Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments

The chemical speciation of potentially toxic elements (As, Cd, Cu, Pb, and Zn) in the contaminated soils and sulfides-rich tailings sediments of an abandoned tungsten mine in Korea was evaluated by conducting modified BCR sequential extraction tests. Kinetic and static batch leaching tests were also conducted to evaluate the potential release of As and other heavy metals by acidic rain water and the leaching behaviors of these heavy metals. The major sources of the elements were As-, Zn- and Pb-bearing sulfides, Pb carbonates (i.e., cerussite), and Pb sulfates (i.e., anglesite). The biggest pollutant fraction in these soil and tailing samples consists of metals bound to the oxidizable host phase, which can be released into the environment if conditions become oxidative, and/or to residual fractions. No significant difference in total element concentrations was observed between the tailings sediments and contaminated soils. For both sample types, almost no changes occurred in the mobility of As and the other heavy metals at 7 days, but the mobility increased afterwards until the end of the tests at 30 days, regardless of the initial pH. However, the mobility was approximately 5–10 times higher at initial pH 1.0 than at initial pHs of 3.0 and 5.0. The leached amounts of all the heavy metal contents were higher from tailings sediments than from contaminated soils at pH > 3.0, but were lower at pH < 3.0 except for As. Results of this study suggest that further dissolution of heavy metals from soil and tailing samples may occur during extended rainfall, resulting in a serious threat to surface and groundwater in the mine area.     

牧牛钨矿岩石地球化学特征与成矿作用

牧牛钨矿主要受断裂和NW向韧性剪切带的控制,空间上含矿构造自西向东逐步收敛,具有"帚"状特征.牧牛矿区先后发现5条含矿石英脉.通过岩石化学研究,里尔峪组为火山陆源碎屑沉积建造;矿区花岗岩属壳源成因,为中浅成侵入深度;斜长角闪岩和透辉岩属幔源成因.钨成矿与印支期岩浆岩有关,成矿作用具有多阶段性.钨矿的成矿温度275～400℃,为中-高温热液矿床.     

中国旅游地质资源分类,分区与编图

作者认为,旅游地质资源是指那些具有旅游价值的地质遗迹和地与地质体直接有关的人类活动遗迹,旅游地质资源具有空间定位性,永续性,不可再生性,科学性等主要特点。作者提出以旅游地质资源的旅游价值为基础,以其地质特点为依据,将我国的旅游地质资源划分为３５类;以控制旅游地质资源区域分布规律的自然地质地理条件为依据,对全国进行了探索性的旅游地质资源分区,将全国分为４个旅游地质资源区和１１个旅游地质资源亚区。     

辽东的主要剪切带及其金矿化特征

辽东地区构造上位于辽中—吉南元古宙活动带西南部,为胶辽克拉通金矿床分布比较集中的地区。金矿化作用发生于古元古宙变质沉积岩和花岗片麻岩的韧性及脆-韧性剪切带之中,剪切活动与成金事件具同时性关系。矿化剪切带分为3大系统,其中近东—西向和北东—南西向两大系统发育于辽河群分布区,其受控于岩石非均匀性,分别借助于早(吕梁)期S₁(≈S₀)和S₂或D₃剪切带而形成,剪切活动(构造事件)与成金事件主要发生于印支运动;丹东韧性剪切带及其相关构造为本区最重要的含矿系统,矿床均顺主构造线分布,并规律性地受控于其次级构造,剪切带的形成和成金事件均在燕山运动时期。本区提供了一个特殊的克拉通成矿作用格局:容矿岩石时代老,成金事件时代新。     

晚期海西运动在塔里木盆地北部油气藏形成中的作用

海西晚期，塔里木板块总体为挤压背景。有资料表明，该时期存在两次性质差异较大的构造运动：早二叠世末期和晚二叠世末期构造运动。前期运动以火山活动、海防变迁为特征；后期以沉积构造格局改变、褶皱、断裂活动为特征，并叠置于前期构造之上。晚期海西运动最终定型的古隆起控制了油气聚集指向，形成的古生代坳陷和中新代坳陷控制着油源区展布，造成了众多的、具有捕获油气能力的圈闭类型。断裂和区域性不整合面为油气运移提供了通道，而且对油气再分布及破坏亦有一定影响。     

煤的变质程度对焦炭结构构造的影响

从宏观和微观两方面对不同变质程度煤所形成焦炭的结构、构造进行了深入研究。从气煤到肥煤阶段（Ｒｏ，ｍ：０．７７％～１．１６％），焦炭气孔壁厚度逐渐增大；进入焦煤阶段（Ｒｏ，ｍ＞１．１６％），焦炭气孔壁厚度降低。气煤、１３焦煤形成的焦炭结构以各向同性体为主，焦煤、肥煤炼出的焦炭以粒状镶嵌结构为主。由气煤和高变质程度的焦煤形成的焦炭，其气孔以微孔和大孔为主，气孔分布标准差Ｄｓ最大；肥煤炼出的焦炭，其气孔分布大小较均一；１３焦煤和低变质程度的焦煤成焦后，气孔分布状况介于上述二者之间     

Tomography Imaging of Near-Surface Velocity Structure Experiment and Its Application in the Ore Concentrate Area of the Lower and Middle Yangtze River

利用矿集区获得的小道距、长排列接收的地震反射初至波走时数据,运用层析成像方法,首次得到长江中下游典型金属矿集区——庐枞火山岩盆地近地表1000 m以上的交叉速度结构.各剖面精细的速度结构揭露出庐枞矿集区隐伏的正长岩体顶界面深度与起伏形态,发现岩体顶面凸起及陡变化部位与矿体分布存在着明显的对应关系,罗河铁矿、小岭铁矿、龙桥铁矿、马鞭山铁矿处对应着高速层顶界面的凸起位置.罗河断裂在lz06-1线与lz06-3线表现为明显的横向速度变化界面.这些结果表明,长排列的深地震反射初至波走时层析成像方法能够为金属矿集区深部隐伏矿床的勘探研究提供丰富的地壳浅表结构(0～1000 m)信息.     

