Compositional gradients surrounding spherulites in obsidian and their relationship to spherulite growth and lava cooling

Spherical masses of crystal fibers (spherulites) crystalize from rhyolitic melt/glass mainly in response to significant undercooling while lava cools. Spherulite growth should induce compositional gradients in the surrounding glass from expulsion of incompatible constituents and diffusion of those constituents away from the spherulite. Finite-difference numerical modeling of one-dimensional diffusion, in which diffusivities are allowed to vary with temperature, is used to investigate how compositional gradients reflect spherulite growth and lava cooling. Overall, three forms of gradients are identified. Elements that diffuse quickly are expelled from the spherulite but then migrate away too quickly to become enriched at the boundary of the spherulite. Elements that diffuse slowly are trapped within the growing spherulite. Between those endmembers are elements that are not trapped, yet diffuse slow enough that they become enriched at the contact. Their slow diffusion away then elevates their concentrations in the surrounding glass. How enriched those elements are at the spherulite-matrix interface and how far their enrichments extend outwards into the glass reflect how spherulites grow and thermal conditions during growth. Concentrations of H₂O, Rb, F, Li, Cl, Na, K, Sr, Cs, Ba, and Be were measured in and around spherulites in obsidian from a 4.7?±?1?km³ rhyolite lava dome erupted from Tequila volcano, Mexico. Measurable concentration gradients are found for H₂O, Rb, and F. Attributes of those gradients and the behaviors of the other elements are in accord with their experimentally constrained diffusivities. Spherulites appear to have grown following radial, rather than volumetric, growth. The observed gradients (and lack of others) are more consistent with growth mainly below the glass transition, which would necessitate the dome cooling at ca. 10^?5 to 10^?7?°C?s^?1. Such slow cooling is consistent with the relatively large volume of the dome.     

Straight from the source's mouth: Controls on field-constrained sediment export across the entire active Corinth Rift,central Greece

The volume and grain-size of sediment supplied from catchments fundamentally control basin stratigraphy. Despite their importance, few studies have constrained sediment budgets and grain-size exported into an active rift at the basin scale. Here, we used the Corinth Rift as a natural laboratory to quantify the controls on sediment export within an active rift. In the field, we measured the hydraulic geometries, surface grain-sizes of channel bars and full-weighted grain-size distributions of river sediment at the mouths of 47 catchments draining the rift (constituting 83% of the areal extent). Results show that the sediment grain-size increases westward along the southern coast of the Gulf of Corinth, with the coarse-fraction grain-sizes (84^th percentile of weighted grain-size distribution) ranging from approximately 19 to 91 mm. We find that the median and coarse-fraction of the sieved grain-size distribution are primarily controlled by bedrock lithology, with late Quaternary uplift rates exerting a secondary control. Our results indicate that grain-size export is primarily controlled by the input grain-size within the catchment and subsequent abrasion during fluvial transport, both quantities that are sensitive to catchment lithology. We also demonstrate that the median and coarse-fraction of the grain-size distribution are predominantly transported in bedload; however, typical sand-grade particles are transported as suspended load at bankfull conditions, suggesting disparate source-to-sink transit timescales for sand and gravel. Finally, we derive both a full Holocene sediment budget and a grain-size-specific bedload discharged into the Gulf of Corinth using the grain-size measurements and previously published estimates of sediment fluxes and volumes. Results show that the bedload sediment budget is primarily comprised (~79%) of pebble to cobble grade (0.475–16 cm). Our results suggest that the grain-size of sediment export at the rift scale is particularly sensitive to catchment lithology and fluvial mophodynamics, which complicates our ability to make direct inferences of tectonic and palaeoenvironmental forcing from local stratigraphic characteristics.     

Data mining methods for hydroclimatic forecasting

Skillful streamflow forecasts at seasonal lead times may be useful to water managers seeking to provide reliable water supplies and maximize hydrosystem benefits. In this study, a class of data mining techniques, known as tree-structured models, is investigated to address the nonlinear dynamics of climate teleconnections and screen promising probabilistic streamflow forecast models for river–reservoir systems. In a case study of the Lower Colorado River system in central Texas, a number of potential predictors are evaluated for forecasting seasonal streamflow, including large-scale climate indices related to the El Niño–Southern Oscillation (ENSO), Pacific Decadal Oscillation (PDO), North Atlantic Oscillation (NAO), and others. Results show that the tree-structured models can effectively capture the nonlinear features hidden in the data. Skill scores of probabilistic forecasts generated by both classification trees and logistic regression trees indicate that seasonal inflows throughout the system can be predicted with sufficient accuracy to improve water management, especially in the winter and spring seasons in central Texas.     

