Retrograde fluids in the Archean Shawmere anorthosite, Kapuskasing Structural Zone, Ontario, Canada

The Archean Shawmere anorthosite lies within the granulite facies portion of the Kapuskasing Structural Zone (KSZ), Ontario, and is crosscut by numerous linear alteration veins containing calcite + quartz ± dolomite ± zoisite ± clinozoisite ± margarite ±paragonite ± chlorite. These veins roughly parallel the trend of the Ivanhoe Lake Cataclastic Zone. Equilibria involving clinozoisite + margarite + quartz ± calcite ± plagioclase show that the vein minerals were stable at T < 600 °C, XCO₂ < 0.4 at P ≈ 6 kbar. The stabilities of margarite and paragonite in equilibrium with quartz are also consistent with T < 600 °C and XCO₂ < 0.4 at 6 kbar. Additional assemblages consisting of calcite + clinochlore + quartz + talc + margarite indicate T < 500 °C with XCO₂ > 0.9. Thus, vein formation, while clearly retrograde, spanned a range of temperatures, and fluid compositions evolved from H₂O-rich to CO₂-rich. The calcite in the retrograde veins has δ¹⁸O values that range from 8.4 to 11.2‰ (average = +9.7 ± 0.9‰) and δ¹³C values that range from −3.9 to −1.6‰ (average = −3.1 ± 0.6‰). These values indicate that the fluids from which calcite precipitated underwent extensive exchange with the anorthosite and other crustal lithologies. The fluids may have been initially derived either from devolatilization of metamorphic rocks or crystallization of igneous rocks in the adjacent Abitibi subprovince. Vein quartz contains CO₂-rich fluid inclusions (final melting T = −57.0 to −58.7 °C) that range in size from 5 to 17 μm. Measured homogenization temperatures (T h) range from −44.0 to 14.5 °C, however for most inclusions (46 of S1), T h = −44.0 to −21.1 °C (ρCO₂ ≈ 1.13 to 1.05 g/cm³). At 400 to 600 °C, these densities correspond to pressures of 3.5 to 7 kbar, which is the best estimate of pressures of vein formation. It has been argued that some high density CO₂-rich fluid inclusions found in the KSZ were formed during peak metamorphism and thus document the presence of a CO₂-rich fluid during peak granulite facies metamorphism (Rudnick et al. 1984). The association of high density CO₂-rich fluid inclusions with clearly retrograde veins documents the formation of similar composition and density inclusions after the peak of metamorphism. Thus, the coincidence of entrapment pressures calculated from fluid inclusion density measurements with peak metamorphic pressures alone should not be considered strong evidence for peak metamorphic inclusion entrapment. All fluid inclusion results are consistent with an initially semi-isobaric retrograde P–T path. Received: 2 April 1996 / Accepted: 15 November 1996     

The Development of Laser Ablation ICP-MS and Calibration Strategies: Examples from the Analysis of Trace Elements in Volcanic Glass Shards and Sulfide Minerals

This contribution presents a review of the recent developments in laser ablation inductively coupled plasma-mass spectrometry. We describe the important developments which have occurred in the laser systems used, leading to a spatial resolution of around 20 (im, and give an overview of the major instrument developments which have affected the geological applications of laser ablation ICP-MS. We describe the calibration of laser ablation for the analysis of trace elements in two different matrices: volcanic glass shards and sulfide minerals. We show how single glass shards can be analysed using the National Institute of Standards and Technology (NIST) glass certified reference materials for calibration and demonstrate the effect of using single spot analyses compared to rastering of the calibration sample. We show the importance of inter-shard variation and demonstrate that averaged single shard analyses produce data which compare well with bulk analyses. The calibration of the laser system for sulfide mineral analysis is discussed and two different strategies are proposed, one using spiked pressed powder pellets of sulfides and the other metal reference materials. We present conclusions and recommendations for the calibration of laser ablation ICP-MS instruments.     

Depositional history and stratigraphical evolution of the Sakoa Group (Lower Karoo Supergroup) in the southern Morondava Basin, Madagascar

The Sakoa Group is the lowermost stratigraphical succession of the Karoo Supergroup and the oldest sedimentary unit in Madagascar, spanning the Late Carboniferous through Early Permian epochs. The Sakoa Group is exposed in the southern Morondava Basin. It is predominantly a siliciclastic sequence comprising seven lithofacies associations: (1) diamictites; (2) conglomeratic sandstones; (3) sandstones; (4) interbedded thin sandstones and mudstones; (5) mudstones; (6) coals; and (7) limestones. These facies represent deposition in the early extensional stages of continental rift development. The sediments were deposited predominantly on alluvial fans, and in braided to meandering stream and overbank environments. Locally lacustrine and coal swamp environments formed in low areas of the basin floor during rift initiation. Subsidence rates remained fairly constant throughout the Early Permian and were accompanied by a gradual reduction in relief of the basin margins and an increased geomorphic maturity of the fluvial systems flowing across the basin floor. Near the end of the Early Permian the southern Morondava Basin was inundated by a marine transgression , which resulted in deposition of the Vohitolia Limestone. Subsequent tectonic uplift and erosion resulted in a regional unconformity between the Sakoa Group and the overlying Sakamena Group.     

北祁连造山带东段老虎山石英闪长岩成因及其地质意义

以北祁连造山带东段老虎山石英闪长岩体为研究对象，进行了锆石U-Pb年龄及全岩元素与Sr-Nd同位素组成的系统 测定，据此探讨了岩石的成因及其对北祁连构造演化的启示。锆石LA-ICP-MS U-Pb定年结果表明，石英闪长岩体的形成 年龄为440 Ma。岩石具有亚碱、准铝以及贫钙、镁、铁的特征，碱铝指数（AKI值） 均低于0.85，铝饱和指数（A/NKC 值） 多小于1.0，属钙碱性I型花岗岩类岩石。在稀土和微量元素组成上，岩石富集轻稀土和大离子亲石元素（如Rb、Cs、 Th和U），亏损高场强元素（如Nb和Ta），显示弧岩浆岩的地球化学特征。岩体具有相对均一的Sr-Nd同位素组成，初始Sr同 位素值为0.7058~0.7071，εNd(t)值为-1.06~-0.31。综合分析表明，老虎山石英闪长岩应起源于玄武质下地壳物质的部分熔 融，并在成岩过程中有少量幔源物质的混入。对区内火成岩地质地球化学特征与产出背景的全面分析，表明受北祁连洋俯 冲及随后岛弧与祁连—柴达木陆块碰撞拼贴影响，弧后盆地的北向俯冲消减作用可能是诱发民乐窑沟和老虎山弧岩浆岩以 及导致毛藏寺—老虎山花岗岩带内埃达克质岩石侵位的基本动力机制。