不同氧化锰矿物对光催化降解苯酚的影响

合成层状结构的酸性和碱性水钠锰矿以及隧道结构的锰钾矿和钙锰矿,将其用于苯酚的光催化降解研究。分别采用X射线衍射(XRD)、原子吸收光谱(AAS)、扫描电镜(SEM)、BET氮气吸附法和紫外可见漫反射光谱(UV-Vis DRS)对供试锰氧化物的晶体结构、化学组成、微观形貌、比表面积以及光吸收性能等进行了表征。研究表明,暗反应条件锰氧化物对苯酚的降解作用较弱,而UV-Vis光照能显著促进锰氧化物对苯酚的降解。光照反应12 h后,锰钾矿、酸性水钠锰矿、钙锰矿以及碱性水钠锰矿的苯酚降解率分别为92.1%、77.3%、57.4%和45.8%;对应的TOC去除率分别由暗反应时的6.3%、11.2%、2.0%和4.6%提高至62.1%、43.1%、25.4%和22.5%。4种供试锰氧化物均具有光催化活性,其大小顺序为:锰钾矿>酸性水钠锰矿>钙锰矿>碱性水钠锰矿。UV-Vis光照下氧化锰矿物光化学降解苯酚主要存在3种降解机制———苯酚的直接光解,锰氧化物的化学氧化和锰氧化物的光化学催化,其中光催化降解起主导作用。     

碎屑锆石对班公湖地区晚侏罗世-早白垩世沉积物源的制约

本文对班公湖地区中生代沙木罗组（J3—K1s）和日松组（J3r）地层的碎屑锆石进行了形态学及U-Pb年代学的研究。结果表明：锆石颗粒粒径约为100～150 μm,内部结构清晰,晶体为长柱状,自形程度较高,多数锆石不含暗色包体及浑圆形内核; 有些锆石颗粒有扇型分带结构。Th/U比值较大,多数大于0.1,均值约为0.86,说明岩浆的成因以锆石为主体,部分颗粒或晶体可能为变质成因; 锆石年龄主要分布在6个区间范围内： 1）180～100 Ma, 2）350～180 Ma, 3）600～450 Ma, 4）1100～600 Ma, 5）1800～1400 Ma, 6）2200～1800 Ma。锆石U-Pb年龄谱对应了羌塘地块经历的几次构造热事件,验证了晚侏罗世—早白垩世班公湖地区的物源主要来自其北部的羌塘地块。     

福建武平地区桃溪群混合岩U-Pb定年及其Hf同位素组成:对桃溪群时代及郁南运动的约束

桃溪群混合岩位于南岭东段武夷山褶皱带南段.本文通过采自桃溪附近帽村-田园两个代表性花岗片麻岩样品进行LA-ICP-MS锆石U-Pb 测年获得494～496Ma的结晶年龄,641～657Ma和799Ma两组继承锆石的206Pb/238U 表观年龄.同时对样品FJ-137进行的Hf同位素测定表明其εHf(t)变化于-2.3...     

江南隆起带中段新元古代花岗岩锆石U-Pb年代学和Hf同位素组成研究

对江南隆起带中段湘东西园坑岩体和赣西九岭岩体的LA-ICPMS锆石U-Pb年代学测定和LA-MC-ICPMS锆石Hf同位素原位分析测试表明:西园坑岩体形成于(804±3)Ma,赣西九岭岩体的年龄为(813±4)Ma和(823±2)Ma,均为新元古代花岗岩.上述三个样品的εHf(t)的加权平均值分别为0.68±0.71,...     

塔里木盆地柯坪地区奥陶系鹰山组台内滩储层地层特征对比研究:以石灰窑和大湾沟剖面为例

塔里木盆地碳酸盐岩礁滩体储层已经成为当前油气勘探的热点.以塔里木盆地柯坪地区石灰窑和大湾沟露头剖面为例,对奥陶系鹰山组台内滩地层的岩相组成及层序地层特征两个方面进行深入对比研究,并在此基础上分析了碳酸盐岩台内滩地层发育的控制因素.结果表明:(1)石灰窑地区和大湾沟地区鹰山组地层发育特征存在差异,石灰窑剖面以薄层颗粒灰岩...     

基于城市化的中国能源消费前景分析及对碳排放的相关思考

工业化和城市化是中国未来的两大发展趋势.以往对中国未来能源消费及碳排放的预测大都是从工业化层面出发,忽略了城市化过程导致的生活能源消费的巨大增量.推动城市化进程是提升生活质量、满足人的基本权利的重要手段;立足城市化进程,保障人均能源消费及碳排放空间是确保人人享有基本的生存权和发展权的重要基础.从对中国城市化进程的发展态...     

Development of 57 novel polymorphic microsatellite markers in half-smooth tongue sole (Cynoglossus semilaevis)

Half-smooth tongue sole (Cynoglossus semilaevis) is a promising species for aquaculture in China.The wild population of C. semilaevis is under threat from environmental factors. Microsatellite markers are very suitable for assessing genetic diversity. Four microsatellite-enriched libraries of half smooth tongue sole (Cynoglossus semilaevis) were constructed,from which 57 polymorphic microsatellites were isolated and characterized.The polymorphism of these microsatellites was assessed by genotyping in 30 ind...     

基于信息量模型的玉树地震次生地质灾害危险性评价

2010-04-14发生在青海省玉树的Ms7.1级地震引发了大量的地质灾害.基于GIS技术和信息量模型方法,以坡度、坡向、高程、坡形、地貌类型、断层距和地层岩性为评价因子,通过空间分析计算各因子的信息量,分析地质灾害在各因子中的空间分布特征,对各评价因子图层进行空间建模,将获取的信息量图划分为高度、中度、轻度三级危险区,通过遥感解译研究区实际滑坡分布,与危险性分布图叠加表明:本次研究得出的危险等级与实际的滑坡发生情况相吻合,为灾区重建提供参考依据.     

汶川地震灾后重建地区的人口容量分析

Assessment of population carrying capacity is a key task in the reconstruction planning of areas struck by disasters, in which the precision of estimation is required. This study developed a decision-making model for estimating the population capacity of the involved townships and cities in the 2008 Wenchuan Earthquake based on the assessment of the suitability for reconstruction of the areas. Through analysis, arable land resources were argued to be the critical constraint of population capacity in these areas. Then, the spatial differentiations of the post-quake development conditions across different regions were analyzed with respect to their natural environments, socio-economic development and quake damages. The expected levels of urbanization, family incomes and income structures, output levels of land, and the reliance of agricultural population on arable land were estimated by different regions. With these parameters, the population capacities of the involved townships and cities in three scenarios were estimated. The total population capacity of the entire areas is abundant compared with the actual post-quake population; however, the status of over-population substantially varies across space. It was suggested to put the emphasis of post-quake resettlement policy on those counties where earthquake had been the main causes of over-population. In the Full Recovery Scenario, three mountain counties were identified including Wenchuan, Beichuan and Maoxian, with a total over-population of about 100,000 people.     

真鲷（Pagrus major）vasa基因5′端启动子克隆及表达载体构建

采用染色体步移（Genome walking）的方法克隆了真鲷vasa基因5′侧翼序列,采用生物信息学方法分析潜在的顺式作用元件,并与斑马鱼核心启动子进行比对,在此基础上构建了绿色荧光蛋白表达载体。序列分析结果显示：克隆得到的真鲷vasa基因5′侧翼序列序列长度为2762bp,其中包括TATA-box、CAAT-box...