminifera, as well as marine cements clearly point to normal marine to hypersaline conditions. This trend is not restricted to the western margin of the Pannonian Basin System but can be observed in the entire Central and even Eastern Paratethys.     

Evidence for a new MeV source observed by the COMPTEL experiment aboard CGRO

We report first evidence for a new unidentified and variable MeV source, located near the galactic plane at (l,b)∼(284.5°, 2.5°). The source, GRO J1036-55, is found at a significance level of ∼5.6σ by COMPTEL in its 3–10 MeV band. The energy spectrum indicates a spectral maximum at 3–4.3 MeV with a steep slope at higher energies. Since the COMPTEL 3–4.3 MeV data contain contamination by an instrumental background line, we performed several consistency checks, which all are consistent with an astrophysical nature of this emission feature.     

Die Galaktische BeschleunigungK(z) Und Das Lokale System

The galactic accelerationK(z) calculated by Perry (1969) is explained by the influence of a local galactic mass concentration.

---

---

Mitteilungen Serie A, Nr. 46.