内陆河流域分布式日出山径流模型——以黑河干流山区流域为例

应用常规的气象水文数据并结合GIS,建立了一个适合西北干旱区内陆河山区流域的以日为步长的分布式径流模型,并对黑河干流山区出山径流进行了模拟计算和讨论。模型以子流域作为最小的产流、汇流单元,根据植被覆盖将各子流域分为裸地区、乔木区、牧草区和冰川区,并根据实际调查将土壤分为 3层,各分区单独进行水量平衡计算。产流过程以土壤储水能力和储水量表征,而储水能力和储水量等则由土壤的孔隙度、干密度和厚度等表征。入渗原理基于土壤储水率平衡原理,并考虑重力势的作用。实际蒸散发与蒸发力和土壤体积含水量的乘积成正比,不同的土壤和植被具有不同的调节参数。模拟结果表明,模拟效果较差的原因是区域日降水过程具有较大的随机性,难以用有限的站点合理计算区域日降水量。寻找一个合适的区域日降水量计算方法是目前少资料大型流域分布式水文模型模拟成功的关键。     

Magmatic‐Hydrothermal Mineralization Sequence in Xinlu Ore Field,Guangxi, South China: Constraints from Zircon U‐Pb,Molybdenite Re‐Os,and Muscovite Ar‐Ar Dating

The Xinlu Sn‐polymetallic ore field is located in the western Nanling Polymetallic Belt in northeastern Guangxi, South China, where a number of typical skarn‐, hydrothermal vein‐type tin deposits have developed. There are two types of Sn deposits: skarn‐type and sulfide‐quartz vein‐type. The tin mineralizations mainly occur on the south side of the Guposhan granitic complex pluton and within its outer contact zone. To constrain the Sn mineralization age and further understand its genetic links to the Guposhan granitic complex, a series of geochronological works has been conducted at the Liuheao deposit of the ore field using high‐precision zircon SHRIMP U‐Pb, molybdenite Re‐Os, and muscovite Ar‐Ar dating methods. The results show that the biotite‐monzogranite, which is part of the Xinlu intrusive unit of the Guposhan complex pluton, has a SHRIMP U‐Pb zircon age of 161.0 ± 1.5 Ma. The skarn‐type ore has a ⁴⁰Ar‐³⁹Ar muscovite plateau age of 160 ± 2 Ma (same as its isochron age), and the sulfide‐quartz vein‐type ore yields an Re‐Os molybdenite isochron age of 154.4 ± 3.5 Ma. The magmatic‐hydrothermal geochronological sequence demonstrated that the hydrothermal mineralization took place immediately following the emplacement of the monzogranite, with the skarn metasomatic mineralization stage predating the sulfide mineralization stage. Geochronologically, we have compared this ore field with 26 typical Sn deposits distributed along the Nanling Polymetallic Belt, leading to the suggestion of the magmatic‐metallogenic processes in the Xinlu ore field (ca. 161–154 Ma) as a component of the Early Yanshanian large‐scale Sn‐polymetallic mineralization event (peaked at 160–150 Ma) in the Nanling Range of South China. Petrogenesis of Sn‐producing granite and Sn‐polymetallic mineralization were probably caused by crust–mantle interaction as a result of significant lithospheric extension and thinning in South China in the Late Jurassic.     

Regional-scale surface air temperature and East Asian summer monsoon changes during the last millennium simulated by the FGOALS-gl climate system model

The spatial patterns and regional-scale surface air temperature （SAT） changes during the last millennium,as well as the variability of the East Asian summer monsoon （EASM） were simulated with a low-resolution version of Flexible Global Ocean-Atmosphere-Land-Sea-ice （FGOALS-gl） model.The model was driven by both natural and anthropogenic forcing agents.Major features of the simulated past millennial Northern Hemisphere （NH） mean SAT variations,including the Medieval Climate Anomaly （MCA）,the Little Ice Age （LIA） and the 20th Century Warming （20CW）,were generally consistent with the reconstructions.The simulated MCA showed a global cooling pattern with reference to the 1961-90 mean conditions,indicating the 20CW to be unprecedented over the last millennium in the simulation.The LIA was characterized by pronounced coldness over the continental extratropical NH in both the reconstruction and the simulation.The simulated global mean SAT difference between the MCA and LIA was 0.14°C,with enhanced warming over high-latitude NH continental regions.Consistencies between the simulation and the reconstruction on regional scales were lower than those on hemispheric scales.The major features agreed well between the simulated and reconstructed SAT variations over the Chinese domain,despite some inconsistency in details among different reconstructions.The EASM circulation during the MCA was stronger than that during the LIA The corresponding rainfall anomalies exhibited excessive rainfall in the north but deficient rainfall in the south.Both the zonal and meridional thermal contrast were enhanced during the MCA.This temperature anomaly pattern favored a stronger monsoon circulation.