Comparison of Michigan Basin crude oils

Michigan Basin oils from the Ordovician Trenton, Silurian Niagaran, and Devonian Dundee formations have been geochemically compared by GC, GC-MS, and carbon isotope mass spectrometry. One oil from each formation was selected for detailed analysis which included measurement of individual n-alkane δ¹³C values. The Ordovician and Devonian oils are strikingly similar to one another, yet clearly different from the Silurian oil. This pattern is unexpected because Ordovician and Devonian reservoirs are physically separated by the Silurian strata. From time-temperature considerations, the Devonian oil probably was formed in older strata and has migrated to its present location. Our analyses suggest a common source for the Devonian and Ordovician oils.     

Extraction of agar from Eucheuma cottonii and Gelidium amansii seaweeds with sonication pretreatment using autoclaving method

The effect of sonication pretreatment condition on Eucheuma cottonii and Gelidium amansii seaweed towards agar extraction wae studied.Four parameters were changed during sonication to investigate the effects on agar yield and quality.These parameters include the time interval,concentration ratio,frequency,and intensity.The highest amount of agar extracted from Eucheuma cottonii species could be obtained from the time interval of 30min,seaweed weight to solvent volume ratio of 1:20,the frequency of 35Hz,and the sonication power intensity of 30%.For Gelidium amansii species,the best agar yield also could be obtained from the time interval of 30 min,1:20 of seaweed weight to water volume ratio,the frequency of 35Hz,and power intensity of 30%.From the experiment,sonication pretreatment signifi cantly influenced the yield and properties of extracted agar.The sonication with autoclaved seaweed produced agar containing less sulfate content,which is an excellent chemical property for gel electrophoresis applications.The gelstrength of sonication with autoclaving for both seaweeds,Eucheuma and Gelidium species was the highest among those by sonication with direct heating,which proved that sonication pretreatment with autoclaving could enhance the physical properties of the agar.     

Comparison of ground- and aerial-based approaches for quantifying polygonal terrain network geometry on Earth and Mars via spatial point pattern analysis

Recently, a particular statistical method - spatial point pattern analysis (SPPA) - has been introduced as an effective means by which qualitative, observable variations in polygonal terrain network arrangements on Earth and Mars can be quantified. A number of ground- and aerial-based techniques are available from which to derive the required input data: the spatial (x-y) coordinates of all polygon trough intersections within the site. However, each of the data collection methods may contain some level of error. Thus, the overarching question addressed by this research is: “how are the results of SPPA affected by the method by which the input data were generated?” At two polygonal terrain sites in the Canadian High Arctic, we performed ground-based surveys using differential and non-differential Global Positioning Systems (GPS) as well as photogrammetric analysis of aerial and satellite images of varying resolution to determine the trough intersection coordinates. It was found that the most robust statistical results were produced when using data from a combination of differential GPS surveys and high-resolution (∼0.25 m/pixel) aerial images. Images of pixel size ≥1 m were found to be unsuitable for this type of analysis. With respect to the investigation of similar Martian landforms, HiRISE and MOC images of polygonal terrain sites in southwestern Utopia Planitia were analyzed. Our results show that it is strongly preferable to perform SPPA using HiRISE images, though an empirical model is outlined that could be used to correct for errors arising from the reduced resolution inherent to MOC images.     

Use of a bubble tiltmeter as a horizontal seismometer

Summary. A bubble tiltmeter has been used as a horizontal seismometer. With the appropriate filters, the bubble system has good response for displacement over the passband of conventional seismometers (from about 10 Hz to 200 s), and for tilt from about 1 Hz to DC. The accuracy of the response is confirmed by comparing the filtered bubble output to conventional seismic instruments. The agreement between the filtered bubble records and broad band ( T ₀= 1 s, T _g= 90 s) and short period ( T ₀= 1 s, T_g= 0.2 s) conventional records is extremely good in every case.
The small size, broad-band response, and lack of moving parts make the bubble ideal as an instrument for remote environments. In particular, the instrument seems ideal for the ocean bottom, land and marine boreholes and planetary missions.     

