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991.
Surface characterization of maize-straw-derived biochars and their sorption performance for MTBE and benzene 总被引:2,自引:1,他引:1
Liwei Xiao Erping Bi Beibei Du Xiaoli Zhao Chen Xing 《Environmental Earth Sciences》2014,71(12):5195-5205
Biochars generated at various temperatures might show significant differences in sorption for organic contaminants. In this study, a series of biochars, generated from pyrolyzing maize straws at different temperatures, were systematically characterized. The characterization results showed that with increasing pyrolysis temperature, the surface areas, micropore areas and aromaticity of biochars were enhanced. Batch experiments were conducted to study methyl tert-butyl ether (MTBE) and benzene sorption to biochars. The results indicated that the sorption capacity of benzene to biochars was higher than that of MTBE. The higher pyrolyzed temperature of biochars resulted in a stronger sorption affinity for target compounds, and the dominant sorption mechanisms varied for biochars pyrolyzed at different temperatures. The sorption to biochars pyrolyzed at 700 and 800 °C performed a high adsorption capacity, which indicated that they might be a promising sorbent to remove MTBE and benzene from water. Biochar pyrolyzed at 400 °C showed transitional sorption mechanisms from partition to adsorption for MTBE and benzene. Pore-filling was a possible sorption mechanism to biochars pyrolyzed at high temperature. 相似文献
992.
Jianglei Wang Yihe Lü Yuan Zeng Zhijiang Zhao Liwei Zhang Bojie Fu 《Environmental Earth Sciences》2014,72(7):2683-2696
Ecological restorations over time may have profound effects on ecological and socio-economic systems. However, land-use changes and landscape functions that accompany ecological restorations can have spatial differentiations due to varied biophysical and socio-economic contexts. Therefore, these spatial differentiations caused by ecological restoration must be understood for better planning and management of restoration activities. The Baota District, with 576 villages in the center of the Chinese Loess Plateau, was selected as the study area because of its dramatic transition from cropland to grassland and shrubland from 1990 to 2010. Using the ArcGIS software and a k-means clustering analysis, an approach to identify types of land-use change patterns (TLCPs) at the village level was developed, and four TLCPs were delineated. The analysis indicated a general pattern of cropland decline by 21.6 %, but revealed significant spatial variations between villages in different TLCPs. Vegetation cover and soil retention, which are key proxies for landscape functions, increased by 22.70 and 108 %, respectively, from 2000 to 2010 with significant spatial heterogeneity. The Universal Soil Loss Equation was employed for the assessment of soil retention. The analysis of landscape metrics revealed a major trend of fragmentation and regularity on the county and village scale; however, spatial variations remained. Physical attributes were used to characterize different TLCPs, and notable differences were found. The spatial heterogeneous change in land use and landscape functions on the village scale may be useful for land use and ecological restoration management policy makers. 相似文献
993.
Wei Chen Wenping Li Enke Hou Zhou Zhao Niandong Deng Hanying Bai Danzhi Wang 《Arabian Journal of Geosciences》2014,7(11):4499-4511
The main objective of this study was to apply a statistical (information value) model using geographic information system (GIS) to the Chencang District of Baoji, China. Landslide locations within the study area were identified using reports and aerial photographs, and a field survey. A total of 120 landslides were mapped, of which 84 (70 %) were randomly selected for building the landslide susceptibility model. The remaining 36 (30 %) were used for model validation. We considered a total of 10 potential factors that predispose an area to a landslide for the landslide susceptibility mapping. These included slope degree, altitude, slope aspect, plan curvature, geomorphology, distance from faults, lithology, land use, mean annual rainfall, and peak ground acceleration. Following an analysis of these factors, a landslide susceptibility map was produced using the information value model with GIS. The resulting landslide susceptibility index was divided into five classes (very high, high, moderate, low, and very low) using the natural breaks method. The corresponding distribution area percentages were 29.22, 25.14, 15.66, 15.60, and 14.38 %, respectively. Finally, landslide locations were used to validate the results of the landslide susceptibility map using areas under the curve (AUC). The AUC plot showed that the susceptibility map had a success rate of 81.79 % and a prediction accuracy of 82.95 %. Based on the results of the AUC evaluation, the landslide susceptibility map produced using the information value model exhibited good performance. 相似文献
994.
查明地质异常是成矿预测的基础、找矿的前提、靶区圈定的依据。本文以"三联式"成矿预测理论为指导,着重探讨了甘肃省铅锌矿地质、地球物理以及地球化学异常的识别、提取与圈定,运用定量分析方法,厘定地质异常与铅锌矿种之间的关联,在此基础上,运用证据权成矿预测方法实现对甘肃省铅锌矿床的成矿定量预测及成矿远景区圈定。 相似文献
995.
地热是主要地球物理场之一,地热能是地球的本土能源。李四光在20世纪60年代开创了我国地热科学。到90年代,学科体系基本建立。在过去20年里,我国地热研究得到了进一步深化和拓展。本文从大地热流、岩石圈热结构、地热系统、油气盆地地热、矿山地热、天然气水合物以及气候变化等方面回顾地热研究代表性的创新进展,并对深层地热、海洋地热、环境地热等研究方向作了展望。本文认为,过去20年我国地热研究成果丰硕,国际影响力得到提高,未来发展势头强劲。在经历了由浅入深,从今到古的成长之后,地热研究还将不断拓展领域,为我国地球科学,特别是能源与环境安全做出更大贡献。 相似文献
996.
