Tracing origins of sewage and organic matter using dissolved sterols in Masan and Haengam Bay,Korea

Masan and Haengam Bays in Korea are highly polluted and semi-enclosed. Domestic and industrial effluents are directly or indirectly discharged into the bays through sewage treatment plants (STP) and creeks. In this study, 15 dissolved sterol compounds were determined in order to understand their sources and relative contribution. Freshwater samples were taken from 13 creeks and at two STP sites on a monthly basis. Total dissolved sterol concentrations ranged from 993 to 4158 ng/L. The concentrations of sterols in winter were higher than in summer. Among the sterols analyzed, cholesterol, β-sitosterol, coprostanol and cholestanone were major compounds in creek water. Seawater samples were concurrently collected at 21 stations in Masan Bay. Total sterol concentrations ranged 118–6,956 ng/L. Inner bay showed high concentrations of sterols in summer, while outer bay showed high sterol concentrations in winter. Among the sterols, cholesterol, β-sitosterol and brassicasterol were major compounds in seawater. In order to examine the contribution of urban sewage, the concentration of coprostanol and fecal sterol ratios were calculated. Most of the creek water, inner bay and near STP outlet samples were affected by sewage. Terrestrial organic matters accounted for a high proportion of dissolved organic matter origin. Fecal origins were relatively high in the inner bay areas and in the STP outlet, while sterols of marine origin were high in the outer bay areas.     

海洋底质测量专用标准规范研究

研究海洋底质测量专用标准体系构成及作业规范技术要点.分析专用海洋底质测量的任务构成和技术特点,依据底质测量的专用需求和国内外底质测量技术规范与数据格式标准的发展趋势,对海洋底质测量专用标准体系构成、数据格式标准及作业技术规程进行了探讨.     

甘肃拾金坡金矿床成因:来自40Ar/39Ar定年、成矿流体及H-O-S同位素证据

甘肃拾金坡金矿床是北山造山带南部的一处重要中型金矿床。矿体以石英脉和蚀变岩形式产出,受东西向断裂控制,赋矿围岩为早泥盆世拾金坡二长花岗岩。矿石中主要金属硫化物为黄铁矿及少量方铅矿、闪锌矿和磁黄铁矿。石英脉两侧花岗岩发生强烈的硅化、黄铁绢英岩化和绿泥石化。热液蚀变绢云母40 Ar/39 Ar坪年龄为(364.6±3)Ma,表明成矿作用发生在晚泥盆世。矿石石英中流体包裹体可分为早晚两期:早期流体包裹体群包含不同气液比水溶液包裹体和含CO2包裹体,指示成矿过程存在流体沸腾作用,其均一温度集中在280～325℃,盐度(w(NaCl))为7.86%～9.21%;晚期流体包裹体群只发育水溶液包裹体,均一温度集中于160～230℃,盐度为9.47%～11.10%。成矿流体属中温低盐度、富CO2流体。流体从早阶段演化到晚阶段,温度降低约100℃,压力由约113 MPa骤减到约11 MPa。流体包裹体的δ18 OH2O值为1.39‰～3.39‰,δD值为-71‰～-99‰。氢氧投图中,石英脉和蚀变岩样品构成良好的线性关系,暗示初始成矿流体主要来自变质热液,晚期有强烈大气降水加入。矿石金属硫化物δ34S值变化范围为4.44‰～11.33‰,峰值为8‰～9‰,呈塔式分布。与区域S同位素资料对比分析表明,石英脉型矿石S主要来自前寒武系基底,蚀变岩型矿石S更多地继承了花岗岩围岩S。综合分析认为,拾金坡金矿床属于造山型金矿,形成于造山晚期挤压—伸展转换环境。     

