Generation of greenhouse effect gases from different landfill types

Recently much attention is focussed on the problems of global warming due to greenhouse effect gases, notably carbon dioxide and methane. Because these gases cause important problems to the global environment, their generation from landfill sites containing solid wastes has drawn attention and their environmental impact is causing concern.

Generally, the gases associated with a greenhouse effect include carbon dioxide, methane and nitrous oxide. However, there are no general basic data available concerning gases generated from biodegradation of solid wastes in landfill sites. Specifically, no assessment has been made concerning greenhouse effect gases from different landfill types.

This paper proposes a quantitative model for estimating the gasification rate by different landfill types. The model is based on measurement data for a long-term material balance for an aerobic landfill and an anaerobic landfill, obtained with two types of large-scale lysimeters.

This paper will also give an estimate for the amount of greenhouse effect gases by for different types of landfill and propose countermeasures for their reduction.     

Fracture step structure: geometrical characterization and effects on fluid flow and breakthrough curve

Groundwater flow and solute transport through fractured rock is highly responsive to the hydraulic anisotropy and heterogeneity that are specific to every major fracture. A major fracture is modeled as the combination of some primal master fractures and several splay fractures that branch out from primal master fractures: step structures (or jog parts). Step structures are commonly observed along a major fracture on various scales. Master fractures were formed and developed by shear movement while some splay fractures were formed by extension normal to their wall. This difference in fracturing process may lead to a permeability difference between master fractures and splay fractures which seems to be one of the major factors controlling flow and solute transport through the fracture networks due to its hydraulic anisotropic and heterogeneous features. This study is composed of two major components: (1) identification and characterization of a step structure from borehole data; (2) evaluation of effect of some idealized step structures on breakthrough curve by numerical simulations. The fracture data of four 1000-m boreholes were used to make clear fracture patterns in the Tono area of Japan. Some major fractures were identified using stereographic projection technique. On the basis of these results, several idealized models of a major fracture having a step was constructed for the numerical study. The obtained results from numerical simulations clearly imply that geometry of step structure plays an important role in flow and transport through the fracture networks.     

Molecular cloning and mRNA expression of cytochrome P4501A1 and 1A2 in the liver of common minke whales (Balaenoptera acutorostrata)

This study presents full-length cDNA sequences of CYP1A1 and 1A2, in common minke whale (Balaenoptera acutorostrata) from the North Pacific. Both CYP1A1 and CYP1A2 cDNAs had an open reading frame of 516 amino acid residues, and predicted molecular masses were 58.3 kDa and 58.1 kDa, respectively. The deduced full-length amino acid sequence of CYP1A1 revealed higher identities with those of sheep (86%) and pig (87%), and that of CYP1A2 was most closely related to human (82%) and monkey CYP1A2 (82%) among species from which CYP1A2 has been isolated so far. Differences in certain conserved and functional amino acid residues of CYP1A1 and 1A2 between common minke whale and other mammalian species indicate the possibility of their specific metabolic function. Concentrations of organochlorine compounds (OCs) including PCBs and DDTs analyzed in common minke whale liver showed no significant correlation with hepatic mRNA expression levels of CYP1A1 and CYP1A2, indicating no induction of these enzymes by such OCs.     

On the Progress Design of Integrated Geologic Analysis System: Object-Relational Database Model and Visualization for Earth Resources

Abstract. An object-relational data model is an entry point and integral part of geologic analysis system, in which we can start geologic modeling inside a database. A conceptual data model named the Geoscience (Earth Resources) Data Model 3.0 has been developed based on the conceptual design of NADM-C1.0 and EGDM 812. Such adaptation makes this data model interoperable with data models from other geoscience fields. The focus of current data model is to effectively manage multi datasets related with the study of earth resources and to create relationship among data types.
The conceptual data model for earth resources is successfully implemented physically by integrating a GIS and relational data storage. The direct link between relational database and GIS makes the database contents highly visual and spatially enabling. Database contents are fully georeferenced through different types of georeferencing systems that enables data integration, visualization and analysis of multi geoscience datasets in 2D and 3D environment. A new way of geologic analysis through visualization of virtually all kinds of geoscience datasets is proposed.
The earth resources research and industry can take benefits on this system through better data management and effective geologic visualization that in turn accelerate a better understanding of earth resources. Meanwhile wider geoscience community will benefit from better interaction and data sharing among geoscience fields for accelerating a better understanding of our complex earth.     

