A study on sample pretreatment of analysis of Cd, Pb and Zn in seawater by IDMS

Isotope dilution mass spectrometry (IDMS) and ultra-clean room approach are successfully used in the determination of Cd, Pb and Zn in seawater and the sample pretreatment of analysis. The precision in the determination of Cd, Pb and Zn in seawater is better than±3% and the limits of detection are 6×10-12, 6×10-11 and 2.4×10-10 respectively. The effects of sample pretreatment such as filtration and acidification on the results of determination of Cd- Pb and Zn in seawater are disscussed.     

长期非平稳荷载调谐质量减振阻尼器优化设计

研究外荷载为长期非平稳随机过程。考虑长期荷载的特性 ,采用 1个概率谱密度函数来反映长期非平稳随机荷载及其特征 ;概率谱密度函数是基于大量的一般谱密度函数的统计特性获得。以延长结构的抗疲劳使用寿命为目标函数 ,提出了调谐质量减振阻尼器的优化设计方法 ,这在实际工程中有着极为广阔的应用前景。本文旨在从理论上发展长期非平稳随机荷载作用下调谐质量减振阻尼器的优化设计方法 ;文中采用长期波浪实测数据 ,给出了 1个数值算例说明整个设计过程。     

渤海南部表层沉积的相特征

通过海上调查及实验室分析,查明渤海南部表层沉积物在结构类型、矿物组合、生物组分及沉积构造等相特征方面具有明显的分区性。渤海南部存在五种沉积相:黄河水下三角洲相、陆架盆地相、海湾相、潮流浅滩相及古滨岸相。黄河水下三角洲相从河口延至水深15—20米处,沉积速率很高,沉积物富含碎屑云母及CaCo_3。陆架盆地相的沉积为粉砂质粘土,具有生物扰动构造。     

浙江省海岸侵蚀及防治概述

浙江海岸侵蚀现象普遍存在。基岩海岸海蚀地貌发育,因其组成物质抗冲蚀能力强,岸线后退不明显;砂砾质海岸普遍发生侵蚀,尤其是无计划的人工挖沙,造成沙滩减小或消失;淤泥质海岸大多处于缓慢的淤涨状态,但由于自然条件的改变和人为作用的影响,某些岸段发生侵蚀,特别是受到台风暴潮的影响,岸线在短时间内出现大规模后退和滩面下蚀。侵蚀岸段主要见于杭州湾北岸澉浦至金丝娘桥岸段,杭州湾南岸临山至西三岸段及瓯江口北岸盘石至黄华岸段。淤泥质海岸后缘为滨海平原,组成物质为粘土质粉砂,抗冲蚀能力弱,为防止和减轻海岸侵蚀,沿岸建造各类海岸工程(海塘、丁坝、导堤等),提高防潮抗浪能力,在朝滩种植大米草,互花米草,消浪促淤明显。另外,在海岸开发活动中,应加强海岸侵蚀监测和综合管理。     

Baroclinic Buoyancy-Inertia Joint Stability Parameter

At present, the barotropic buoyant stability parameter has been derived from a vertical virtual displacement of a water parcel. The barotropic inertial stability parameter in the eccentrically cyclogeostrophic, basic current field was derived in 2003 from a horizontal cross-stream virtual displacement of a parcel. By expressing acceleration of a parcel due to a virtual displacement, which is arbitrarily sloping within a vertical section across the basic current, in terms of natural coordinates, we derived the vertical component of baroclinic buoyant stability parameter B ₂ ², the horizontal component of baroclinic inertial stability parameter I ₂ ², the baroclinic joint stability parameter J ², its buoyant component B ² and its inertial component I ². B ² is far greater than I ₂ ², and when neglecting relative vorticity except for vertical shear, a downward convex curve of J ² plotted against the slope of a virtual displacement follows a trend of B ² curve. If a parcel displaces along a horizontal surface or an isopycnal surface, however, B ² vanishes, and J ² becomes equal to I ². Actual parcel is apt to displace not only along the bottom slope, but also along the sea surface and an isopycnal interfacial surface, which is approximately equivalent to an isentropic surface, preferred by lateral mixing and exchange of momentum. Such actual displacement makes B ² vanishing, and grants I ² an important role. The present analysis of I ² examining effects due to curvature and horizontal and vertical shear vorticities are useful in deepening our understanding of baroclinic instability in actual oceanic streams.     

