Ontologies in support of activities in geographical space

A method is proposed to derive ontologies of geographical domains from natural language texts that describe human activities. Through its textual grounding, the method addresses the issue of where to take the contents of ontologies from. Through its focus on actions afforded by domain objects, it establishes a criterion for selecting the contents. The actions are organized into a hierarchical theory of human activities in the domain. Using an analysis of the German traffic code as a case study, the paper demonstrates the informal parts of the process to derive such ontologies.     

Life Histories, Salinity Zones, and Sublethal Contributions of Contaminants to Pelagic Fish Declines Illustrated with a Case Study of San Francisco Estuary, California, USA

Human effects on estuaries are often associated with major decreases in abundance of aquatic species. However, remediation priorities are difficult to identify when declines result from multiple stressors with interacting sublethal effects. The San Francisco Estuary offers a useful case study of the potential role of contaminants in declines of organisms because the waters of its delta chronically violate legal water quality standards; however, direct effects of contaminants on fish species are rarely observed. Lack of direct lethality in the field has prevented consensus that contaminants may be one of the major drivers of coincident but unexplained declines of fishes with differing life histories and habitats (anadromous, brackish, and freshwater). Our review of available evidence indicates that examining the effects of contaminants and other stressors on specific life stages in different seasons and salinity zones of the estuary is critical to identifying how several interacting stressors could contribute to a general syndrome of declines. Moreover, warming water temperatures of the magnitude projected by climate models increase metabolic rates of ectotherms, and can hasten elimination of some contaminants. However, for other pollutants, concurrent increases in respiratory rate or food intake result in higher doses per unit time without changes in the contaminant concentrations in the water. Food limitation and energetic costs of osmoregulating under altered salinities further limit the amount of energy available to fish; this energy must be redirected from growth and reproduction toward pollutant avoidance, enzymatic detoxification, or elimination. Because all of these processes require energy, bioenergetics methods are promising for evaluating effects of sublethal contaminants in the presence of other stressors, and for informing remediation. Predictive models that evaluate the direct and indirect effects of contaminants will be possible when data become available on energetic costs of exposure to contaminants given simultaneous exposure to non-contaminant stressors.     

Global warming and South Indian monsoon rainfall—lessons from the Mid-Miocene

Precipitation over India is driven by the Indian monsoon. Although changes in this atmospheric circulation are caused by the differential seasonal diabatic heating of Asia and the Indo-Pacific Ocean, it is so far unknown how global warming influences the monsoon rainfalls regionally. Herein, we present a Miocene pollen flora as the first direct proxy for monsoon over southern India during the Middle Miocene Climate Optimum. To identify climatic key parameters, such as mean annual temperature, warmest month temperature, coldest month temperature, mean annual precipitation, mean precipitation during the driest month, mean precipitation during the wettest month and mean precipitation during the warmest month the Coexistence Approach is applied. Irrespective of a ~ 3–4 °C higher global temperature during the Middle Miocene Climate Optimum, the results indicate a modern-like monsoonal precipitation pattern contrasting marine proxies which point to a strong decline of Indian monsoon in the Himalaya at this time. Therefore, the strength of monsoon rainfall in tropical India appears neither to be related to global warming nor to be linked with the atmospheric conditions over the Tibetan Plateau. For the future it implies that increased global warming does not necessarily entail changes in the South Indian monsoon rainfall.     

Microstructure characteristics during hydrate formation and dissociation revealed by X-ray tomographic microscopy

Despite much progress over the past years in fundamental gas hydrate research, frontiers to the unknown are the early beginning and early decomposition of gas hydrates in their natural, submarine environment: gas bubbles meeting ocean water and forming hydrate, and gas starting to escape from the surface of a hydrate grain. In this paper we report on both of these topics, and present three-dimensional microstructure results obtained by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM). Hydrates can precipitate when hydrate-forming molecules such as methane exceed solubility, and combine with water within the gas hydrate stability zone. Here we show hydrate formation on surfaces of bubbles from different gas mixtures and seawater, based on underwater robotic in situ experiments in the deep Monterey Canyon, offshore California. Hydrate begins to form from the surrounding water on the bubble surfaces, and subsequently grows inward into the bubble, evidenced by distinct edges. Over time, the bubbles become smaller while gas is being incorporated into newly formed hydrate. In contrast, current understanding has been that hydrate decomposition starts on the outer surface of hydrate aggregates and grains. It is shown that in an early stage of decomposition, newly found tube structures connect well-preserved gas hydrate patches to areas that are dissociating, demonstrating how dissociating areas in a hydrate grain are linked through hydrate that is still intact and will likely decompose at a later stage.

