An ion-association model for PbO-SiO2 melts: interpretation of thermochemical,conductivity, and density data

We propose that within PbO-SiO₂ melts the component species PbO(1) and SiO₂(1) associate to form a lead orthosilicate complex [Pb₂SiO₄(1)] according to $\text{2PbO(1) + SiO}{}_2\text{(1)}\text{a}\text{?}\text{f Pb}{}_2\text{SiO}{}_4\text{(1)}$ The association constant (K) for the above reaction is near 30 at 900 and 1000°C On the premises that the enthalpy of the above reaction is the only contributor to the enthalpy of mixing and that three melt species [PbO(1), SiO₂(1), Pb₂SiO₄(1)] mix ideally (Raoult's Law obeyed), the partial molar properties and the integral mixing properties of the melt have been calculated and have been found to accurately reproduce the measured thermochemical data.The conductivity data and density data for PbO-SiO₂ melts have been calculated using the association model. The calculated data again are remarkably consistent with the experimental data.Other silicate-melt models have been reinterpreted and that of Toop and Samis is compatible with the proposed model. In fact the Toop and Samis model implicitly assumes the formation of orthosilicate species rather than condensed polymeric species.     

The impact of drilling fluid and well cuttings on polychaete feeding guilds from the US northeastern continental shelf

The effect of recent drilling operations (fluid and well cuttings) on polychaete feeding guilds from the continental shelf off Atlantic City, New Jersey, was examined. Although there were some adverse effects on macrobenthos from 2160 metric tons of cuttings and mud solids discharged into the marine environment, the composition of polychaete feeding guilds remained essentially unchanged. This key trophic relationship between polychaetes and the changing environment due to the drilling operation was apparently uninterrupted. This relationship remains to be examined in other natural and perturbed habitats.     

Evidence of the terdiurnal,S 3, atmospheric tide in the surface wind field over the ocean

Surface winds were measured from anchored buoys at the corners of a 100-km triangle in the Atlantic ocean for three weeks in September 1972. The measurements were part of the British Royal Society Joint Air-Sea Interaction Project, JASIN-72. Peaks were found at a frequency of 0.125 cph (8-h period) in various wind statistics, indicating the presence of the terdiurnal, S ₃, component of the atmospheric tides that had previously been extensively studied because it is a prominent component in surface air-pressure records.     

Ore transport and deposition in the Red Sea geothermal system: a geochemical model

Thermodynamic calculation of distribution of dissolved aqueous species in the Red Sea geothermal brine provides a model of ore transport and deposition in good agreement with observed accumulations of base metal sulfides, anhydrite, and barite.The Red Sea brine is recirculated seawater that acquires high salinity by low-temperature interaction with Miocene evaporites and is subsequently heated to temperatures in excess of 200°C by interaction with recent rift zone intrusive rocks. At temperatures up to 250°C, NaSO^?₄ and MgSO⁰₄ are the dominant sulfur-bearing species. H₂S forms by inorganic sulfate reduction at the higher temperatures but is maintained at a uniform concentration of about 2 ppm by the strength of the sulfate complexes.Chloride complexes solubilize metals at the higher temperatures, and thus sulfide and metals are carried together into the Atlantis II Deep. Below 150°C, the brine becomes supersaturated with respect to chalcopyrite, sphalerite, galena, and iron monosulfide due to chloride-complex dissociation. Sulfide precipitation rates, based on the rate of brine influx, are in good agreement with measured sedimentation rates. Anhydrite precipitates as crystalline fissure infillings from high-temperature inflowing brine. Barite forms from partial oxidation of sulfides at the interface between the lower hot brine and the transitional brine layer.     

Dating climatic episodes of the Holocene

Monitoring evidence indicates that the Holocene embraced a sequence of rather discrete climatic episodes. The transitions between these environmental episodes apparently were abrupt and globally synchronous. This paper reports on statistical analyses of radiocarbon dates associated with environmental change and cultural change.Over 800 ¹⁴C dates associated with pollen maxima and minima, sea level maxima and minima, and top and bottom surfaces of peat beds were simultaneously analyzed to identify times of globally synchronous environmental discontinuities.Some 3700 ¹⁴C dates associated with 155 cultural continua of the world were collectively analyzed to identify worldwide synchroneities in appearance and termination of the cultures.Significant globally synchronous discontinuities were identified in each independent analysis. The dates of environmental and cultural discontinuities are rather similar, particularly during the recent half of the Holocene. The fact that the cultural discontinuities mostly follow rather closely those of the paleobotanical record suggests that there has been a distinct climatic impact on the cultural history of man.     