耿庄金矿含FeS2晶须环带重晶石巨晶的特征及成因意义

在山西耿庄金矿区含金隐爆角砾岩体的晶洞内,发现了含FeS2晶须环带重晶石巨晶,用扫描电镜、电子探针、Ｘ射线粉晶衍射等手段系统研究了重晶石及其所含FeS2晶须的矿物特征。结果表明,重晶石化学成分单一;晶体结构标准;发育完好;晶须为FeS2 Fe(Ni, Co)S2的类质同象系列。根据地质背景,结合包裹体研究成果,运用晶体生长和地球化学理论,讨论了重晶石巨晶及所含晶须的成因。认为重晶石巨晶是该区燕山期花岗岩浆活动的期后热液演化到后期阶段时,SO2-4与围岩中的钡反应而形成;所含的FeS2晶须是持续进行的火山隐爆作用所产生的大量H2S、SO2等与热液中分解出的Fe2+、Ni2+、Co2+反应而形成的;富碱、H2S溶解度增大,S2-增高有利于晶须的生长;重晶石和晶须生长的地质环境具有宏观上的一致性和具体条件的差异性。当pH值为1~8.5、lgfO2为-31~-38时,优先进入FeS2生长的优势场,形成FeS2晶须矿物。当pH值为5.5~10、lgfO2在-25~-36时形成重晶石;FeS2环带和重晶石的共生现象是两者共结晶交互生长的结果;重晶石的套叠生长和晶须环带特征,是耿庄地区隐爆作用脉动性和周期性作用的结果。耿庄含晶须重晶石巨晶,明确标示出所形成的地质条件和地质作用过程,为深入研究隐爆作用和理解该区成矿作用提供了矿物学证据。     

The study of s-process nucleosynthesis based on barium stars, CEMP-s and CEMP-r/s stars

In order to get a broader view of the s-process nucleosynthesis we study the abundance distribution of heavy elements of 35 barium stars and 24 CEMP-stars, including nine CEMP-s stars and 15 CEMP-r/s stars. The similar distribution of [Pb/hs] between CEMP-s and CEMP-r/s stars indicate that the s-process material of both CEMP-s and CEMP-r/s stars should have a uniform origin, i.e. mass transfer from their predominant AGB companions. For the CEMP-r/s stars, we found that the r-process should provide similar proportional contributes to the second s-peak and the third s-peak elements, and also be responsible for the higher overabundance of heavy elements than those in CEMP-s stars. Which hints that the r-process origin of CEMP-r/s stars should be closely linked to the main r-process. The fact that some small r values exist for both barium and CEMP-s stars, implies that the single exposure event of the s-process nucleosynthesis should be general in a wide metallicity range of our Galaxy. Based on the relation between C _r and C _s, we suggest that the origin of r-elements for CEMP-r/s stars have more sources. A common scenario is that the formation of the binary system was triggered by only one or a few supernova. In addition, accretion-induced collapse(AIC) or SN 1.5 should be the supplementary scenario, especially for these whose pre-AGB companion with higher mass and smaller orbit radius, which support the higher values of both C _r and C _s.     

Puzzling Origin of CEMP-r/s Stars: An Interpretation of Abundance and Enrichment of s- and r-Process Elements from Asymptotic Giant Branch Supernovae

CEMP-r/s stars at low metallicity are known as double-enhanced stars that show enhancements of both r-process and s-process elements. The chemical abundances of these very metal-poor stars provide us a lot of information for putting new restraints on models of neutron-capture processes. In this article, we put forward an accreted scenario in which the double enrichment of r-process and s-process elements is caused by a former intermediate-mass Asymptotic Giant Branch (AGB) companion in a detached binary system. As the AGB superwind is only present at the ultimate phase of AGB stars, there is thus a lot of potential that the degenerate-core mass of an intermediate-mass AGB star reaches the Chandrasekhar limit before the AGB superwind. In these circumstances, both s-process elements produced in the AGB shell and r-process elements synthesized in the subsequent explosion would be sprayed contemporaneously and accreted by its companion. Despite similarity to physical conditions of a core-collapse supernova, a major focus in this scenario is the degenerate C–O core surrounded by an envelope of a former intermediate-mass AGB donor that may collapse and explode. Due to the existence of an outer envelope, r-process nucleosynthesis is expected to occur. Hypothesizing the material-rich europium (Eu) accreted by the secondary via the wind from the supernova to be in proportion to the geometric fraction of the companion with respect to the exploding donor star, we find that the estimated yield of Eu (as representative of r-process elements) per AGB supernova event is about 1 × 10^?9 M _⊙ ～ 5 × 10^?9 M _⊙. Using the yields of Eu, the overabundance of r-process elements in CEMP-r/s stars can be accounted for. The calculated results show that the value of parameter f , standing for efficiency of wind pollution from the AGB supernova, will reach about 10⁴, which means that the enhanced factor is much larger than unity due to the impact of gravity of the donor and the result of the gravitational focusing effect of the companion.     