Late Cenozoic evolution of epithermal gold metallogenic provinces in Kyushu, Japan

Kyushu Island, Japan, is located at the junction of the Southwest Japan arc and the Ryukyu arc. There are two major late Cenozoic epithermal gold-silver provinces in Kyushu, which are termed the Northern and Southern provinces. The provinces are characterized by: 1) Pliocene volcanism dominated by calc-alkaline andesite, followed by Quaternary volcanism including extrusion of both calc-alkaline and tholeiitic magmas; 2) formation of extensional grabens; 3) Pliocene to Pleistocene mineralization, which was dominated by abundant low sulfidation (LS) epithermal deposits with a few high sulfidation (HS) examples. The two epithermal gold-silver provinces have evolved differently since about 5 Ma; the Northern province has exhibited diminished hydrothermal activity from the Pliocene to Pleistocene, whereas the Southern province has witnessed increased hydrothermal activity mainly in easterly and northerly directions. Changes of tectonic setting from the Pliocene to Pleistocene account for the variable trends in epithermal gold deposit formation. Westward oblique subduction of the Philippine Sea plate beneath the Southwest Japan arc caused development of the Hohi graben and arc-related volcanism at about 6 Ma. This was associated with widespread LS mineralization in and surrounding the Hohi graben, as is represented by the Bajo and Taio deposits. The subduction of the relatively buoyant Kyushu-Palau ridge during the early Pliocene strengthened the coupling between the slab and overriding Ryukyu arc, leading to polygenetic andesite volcanism with associated HS (Kasuga, Iwato, and Akeshi) and LS (Kushikino) mineral deposits forming in the Southern province. A change of the subduction direction of the Philippine Sea plate, from west to north-northwest in the early Pliocene, increased the orthogonal convergence rate between the Southwest Japan arc and the Philippine Sea plate, resulting in a decrease of volcanic and hydrothermal activity in the Hohi graben of the Northern province. The more northerly subduction of the Philippine Sea plate shifted the locus of the Kyushu-Palau ridge subduction northward, resulting in underplating of the older (85–60 Ma), negatively buoyant Amami basin oceanic slab in the Southern province, rather than continued subduction of the young (27–15 Ma), buoyant Shikoku basin slab. This replacement caused steepening of the slab angle and slab-rollback in the Southern province, which was associated with regional extension, an eastward shift of the Ryukyu volcanic front, and development of the Kagoshima and Shimabara grabens, as well as the Okinawa trough. Rhyolite and basalt volcanism, in addition to andesite volcanism, have occurred since 2 Ma in the area of the Ryukyu back arc; coincident LS mineralization at Hishikari and Ohkuchi was affiliated with the rhyolite volcanism. Another change of the subduction direction of the Philippine Sea plate to the northwest occurred at 2–1 Ma. The forearc sliver of the Southwest Japan arc shifted westward, in association with right-lateral strike-slip faulting along the Median tectonic line, due to the increase of the westward convergence rate. This shift resulted in shortening and cessation of graben development in the Hohi area, restricting the subsequent volcanism and related hydrothermal activity to the central part of the graben.     

Multi-functional heat pulse probe measurements of coupled vadose zone flow and transport

Simultaneous measurement of coupled water, heat, and solute transport in unsaturated porous media is made possible with the multi-functional heat pulse probe (MFHPP). The probe combines a heat pulse technique for estimating soil heat properties, water flux, and water content with a Wenner array measurement of bulk soil electrical conductivity (EC_bulk). To evaluate the MFHPP, we conducted controlled steady-state flow experiments in a sand column for a wide range of water saturations, flow velocities, and solute concentrations. Flow and transport processes were monitored continuously using the MFHPP. Experimental data were analyzed by inverse modeling of simultaneous water, heat, and solute transport using an adapted HYDRUS-2D model. Various optimization scenarios yielded simultaneous estimation of thermal, solute, and hydraulic parameters and variables, including thermal conductivity, volumetric water content, water flux, and thermal and solute dispersivities. We conclude that the MFHPP holds great promise as an excellent instrument for the continuous monitoring and characterization of the vadose zone.     

Size distributions of aerosol number concentrations and water-soluble constituents in Toyama, Japan: A comparison of the measurements during Asian dust period with non-dust period

Size-separated aerosol number concentrations and water-soluble constituents were measured in Toyama, the Hokuriku district, near the coast of the Japan Sea, during the spring and summer in 2003. The number concentrations of coarse particles were significantly high in April, which was due to Asian dust events called Kosa in Japanese. Particulate nssCa²⁺, which is mostly present in the coarse-mode particles, was significantly high in April. On the other hand, the concentrations of NH₄⁺ and nssSO₄²⁻, which mainly exist as the accumulation-mode particles were not high in April. The mass-size distributions of water-soluble constituents were compared with the size-separated number concentrations of particles. Backward trajectory analysis was also employed to examine the transport process of the air mass in Toyama.