The day-to-day monitoring of the 2011 severe drought in China

Dry/wet condition has a large interannual variability. Decision-makers need to know the onset, duration, and intensity of drought, and require droughts be monitored at a daily to weekly scale. However, previous tools cannot monitor drought well at this short timescale. The Palmer Drought Severity Index has been found dissatisfactory in monitoring because of its complexity and numerous limitations. The Standardized Precipitation Index (SPI) always asks for a timescale, and precipitation is averaged over the period of the scale. Because of this, the SPI cannot be used for short scales, e.g., several days, and what it tells is the overall drought situation of the period. The weighted average of precipitation (WAP) developed by Lu (Geophys Res Lett 36:L12707, 2009) overcomes the deficiency of the SPI; it does not require a timescale, and can provide the drought (and flood) extent of each day. Therefore, the WAP can monitor drought at scales from daily to weekly, monthly, and any longer scale, and is really “flexible and versatile for all timescales”. In this study, the standardized WAP (SWAP) is used to monitor the 2011 drought over China. Drought swept the country during the year from north to south and from east to west. In spring, a once-in-a-fifty-year drought occurred over the Yangtze River basin and the southern region, causing serious shortage of drinking water for people and livestock, as well as tremendous losses in agriculture and the shipping industry. Results show that the SWAP, with its monthly mean plots, can well reproduce the seasonal shift of the 2011 drought across the country. The animation of daily plots demonstrates that the SWAP would have been able to monitor the day-to-day variation of the spring drought around the Yangtze River basin. It can provide the details of the drought, such as when the drought emerged over the region, how long it maintained there (though drought area may move back and forth with extension and contraction of the area), and when the drought relieved over the basin.     

Fluxes of inorganic carbon from two forested catchments in the Appalachian mountains

This study uses long‐term records of stream chemistry, discharge and air temperature from two neighbouring forested catchments in the southern Appalachians in order to calculate production of dissolved CO₂ and dissolved inorganic carbon (DIC). One of the pair of catchments was clear‐felled during the period of the study. The study shows that: (1) areal production rates of both dissolved CO₂ and DIC are similar between the two catchments even during and immediately after the period of clear‐felling; (2) flux of total inorganic carbon (dissolved CO₂+ DIC) rises dramatically in response to a catchment‐wide acidification event; (3) DIC and dissolved CO₂ are dominantly released on the old water portion of the discharge and concentrations peak in the early autumn when flows in the study catchments are at their lowest; (4) total fluvial carbon flux from the clear‐felled catchment is 11·6 t km⁻² year⁻¹ and for the control catchment is 11·4 t km⁻² year⁻¹. The total inorganic carbon flux represents 69% of the total fluvial carbon flux. The method presented in the study provides a useful way of estimating inorganic carbon flux from a catchment without detailed gas monitoring. The time series of dissolved CO₂ at emergence to the stream can also be a proxy for the soil flux of CO₂. Copyright © 2005 John Wiley & Sons, Ltd.     

ACE‐2 multiple angle micro‐pulse lidar observations from Las Galletas, Tenerife, Canary Islands

Multiple‐angle micro‐pulse lidar (MPL) observations were made at Las Galletas on Tenerife, Canary Islands during the Aerosol Characterization Experiment‐2 (ACE‐2) conducted June–July, 1997. A principal objective of the MPL observations was to characterize the temporal/spatial distributions of aerosols in the region, particularly to identify and profile elevated Saharan dust layers which occur intermittently during the June–July time period. Vertical and slant angle measurements taken 16 and 17 July characterize such an occurrence, providing aerosol backscatter, extinction, and optical depth profiles of the dust layer between 1 and 5 km above mean sea level (MSL). Additionally, horizontal measurements taken in Las Galletas throughout the 6‐week period provide a time profile of the varying aerosol extinction at the surface. This profile exhibits the alternating periods of clean maritime air and pollution outbreaks that typified the region. Horizontal measurements also provide some evidence suggesting the possible influx of Saharan dust from the free troposphere to the surface. This paper presents estimates of aerosol optical properties retrieved from the multi‐angle MPL measurements in addition to an outline of the methodologies employed to obtain these results.