无锡光伏产业链中的全球-本地联系

以无锡市为例,通过实地调研当地光伏产业链中多晶硅生产、电池元件生产、组件制造、相关设备生产、光伏设备运维服务,以及光伏用户等不同环节,从全球生产网络的视角,考察全球-本地联系在当地光伏产业链形成演化和技术发展动态中的具体表现。结论指出：① 无锡光伏产业在短短10 a之内从“两头在外”的发展模式到形成全产业链竞争优势,体现了新兴技术的全球生产网络技术加速更新和产业快速转移的新特点;② 本地相关产业集群通过技术引进、消化和改进为新技术突破规模化瓶颈,获取市场竞争力打下基础,并由此对全球光伏技术发展的路径产生了关键影响;③ 产业进一步发展需要针对能源转型的长期目标,着重探索能源消费侧的技术转型路径。     

川西高原水环境的氧化还原特征初探

从川西高原饮用水赋存的环境-地质条件出发进行研究,较全面的探讨了该区气象、水文、土壤等环境要素对水中氧化还原电位的制约作用。通过对研究区内饮用水赋存环境的一系列环境地质调查与氧化还原电位的现场测试可以得出：（1）该研究区所处特殊的地理位置（青藏高原的东南部-横断山系北段,属川西高山高原区）导致该区具有冬长,无夏,春秋短,气温低,温差大等独有的气象条件;该区主要的构造侵蚀高山地貌类型导致地下水循环具有径流途径短,水力坡度大,水-土间交换作用十分强烈的特点,该区土壤的特点是淋滤作用较强且成弱酸性等,这三个环境要素的特点是直接导致该区饮用水中氧化还原电位值升高的主要原因;（2）由于不同类型水（河水、沟水、泉水、土井水）其与大气接触程度的差异导致其氧化还原值呈现由高到低的趋势,即河水〉沟水〉泉水〉土井水。     

Geology and Hydrothermal Alteration of the Milyang Pyrophyllite Deposit, Southeast Korea

Abstract: The Milyang pyrophyllite deposit, which is embedded in the Late Cretaceous Yuchon Group of the Kyongsang Supergroup, is one of the largest hydrothermal clay deposits in the Kyongsang basin, southeast Korea. Host rocks of the deposit are porphyritic andesite lava and minor andesitic lapilli tuff. In the Milyang district, a hydrothermally altered zone is about 2 × 3 km in extent; we can recognize the concentric arrangement of advanced argillic, propylitic, and sericitic alteration zones from the central to peripheral parts of the zone. The Milyang pyrophyllite deposit forms a part of the advanced argillic alteration zone. The Milyang pyrophyllite deposit is subdivided into the following four zones based on mineral assemblages: the pyrophyllite zones 1, 2, 3, and the silicified zone. The pyrophyllite zone 1, which occupies the central part of the deposit, comprises mainly pyrophyllite, kaolinite, and diaspore without quartz. Diaspore nodules often concentrate in beds 40–50 cm thick. Andalusite, dumortierite, and tourmaline locally occur as network veins, crack‐filler, or small spherulitic spots. The Al₂O₃ content of the ore ranges from 27 to 36 wt%. The pyrophyllite zone 2, which constitutes a major part of the deposit, comprises mainly pyrophyllite, kaolinite, and quartz. The Al₂O₃ content of the ore ranges from 15 to 24 wt%. The pyro‐phyllite zone 3 is the hematite‐rich marginal facies of the deposit. The silicified zone, which occurs as beds and septa, is mostly composed of quartz with minor pyrophyllite and kaolinite; the SiO₂ contents range from 79 to 90 wt%. Comparing chemical compositions of the high‐Al ores with those of unaltered host andesite, the Fe, Ca, alkalis, HFSE, and HREE contents are significantly depleted, whereas S, B, As, Sr, and LREE are enriched. The hydrothermal alteration of the Milyang pyrophyllite deposit can be classified into the following four stages: 1) extensive sericitic and propylitic alteration, 2) medium‐temperature (200–250°C) advanced argillic alteration, 3) high‐temperature (250–350°C or more) advanced argillic alteration, and 4) retrograde low‐temperature alteration. The heat and some volatile components such as B and S would be derived from the Pulguksa Granite intruded underneath the deposit.