Vulnerability indicators of sea water intrusion

In this paper, simple indicators of the propensity for sea water intrusion (SWI) to occur (referred to as "SWI vulnerability indicators") are devised. The analysis is based on an existing analytical solution for the steady-state position of a sharp fresh water-salt water interface. Interface characteristics, that is, the wedge toe location and sea water volume, are used in quantifying SWI in both confined and unconfined aquifers. Rates-of-change (partial derivatives of the analytical solution) in the wedge toe or sea water volume are used to quantify the aquifer vulnerability to various stress situations, including (1) sea-level rise; (2) change in recharge (e.g., due to climate change); and (3) change in seaward discharge. A selection of coastal aquifer cases is used to apply the SWI vulnerability indicators, and the proposed methodology produces interpretations of SWI vulnerability that are broadly consistent with more comprehensive investigations. Several inferences regarding SWI vulnerability arise from the analysis, including: (1) sea-level rise impacts are more extensive in aquifers with head-controlled rather than flux-controlled inland boundaries, whereas the opposite is true for recharge change impacts; (2) sea-level rise does not induce SWI in constant-discharge confined aquifers; (3) SWI vulnerability varies depending on the causal factor, and therefore vulnerability composites are needed that differentiate vulnerability to such threats as sea-level rise, climate change, and changes in seaward groundwater discharge. We contend that the approach is an improvement over existing methods for characterizing SWI vulnerability, because the method has theoretical underpinnings and yet calculations are simple, although the coastal aquifer conceptualization is highly idealized.     

The diurnal variation of polar mesospheric cloud frequency near 55°N observed by SHIMMER

We present the first measurement of polar mesospheric cloud (PMC) occurrence frequency over the diurnal cycle from a satellite. The observations are made during the 2007 northern hemisphere PMC season by the Spatial Heterodyne IMager for MEsospheric Radicals (SHIMMER), which views the limb near 309 nm typically between 34 and 98 km. The PMC diurnal variation is derived between 50 and 58°N, where local times at the tangent point precess by ～30 min/day allowing for observations between 0330 and 2130 local time during the PMC season. We find that the occurrence frequencies exhibit a strong semidiurnal behavior with peaks near 0600 and 1800 local time and a minimum between 0900 and 1600 during which they are on average an order of magnitude less. The semidiurnal dependence is strongly correlated with concurrent ground-based measurements of meridional winds and temperatures measured at the same latitude. Our results for PMC frequency over the diurnal cycle can be used to help reconcile observations from other satellites that only permit cloud measurements at discrete local times.     

High-altitude data assimilation system experiments for the northern summer mesosphere season of 2007

A global numerical weather prediction system is extended to the mesosphere and lower thermosphere (MLT) and used to assimilate high-altitude satellite measurements of temperature, water vapor and ozone from MLS and SABER during May–July 2007. Assimilated temperature and humidity from 100 to 0.001 hPa show minimal biases compared to satellite data and existing analysis fields. Saturation ratios derived diagnostically from these assimilated temperature and water vapor fields at PMC altitudes and latitudes compare well with seasonal variations in PMC frequency measured from the aeronomy of ice in the mesosphere (AIM) satellite. Synoptic maps of these diagnostic saturation ratios correlate geographically with three independent transient mesospheric cloud events observed at midlatitudes by SHIMMER on STPSat-1 and by ground observers during June 2007. Assimilated temperatures and winds reveal broadly realistic amplitudes of the quasi 5-day wave and migrating tides as a function of latitude and height. For example, analyzed winds capture the dominant semidiurnal MLT wind patterns at 55°N in June 2007 measured independently by a meteor radar. The 5-day wave and migrating diurnal tide also modulate water vapor mixing ratios in the polar summer MLT. Possible origins of this variability are discussed.     

