High-resolution Echo-sounding and Detection of Embedded Archaeological Objects with Nonlinear Sub-bottom Profilers

Sub-bottom profilers based on nonlinear acoustics offer many advantages especially for detecting and locating embedded objects in shallow waters. They have a narrow beam in spite of small transducers and virtually no side lobes. It is possible to realize mobile low-frequent sub-bottom profilers, which transmit very short sound pulses. Excellent vertical as well as horizontal resolutions at reasonable penetrations are proven benefits of using this technique. In this paper some technical aspects are discussed and a new experimental nonlinear scanning sub-bottom profiler system is described. Results from a field trial in archaeological prospection are shown to illustrate the successful application in practice.     

The flux of particulate material through a well-mixed estuary

The flux of suspended particulate material across the mouth of a well-mixed estuary was measured over 12 months. Samples were taken over one neap and one spring tidal cycle each month and analysed for total suspended particulate material, inorganic and organic particulates, particulate organic carbon and particulate organic nitrogen. Water volume transport at discrete time-steps were determined by means of a one-dimensional hydrodynamic model, calibrated for each tidal cycle sampled. Net transport varied between tidal cycles with regard to direction (import or export) and magnitude. Annual budgets revealed a net export of 5306 tonne of total suspended particulate material (3900 tonne of inorganic particulates, 1286 tonne of particulate organic carbon and 120 tonne of particulate organic nitrogen). The sources of particulate organic carbon are mainly from saltmarshes (194 g POC m²y¹) and from intertidal invertebrate production (586 g POC m⁻²y⁻¹).     

U-Pb zircon and Sm-Nd model ages of high-grade Moldanubian metasediments,Bohemian Massif,Czechoslovakia

We report single grain U-Pb ion-microprobe as well as conventional bulk size fraction ages for zircons from 3 metasediment samples of the Moldanubian Complex, Bohemian Massif, one of the largest crystalline complexes of the Hercynian foldbelt in Europe. These are complemented by whole-rock Sm-Nd model ages. The metasediments are of upper amphibolite to granulite grade and come from the Bory Massif in Moravia, NW of Brno (sample AA-1) and from the Varied Group (AA-2) and Monotonous Group (AA-3) in the Ceske Budejovice region of SW Bohemia.Ion-microprobe data for detrital zircons yielded ²⁰⁷Pb/ ²⁰⁶Pb ages between ca. 1750 Ma and 2680 Ma and reflect chronologically heterogeneous source terrains. One grain in sample AA-1 of the Bory granulite massif may be as old as 2684±14 Ma, and this constitutes the oldest reported zircon age for the Hercynian belt of central Europe. The single grain data are much less discordant than previously published conventional U-Pb analyses from bulk zircon samples and suggest a significant early Proterozoic crust-formation event between 2 and 2.2 Ga ago. The size fraction data are compatible with the single grain ages and give a fairly precise definition of the Hercynian event between 347 and 367 Ma ago while their upper Concordia intercept ages between 1700 and 2050 Ma represent the mean of the respective grain populations and are probably geohronologically meaningless. The Nd whole-rock model ages between 1.7 and 3.0 Ga confirm mid-Proterozoic to Archaean source terrains for the dated metasediments.     

Managing Bay and Estuarine Ecosystems for Multiple Services

Managers are moving from a model of managing individual sectors, human activities, or ecosystem services to an ecosystem-based management (EBM) approach which attempts to balance the range of services provided by ecosystems. Applying EBM is often difficult due to inherent tradeoffs in managing for different services. This challenge particularly holds for estuarine systems, which have been heavily altered in most regions and are often subject to intense management interventions. Estuarine managers can often choose among a range of management tactics to enhance a particular service; although some management actions will result in strong tradeoffs, others may enhance multiple services simultaneously. Management of estuarine ecosystems could be improved by distinguishing between optimal management actions for enhancing multiple services and those that have severe tradeoffs. This requires a framework that evaluates tradeoff scenarios and identifies management actions likely to benefit multiple services. We created a management action-services matrix as a first step towards assessing tradeoffs and providing managers with a decision support tool. We found that management actions that restored or enhanced natural vegetation (e.g., salt marsh and mangroves) and some shellfish (particularly oysters and oyster reef habitat) benefited multiple services. In contrast, management actions such as desalination, salt pond creation, sand mining, and large container shipping had large net negative effects on several of the other services considered in the matrix. Our framework provides resource managers a simple way to inform EBM decisions and can also be used as a first step in more sophisticated approaches that model service delivery.     

Routine analysis of sediment pore water of high ionic strength

Pore water of sediments plays an important role in aquatic systems as mediator and as the reactive zone between the sediment and surface water. Sediment pore waters with high ionic strength from acidified pit lakes were investigated to obtain information about the influence on the lake water quality. The analysis of soluble reactive phosphorus, nitrate, ammonium, silica, dissolved organic carbon, ferrous iron, sulfate, chloride, sodium, potassium, calcium, magnesium, manganese, and total dissolved iron was predetermined as the dataset required for evaluation of water quality. The data collection procedure was optimised by designing a methodology for stabilisation, dilution of pore water samples and adaptation of analytical methods. The developed methodology was evaluated with respect to the effort required in the laboratory under routine conditions. In the first round of analyses, 72% of 638 individual analyses from a random selection of pore water profiles were found to be within the calibration ranges. Remedial actions to handle the remaining 28% of invalid analytical results are exemplified. Differences between comparative analyses of some ions by continuous flow analysis, ion chromatography, and atomic emission spectroscopy were evaluated. The majority of results measured by ion chromatography differed on a highly significant level from results measured by atomic emission spectroscopy. Possible reasons, originating from the extreme sample matrix, are discussed. Finally, the designed methodology and the results of the method comparison are used to recommend the selection of analytical methods under specific conditions.     

A three-dimensional UPb discordia plane to evaluate samples with common lead of unknown isotopic composition

The concordia method introduced by G.W. Wetherill or in a modified fashion by F. Tera and G.J. Wasserburg, which can only be applied to the radiogenic leead fraction of U-containing minerals, can be extended to the measured total Pb isotope ratios by a three-dimensional discordia plane. The three-dimensional model does not require knowledge of the isotope ratios of the common Pb used for correction if the assumption of only one type of common Pb (with an a priori unknown isotopic composition) for the investigated samples is justified. The theory is derived and formulae for calculation of best-fit plane parameters as well as for their errors are derived. With one synthetic set of data the applicability of the method is demonstrated.