Preconditioned Optimizing Utility for Large-dimensional analyses (POpULar)

I present the derivation of the Preconditioned Optimizing Utility for Large-dimensional analyses (POpULar), which is developed for adopting a non-diagonal background error covariance matrix in nonlinear variational analyses (i.e., analyses employing a non-quadratic cost function). POpULar is based on the idea of a linear preconditioned conjugate gradient method widely adopted in ocean data assimilation systems. POpULar uses the background error covariance matrix as a preconditioner without any decomposition of the matrix. This preconditioning accelerates the convergence. Moreover, the inverse of the matrix is not required. POpULar therefore allows us easily to handle the correlations among deviations of control variables (i.e., the variables which will be analyzed) from their background in nonlinear problems. In order to demonstrate the usefulness of POpULar, we illustrate two effects which are often neglected in studies of ocean data assimilation before. One is the effect of correlations among the deviations of control variables in an adjoint analysis. The other is the nonlinear effect of sea surface dynamic height calculation required when sea surface height observation is employed in a three-dimensional ocean analysis. As the results, these effects are not so small to neglect.     

2000年夏季莱州湾生态环境要素的分布特征

论文依据 2 0 0 0年夏季 8月 2 9日至 9月 2日莱州湾的 1次综合性生态环境调查资料 ,给出了表、中、底 3层的平均温度、盐度、主要营养盐浓度及其比例和叶绿素 a浓度 ,分析了莱州湾的温盐结构、主要营养盐和叶绿素 a的分布特征。由于莱州湾的水深较浅 ,各要素的垂直分布都比较均匀。生态环境要素的水平分布表现为小清河口为高温、低盐、高营养盐和高叶绿素 a浓度区 ,小清河口东测的湾顶区域为高温、高盐、相对低的营养盐和叶绿素 a浓度区。此次观测到的盐度较 1997年以前有明显升高。莱州湾各层平均的 N/ P和 Si/ N分别为 16.73和 1.67,都比 1998～ 1999年渤海中部的值大 ,但 N/ P比 1992 ,1995和 1996年莱州湾的 N/ P明显偏低。叶绿素 a浓度与硅酸盐浓度之间有较好的相关关系 (α=0 .0 1) ,表、中、底 3层叶绿素 a浓度同硅酸盐浓度的线性相关系数分别为 :0 .5 4 ,0 .68和 0 .67     

涠洲岛珊瑚礁生态系中浮游动植物与环境因子关系的初步探讨

本文根据1990年4月、10月间的理化分析数据，结合2002年9月涠洲岛珊瑚礁生态环境的调查状况，首次从珊瑚礁生态系的角度初步探讨该岛区浮游动植物与环境因子的关系。结果表明：该岛区浮游动植物的分布具有明显的区域性和季节性，既体现了珊瑚礁生态系具有较高的初级生产力特征，也体现了浮游动植物具有显著的季节交替现象。相关分析显示，水温、盐度、N，P，Si营养盐对浮游植物的种类组成及数量变动均有明显影响，但对浮游动物的影响不大；N是该生态系中浮游植物的限制因子，P限制状况只有在珊瑚礁生长带较深的海域出现，Si呈相对富足状态。     

南极磷虾年龄组成的体长频数分布混合分析

本文依据１９８９／１９９０和１９９０／１９９１两个南极夏季在普里兹湾以北海域所获的拖网样品，应用分布混合分析方法，研究大磷虾种群的年龄结构。结果表明，种群内最多可能包括６个年龄：发年幼体，１＾＋，２＾＋，３＾＋，４＾＋和＾５＋龄虾。     

赤道西太平洋大气边界层的诊断分析

利用１９９３年ＥＮＳＯ事件爆发（４月）前酝酿时期“热带大洋与全球大气－海洋耦合响应试验”强化观测阶段“向阳红五号”科学考察船１５５°Ｅ，２°Ｓ定点海洋气象和高空大气探测资料，分析了赤道西太平洋大气边界层特征。结果表明：赤道西太平洋上空辐合对流区边界层内也有等温或逆温层存在，大气边界层物理参数变化与大尺度海－气变异有密切关系，赤道太平洋沃克环流加强、东移，边界层上部逆温层出现概率明显增大，边界层内高湿层湿度减小。另外，边界层内实测风速、风向廓线随高度的变化基本上不服从Ｅｋｍａｎ规律，但由其平均，分量合成得到的平均风随高度的变化却基本符合Ｅｋｍａｎ规律。