Assessment of the UV camera sulfur dioxide retrieval for point source plumes

Digital cameras, sensitive to specific regions of the ultra-violet (UV) spectrum, have been employed for quantifying sulfur dioxide (SO₂) emissions in recent years. The instruments make use of the selective absorption of UV light by SO₂ molecules to determine pathlength concentration. Many monitoring advantages are gained by using this technique, but the accuracy and limitations have not been thoroughly investigated. The effect of some user-controlled parameters, including image exposure duration, the diameter of the lens aperture, the frequency of calibration cell imaging, and the use of the single or paired bandpass filters, have not yet been addressed. In order to clarify methodological consequences and quantify accuracy, laboratory and field experiments were conducted. Images were collected of calibration cells under varying observational conditions, and our conclusions provide guidance for enhanced image collection. Results indicate that the calibration cell response is reliably linear below 1500 ppm m, but that the response is significantly affected by changing light conditions. Exposure durations that produced maximum image digital numbers above 32 500 counts can reduce noise in plume images. Sulfur dioxide retrieval results from a coal-fired power plant plume were compared to direct sampling measurements and the results indicate that the accuracy of the UV camera retrieval method is within the range of current spectrometric methods.     

Impact of Sea-Level Rise on Sea Water Intrusion in Coastal Aquifers

Despite its purported importance, previous studies of the influence of sea-level rise on coastal aquifers have focused on specific sites, and a generalized systematic analysis of the general case of the sea water intrusion response to sea-level rise has not been reported. In this study, a simple conceptual framework is used to provide a first-order assessment of sea water intrusion changes in coastal unconfined aquifers in response to sea-level rise. Two conceptual models are tested: (1) flux-controlled systems, in which ground water discharge to the sea is persistent despite changes in sea level, and (2) head-controlled systems, whereby ground water abstractions or surface features maintain the head condition in the aquifer despite sea-level changes. The conceptualization assumes steady-state conditions, a sharp interface sea water-fresh water transition zone, homogeneous and isotropic aquifer properties, and constant recharge. In the case of constant flux conditions, the upper limit for sea water intrusion due to sea-level rise (up to 1.5 m is tested) is no greater than 50 m for typical values of recharge, hydraulic conductivity, and aquifer depth. This is in striking contrast to the constant head cases, in which the magnitude of salt water toe migration is on the order of hundreds of meters to several kilometers for the same sea-level rise. This study has highlighted the importance of inland boundary conditions on the sea-level rise impact. It identifies combinations of hydrogeologic parameters that control whether large or small salt water toe migration will occur for any given change in a hydrogeologic variable.     

Do Cloud Properties in a Puerto Rican Tropical Montane Cloud Forest Depend on Occurrence of Long-Range Transported African Dust?

We investigated cloud properties of warm clouds in a tropical montane cloud forest at Pico del Este (1,051 m a.s.l.) in the northeastern part of Puerto Rico to address the question of whether cloud properties in the Caribbean could potentially be affected by African dust transported across the Atlantic Ocean. We analyzed data collected during 12 days in July 2011. Cloud droplet size spectra were measured using the FM-100 fog droplet spectrometer that measured droplet size distributions in the range from 2 to 49 µm, primarily during fog events. The droplet size spectra revealed a bimodal structure, with the first peak (D < 6 µm) being more pronounced in terms of droplet number concentrations, whereas the second peak (10 µm < D < 20 µm) was found to be the one relevant for total liquid water content (LWC) of the cloud. We identified three major clusters of characteristic droplet size spectra by means of hierarchical clustering. All clusters differed significantly from each other in droplet number concentration ( \(N_{\rm tot}\) ), effective diameter (ED), and median volume diameter (MVD). For the cluster comprising the largest droplets and the lowest droplet number concentrations, we found evidence of inhomogeneous mixing in the cloud. Contrastingly, the other two clusters revealed microphysical behavior, which could be expected under homogeneous mixing conditions. For those conditions, an increase in cloud condensation nuclei—e.g., from processed African dust transported to the site—is supposed to lead to an increased droplet concentration. In fact, one of these two clusters showed a clear shift of cloud droplet size spectra towards smaller droplet diameters. Since this cluster occurred during periods with strong evidence for the presence of long-range transported African dust, we hypothesize a link between the observed dust episodes and cloud characteristics in the Caribbean at our site, which is similar to the anthropogenic aerosol indirect effect.