在具有相同储集砂体和相似断层输导情况下,牛庄洼陷沙三中亚段砂岩体油藏长期存在以下难以解释的现象:1)现今砂岩孔隙度分布与油气分布不一致,高孔隙砂岩不含油而低孔隙砂岩含油;2)相同物性砂岩有的含油而有的不含油,含油砂体现今物性接近,但含油级别却存在很大差异。本文从古孔隙度恢复方面分析了牛庄洼陷西部地区沙三中砂岩储层在成藏期的储集条件,并探讨了成藏期储层临界孔隙度。研究发现:1)虽然现今储层物性下限很低,部分砂岩已经致密化,但成藏期的古孔隙度分布在18%~25%范围内,远大于成藏期临界孔隙度13.9%。但由于埋藏过程的差异导致砂岩储层后期减孔幅度不同,因而现今储层物性不能反映成藏期储层物性,成藏期孔隙度高并不能代表现今孔隙度高;2)成藏期高孔隙度带与现今油气分布范围高度一致,表明在相似断层输导条件下,由于储层物性级差优势形成油气优势运移通道,导致高孔隙度带砂体含油,因此,沙三中亚段岩性油藏富集在成藏期高孔隙带中,成藏期砂岩古孔隙度是油气成藏的重要控制因素,而现今砂岩储层高孔隙带在成藏期并不一定高。牛庄洼陷西部地区沙三中亚段储层中具有高古孔隙度的砂岩仍有较大勘探潜力。 相似文献
997.
998.
To ensure the safety of structures, high-speed railway and highway founded on liquefiable soils, liquefaction evaluation is a primary task. Herein, a dynamic set pair analysis method based on variable weights is introduced to assess liquefaction. A concept of connection degree of set pair consisting of the evaluation sample and the classification standard was described to interpret the uncertainty of liquefaction and relationship. Moreover, based on reward and penalty mechanism, state variable vectors were presented to assign composite weights of evaluation indicators in order to take into account impacts of indicator variation. And the integrated connection degree to each grade was calculated to evaluate liquefaction of the evaluated cases. Results from practical example and comparison with field investigation and extension method indicated that this proposed model used to evaluate liquefaction is feasible and effective. In addition, it can quantitatively describe liquefaction hierarchy of evaluated samples. 相似文献
999.
The relationships between fire danger indices and fire risk have been extensively studied in many regions of the world. This work uses partial effect analysis in semiparametric logistic regression models to assess the nonlinear relationships among location, day, altitude, fire danger indices, normalized difference vegetation index (NDVI), and fire ignition from 1996 to 2008 in four different climatic regions in China. The four regions are North China (NR), Northeast China (NE), Southeast China (SE), and Southwest China (SW). The three main results are as follows: First, different fire danger indices are selected as significant variables dependent on the region. The inter-regional difference could be partially explained by difference in local weather and vegetation conditions. Second, spatial location exerts highly significant effects in all four regions. NDVI values are selected as explained variable for NR, NE, and SE on fire ignitions. On a daily scale, altitude influences fire ignition for NR, SE, and SW. Third, the robustness of the probability models used in NE, SE, and SW is better than that in NR on a daily scale. The semiparametric logistic regression model used in this study is useful for assessing the ability of fire danger indices to estimate probabilities of fire ignition on a daily scale. This study encourages further research on assessing the predictive ability of fire danger indices developed at other temporal and spatial scales in China. 相似文献
1000.
The mineralogy of the high-volatile bituminous coals and associated strata from the Greta seam, Sydney Basin, Australia, has been evaluated in this study. Although the seam is not immediately overlain by marine strata, percolation of marine water into the original peat bed is indicated by the petrological, mineralogical and geochemical characteristics, which resemble those of coals with marine roof strata. The upper and lower sections of the seam have contrasting mineralogy. Pyrite typically comprises 40 to 56 wt% of the mineral assemblage in the marine-influenced upper part of the seam section. The lower part contains much less pyrite (typically <5 wt%, organic-free basis), and also relatively abundant dawsonite (up to 14 wt%, organic-free basis). The minerals within most coal plies are largely of authigenic origin. These include pyrite, siderite, clay minerals (mainly kaolinite and Na-rich mixed-layer illite/smectite), and quartz, most of which have a relatively early, syngenetic origin. Minor Ti-bearing minerals, anatase or rutile, and phosphate minerals, fluorapatite and goyazite, were probably also formed during early diagenesis. Other minerals have features that indicate late-stage precipitation. These include abundant cleat- and fracture-filling dawsonite, which may be the result of reactions between earlier-precipitated kaolinite and Na2CO3- or NaHCO3-bearing fluids. Minor albite may also be epigenetic, possibly precipitated from the same Ca–Al bearing fluids that formed the dawsonite. The most abundant detrital minerals in the Greta coals are quartz, poorly ordered kaolinite, illite and mixed-layer illite/smectite (I/S). These occur mainly in the floor, roof and other epiclastic horizons of the seam, reflecting periods of greater clastic influx into those parts of the original peat-forming environment. Detrital minerals are rare in the coals away from the epiclastic horizons, probably owing to almost complete sediment bypassing in the depositional system. Alternatively, any detrital minerals that were originally present may have been leached from the peat bed by diagenetic or post-diagenetic processes. 相似文献