Petrology of the Permian Yellow Sands of northeastern England and their North Sea Basin equivalents

The Permian Yellow Sands of northeastern England and the Permian Weissliegendes of the English North Sea Basin are petrologically defined as multicycle, moderately sorted, subrounded graywackes, subgraywackes and subarkoses with post-depositionally etched and overgrown grains. These sandstones were derived by the marine reworking of the Permian Rotliegendes and transported from the east to the southwest. Petrologic data show that these Upper Permian sandstones were deposited in a shallow marine environment and that the commonly held aeolian dune interpretation for them should be rejected. Their formation during the transgression of the Zechstein Sea places them within the Zechstein sequence and therefore they are Thuringian in age rather than Saxonian.     

Extraction of agar from Eucheuma cottonii and Gelidium amansii seaweeds with sonication pretreatment using autoclaving method

The effect of sonication pretreatment condition on Eucheuma cottonii and Gelidium amansii seaweed towards agar extraction wae studied. Four parameters were changed during sonication to investigate the effects on agar yield and quality. These parameters include the time interval, concentration ratio, frequency, and intensity. The highest amount of agar extracted from Eucheuma cottonii species could be obtained from the time interval of 30 min, seaweed weight to solvent volume ratio of 1:20, the frequency of 35 Hz, and the sonication power intensity of 30%. For Gelidium amansii species, the best agar yield also could be obtained from the time interval of 30 min, 1:20 of seaweed weight to water volume ratio, the frequency of 35 Hz, and power intensity of 30%. From the experiment, sonication pretreatment significantly influenced the yield and properties of extracted agar. The sonication with autoclaved seaweed produced agar containing less sulfate content, which is an excellent chemical property for gel electrophoresis applications.The gel strength of sonication with autoclaving for both seaweeds, Eucheuma and Gelidium species was the highest among those by sonication with direct heating, which proved that sonication pretreatment with autoclaving could enhance the physical properties of the agar.     

Optimum distance model of relaxation around substitutional defects

The relaxation patterns around isovalent substituent atoms in the NaCl, CsCl, ZnS, CaF₂, Li₂O, and ReO₃ structure types have been calculated. Such models (1) emphasize geometric structural criteria and are thus conceptually simple, (2) are computationally straightforward though perhaps computer-time consuming for large, low symmetry cases, and (3) agree reasonably well with more complex calculations, such as energy minimization methods. On the basis of such optimum interatomic distance models, atomic displacements resulting from an isovalent substitution: (1) depend strongly on the structural connectivity (structural type) involved, (2) are decidedly greater for atoms with radius vectors parallel to the substituent's bonds and least for atoms with radius vectors oriented between such bonds, (3) decrease in magnitude approximately inversely proportional to the square of the distance to the substituent, regardless of direction, and (4) are mostly, but not strictly, radial. The simplest relationship to structural type is the dependence on the coordination of the substituent's ligands — the greater the coordination number of the atoms bonded to the substituting atom, the less compliant the structure.     

The influence of surface cover and climate on energy partitioning and evaporation in a subarctic wetland

Energy partitioning and evaporation were measured over three wetland surfaces in a subarctic coastal marsh during pre-growing and growing periods. These surfaces included an alder/willow woodland, a sedge marsh and a raised backshore sedge meadow. A combination model analysis was used to assess the relative importance of surface resistance and meteorological conditions on the magnitude of the Bowen ratio, , during the growing period.Overall, the three surfaces experienced important site-to-site and seasonal differences in and evaporation, Q _E. During the non-foliated period, Q _E was largest and was smallest for the open water marsh, while the dry backshore site experienced the smallest Q _E and largest . The non-foliated woodland assumed intermediate values of and Q _E. After the vegetation covers were established, the woodland assumed the smallest and largest Q _E flux. It was also found that at the marsh site increased with the presence of a vegetation cover.Wind direction was always an important factor in determining Q _E and at all sites. was substantially larger and Q _E was smaller for onshore winds (i.e., originating from James Bay) than for offshore winds. The combination model analysis showed that canopy resistance at all sites was largest during warm offshore winds, which were associated with large saturation deficits. However, the effect of increased canopy resistance on during offshore winds was offset by a large climatological resistance, resulting in small values and large Q _E. When winds originated from James Bay, canopy resistance was smaller than for offshore winds, but the climatological resistance also was much smaller, resulting in larger and small Q _E. The results have important implications for changes in land cover and climate on the regional water balance.