Determination of Cepheid parameters by light-curve template fitting

We describe techniques to characterize the light curves of regular variable stars by applying principal component analysis (PCA) to a training set of high-quality data, and to fit the resulting light-curve templates to sparse and noisy photometry to obtain parameters such as periods, mean magnitudes etc. The PCA approach allows us to efficiently represent the multiband light-curve shapes (LCSs) of each variable, and hence quantitatively describe the average behaviour of the sample as a smoothly varying function of period, and also the range of variation around this average.
In this paper we focus particularly on the utility of such methods for analysing Hubble Space Telescope ( HST ) Cepheid photometry, and present simulations which illustrate the advantages of our PCA template-fitting approach. These are: accurate parameter determination, including LCS information; simultaneous fitting to multiple passbands; quantitative error analysis; objective rejection of variables with non-Cepheid-like light curves or those with potential period aliases.
We also use PCA to confirm that Cepheid LCSs are systematically different (at the same period) between the Milky Way and the Large and Small Magellanic Clouds, and consider whether LCS might therefore be used to estimate the mean metallicities of Cepheid samples, thus allowing metallicity corrections to be applied to derived distance estimates.     

Spatial comparisons in wetland loss,mitigation, and flood hazards among watersheds in the lower St. Johns River basin,northeastern Florida,USA

Natural Hazards - The objective of this research is to establish a model that characterizes integrated humanitarian operations management in response to flood disasters, during which an optimal...     

Comparison of solutions to the thirteen-moment and standard transport equations for low speed thermal proton flows

We have compared solutions obtained from the general 13-moment system of transport equations with those obtained from the standard collision-dominated transport equations for conditions corresponding to low speed thermal proton flow in the topside ionosphere in the vicinity of the plasmapause. In general, the solutions obtained from the 13-moment system of equations, which allows for different species temperatures parallel and perpendicular to the geomagnetic field and non-classical heat flows, are different from those obtained from the standard transport equations, which account for isotropic temperatures and classical collision-dominated heat flows. Within the plasmasphere, where the electron density is high, the differences between the 13-moment and standard solutions are typically small. However, outside the plasmasphere where the electron density is lower and in the ionosphere above SAR-arcs, where substantial electron and proton heat flows occur, there can be significant differences between the 13-moment and standard solutions. Generally, the differences are much larger for the protons than for the electrons. Our 13-moment solutions indicate that the proton and electron distributions are anisotropic with the difference between parallel and perpendicular temperatures approaching 4000 K for the protons and 2500 K for the electrons in the ionosphere above SAR-arcs. Also, above SAR-arcs the 13-moment heat flow equations yield proton heat flows as much as a factor of 10 lower and electron heat flows as much as a factor of 2 lower than those predicted by the classical collision-dominated heat flow expressions for the same boundary conditions.     

Archaean TTGs as sources of younger granitic magmas: melting of sodic metatonalites at 0.6–1.2 GPa

Two natural, low K₂O/Na₂O, TTG tonalitic gneisses (one hornblende-bearing and the other biotite-bearing) were partially melted at 0.8–1.2 GPa (fluid-absent). The chief melting reactions involve the breakdown of the biotite and hornblende. The hornblende tonalite is slightly less fertile than the biotite tonalite, but melt volumes reach around 30% at 1,000°C. This contrasts with results of most previous work on more potassic TTGs, which generally showed much lower fertility, though commonly producing more potassic melts. Garnet is formed in biotite-bearing tonalitic protoliths at P > 0.8 GPa and at > 1.0 GPa in hornblende-bearing tonalitic protoliths. All fluid-absent experiments produced peraluminous granitic to granodioritic melts, typically with SiO₂ > 70 wt.%. For the biotite tonalite, increasing T formed progressively more melt with progressively lower K₂O/Na₂O. However, the compositions of melts from the hornblende tonalite do not vary significantly with T. With increasing P, melts from the biotite tonalite become less potassic, due to the increasing thermal stability of biotite. For the hornblende tonalite, again there is no consistent trend. Fluid-absent melting of sodic TTGs produces melts with insufficient K₂O to model the magmas that formed the voluminous, late, potassic granites that are common in Archaean terranes. Reconnaissance fluid-present experiments at 0.6 GPa imply that H₂O-saturated partial melting of TTGs is also not a viable process for producing magmas that formed these granites. The protoliths for these must have been more potassic and less silicic. Nevertheless, at granulite-facies conditions, sodic TTGs will produce significant quantities of broadly leucogranodioritic melt that will be more potassic than the protoliths. Upward abstraction of this melt would result in some LILE depletion of the terrane. Younger K-rich magmatism is unlikely to represent recycling of TTG crust on its own, and it seems most likely that evolved crustal rocks and/or highly enriched mantle must be involved. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

The Amsterdam-St. Paul volcanic province,and the formation of low Al tholeiitic andesites

The island of St. Paul in the Indian Ocean is located on the axis of the southeastern branch of the Indian Ocean Rise, as is the similar volcano of Amsterdam, 80 km to the north. Both volcanoes and possibly part of the local ridge are formed of a high-alumina plagioclase tholeiite making this a distinctive volcanic province. Lavas with Al₂O₂ contents of 12 to 22% are directly related by plagioclase fractionation. Residual rocks are a distinctive low silica, low alumina, potassic andesite with andesine and even olligoclase feldspar. Parallel lines of evolution exist in the sea floor plagioclase tholeiites, which differ only in slightly lower tenor of Sr and potassium group elements, and in the Steens Mountain tholeiites of Oregon, which differ in their significantly higher Sr and K group elements