Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Evolution of a Holocene banner bank controlled by morphodynamics and structural setting of a macrotidal coast: Saint-Brieuc Bay(NW-Europe)

The morphology and internal structure of the Horaine Bank(Bay of Saint-Brieuc, NW France) are described based on multibeam echosounder and high-resolution seismic datasets coupled with vibro-core data. The Horaine Bank shows large-scale bedforms in the lee of a submerged rocky shoal, which allowed defining it as a Banner Bank.The internal structure of the sandbank reveals four seismic units(U1–U4) on a Cambrian basement(U0). The basal unit U1 is interpreted as reworked lowstand fluvial sediments those infilled micro incised valleys during a rise in sea level. This unit is overlain by paleo-coastal barrier sand-spit(U2) whose development was controlled by swell in the context of a rapid rise in sea level. The successive prograding unit(U3) is interpreted as flooding deposits in continuity with unit U2. The unit U4 is characterized by oblique reflectors oriented in two opposite directions. This last unit, dated post 3500 yr BP, corresponds to migrating dunes superimposed on the bank and observable in the high-resolution bathymetric data. The strong correlation between tidal currents and the apparent clockwise migration of dune crests suggests the presence of a tidal gyre controlling the present-day dynamics of most of the Horaine bank dunes. This study proposes a new model for the construction of banner banks characterized by the gradual transition of a sand spit to a banner bank during marine transgression and ensuing hydrodynamic variability.     

Disaster risk reduction on non-sovereign islands: La Réunion and Mayotte,France

The Islands of Réunion and Mayotte are French territories in the Indian Ocean and are prone to numerous and recurrent hazards as well as to increasing vulnerabilities. This paper examines disaster risk reduction on non-sovereign islands through the case studies of Réunion and Mayotte. The approach used is embedded in standard geographical approaches to risk analysis, focusing on place-based vulnerability, in order to understand disaster risk and disaster risk reduction on both islands. In addition to establishing baseline information and visiting both islands for further data, 21 semi-structured individual interviews were completed to understand the people’s perceptions of the hazards and of their vulnerabilities. Disaster risk reduction strategies, and attitudes from governing bodies implementing the strategies, tend to assume similar vulnerability contexts as mainland France, despite obvious differences on the islands. Many policies are implemented in a top–down manner by those from mainland France who have little interest in, and who do not fully take into consideration, local realities. This paper contributes new case studies to the literature, especially in comparing two non-Anglophone non-sovereign islands, and reinforces recommendations factoring in local contexts when addressing ‘vulnerability of a place’ to disasters.     

Improved barometric and loading efficiency estimates using packers in monitoring wells

Measurement of barometric efficiency (BE) from open monitoring wells or loading efficiency (LE) from formation pore pressures provides valuable information about the hydraulic properties and confinement of a formation. Drained compressibility (α) can be calculated from LE (or BE) in confined and semi-confined formations and used to calculate specific storage (S _s). S _s and α are important for predicting the effects of groundwater extraction and therefore for sustainable extraction management. However, in low hydraulic conductivity (K) formations or large diameter monitoring wells, time lags caused by well storage may be so long that BE cannot be properly assessed in open monitoring wells in confined or unconfined settings. This study demonstrates the use of packers to reduce monitoring-well time lags and enable reliable assessments of LE. In one example from a confined, high-K formation, estimates of BE in the open monitoring well were in good agreement with shut-in LE estimates. In a second example, from a low-K confining clay layer, BE could not be adequately assessed in the open monitoring well due to time lag. Sealing the monitoring well with a packer reduced the time lag sufficiently that a reliable assessment of LE could be made from a 24-day monitoring period. The shut-in response confirmed confined conditions at the well screen and provided confidence in the assessment of hydraulic parameters. A short (time-lag-dependent) period of high-frequency shut-in monitoring can therefore enhance understanding of hydrogeological systems and potentially provide hydraulic parameters to improve conceptual/numerical groundwater models.     

Flood-prone area mapping using machine learning techniques: a case study of Quang Binh province,Vietnam

Natural Hazards - Vietnam’s central coastal region is the most vulnerable and always at flood risk, severely affecting people’s livelihoods and socio-economic development. In...     

Lithostratigraphy and depositional environment of the Permian Nowra Sandstone in the southwestern Sydney Basin,Australia

Lithofacies in the mid‐Permian Nowra Sandstone indicate a middle/upper shoreface to foreshore environment of deposition under the influence of storm‐generated waves and north‐northeasterly directed longshore currents. Palaeogeographic reconstruction for the Nowra Sandstone portrays a sand‐dominated high energy shelf and offshore shoal forming a sequence thickening seaward away from the western shore of the Sydney Basin. The shoal‐crest at the outer edge of the shelf trends north‐northeast. It is characterized by fine‐ to medium‐grained sandstone with upper flow regime structures and a high proportion of conglomerate, whereas coarser sandstone with lower energy bedforms occurs along the seaward side of the shoal. In the deeper water to the east, the lower Nowra Sandstone becomes rapidly thinner as it passes seaward, via bioturbated storm redeposited sandstone beds, into the shelf deposits of the Wandrawandian Siltstone. This sequence accumulated during a regressive event and the base of the formation becomes progressively younger eastward. The sand may have been supplied by rivers along the western coast but the major source was south of the study area. The lower Nowra Sandstone is separated from the upper part of the formation by an extensive ravinement surface overlain by the Purnoo Conglomerate Member. In contrast to the lower unit, the upper Nowra Sandstone forms a westward thickening wedge that represents a backstepping nearshore sand facies that accumulated during a transgression. The upper Nowra Sandstone passes vertically and laterally eastward into the Berry Siltstone. Thus both boundaries of the Nowra Sandstone are diachronous, first younging eastward and then westward as a response to a regressive‐transgressive episode.     

A Pliocene mega-tsunami deposit and associated features in the Ranquil Formation,southern Chile

An exceptionally large tsunami affected the coastline of southern Chile during the Pliocene. Its backflow eroded coarse beach and coastal dune sediments and redistributed them over the continental shelf and slope. Sandstone dykes and sills injected from the base of the resulting hyperconcentrated flow into underlying cohesive muds, assisted in plucking up large blocks of the latter and incorporating them into the flow. Locally, the rip-up intraclasts were fragmented further by smaller-scale injections to form a distinct breccia of angular to rounded mudstone clasts within a medium to coarse sandstone matrix. Sandstone sills in places mimic normal sedimentary beds, complete with structures resembling inverse gradation, planar laminae, as well as ripple and trough cross-lamination. These were probably formed by internal sediment flow and shear stress as the semi-liquefied sand was forcefully injected into cracks. In borehole cores, such sills can easily be misinterpreted as normal sedimentary beds, which can have important implications for hydrocarbon exploration.