鲁西南地区石炭纪—二叠纪含煤岩系层序地层及聚煤特征

根据钻井、测井和地质等资料,对鲁西南地区石炭纪—二叠纪含煤岩系进行了层序地层学与聚煤作用研究。识别出以区域不整合面、古土壤层底面、海侵方向转换面、下切谷砂体底面为代表的4种类型的层序界面;划分出本溪组、太原组、山西组和下石盒子组中的4个三级层序,从下到上依次为SⅢ1、SⅢ2、SⅢ3及SⅢ4。通过对比研究不同层序的含煤性及煤层的发育特征后认为,形成于分流间湾沼泽环境的SⅢ3煤层发育最好,形成于潟湖与沼泽环境的SⅢ1及SⅢ2煤层发育次之,SⅢ4没有煤层发育。在同一个层序内部,泥炭聚集速率与可容空间增加速率之间的平衡状态决定了煤层的厚度,这种平衡状态保持较长时间是煤层形成的基本条件,而与泥炭聚集有关的可容空间的持续增加需要基准面的不断抬升,因此,发育较好的煤层最可能形成于海侵体系域末期,如SⅢ3的TST末期的3号煤层。     

黄河源区陆面过程观测和模拟研究进展

陆面过程对黄河源区水资源变化有重要的影响,探索黄河源区陆面过程和水分循环特征的关联机理有十分重要的意义.首先简述了黄河源区气候变化背景和陆面过程的基本特征,并详细介绍了近年来在黄河源区开展的一系列陆面过程野外观测试验及相关研究主题和研究进展;进一步给出了在野外试验观测资料分析、卫星遥感、数据同化应用和数值模拟等方面取得...     

对矿物包裹体溶液性质的新认识——兼论含矿溶液是酸性溶液的地质证据

对金属矿床成矿溶液的性质 ,特别是 pH值 (酸碱度 )的确定 ,是认识含矿溶液的成因、成矿条件和成矿机理的关键。目前对成矿溶液性质的研究主要局限在对围岩蚀变矿物包裹体的测定方面 ,并得出近中性热卤水成矿的结论。作者认为 ,多数围岩蚀变矿物的包裹体溶液不能代表原成矿溶液的性质 ,“近中性的热卤水成矿”的认识有误 ,应是酸性水形成的含矿溶液成矿 ,并从矿物包裹体溶液的特征、Roedder的高金属含量的矿物包裹体溶液的发现、氢氧同位素资料、矿物包裹体中高卤水溶液的起源以及成矿溶液的演化机理等方面论述了酸性金属含矿溶液的成因及成矿演化过程。     

The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

天然气运移的气体同位素地球化学示踪

本文通过鄂尔多斯等含油气盆地内岩石酸解烃、罐顶气和同源多产层天然气碳同位素组成的变化，从实例剖析出发，探讨了天然气运移时气体同位素组成的变化及其对天然气运移的示踪。天然气在通过沉积地层中孔隙系统和微裂隙运移时，天然气中的甲烷碳同位素会发生一定的分馏，而乙烷以上重烃碳同位素几乎不发生分馏；在天然气层所在深度，罐顶气甲烷碳同位素组成与天然气一致，在天然气层附近，罐顶气甲烷碳同位素则明显偏离了热演化趋势线；烃源岩酸解烃与其同源的天然气重烃碳同位素组成具有较好的一致性和可比性。由此，可利用气体组分碳同位素的上述变化特征，追索天然气的运移作用。     

Tin mineralization in the Dajing tin–polymetallic deposit, Inner Mongolia, China

Dajing is a large-scale tin–polymetallic deposit that hosts the largest tin mine in North China. It is a hydrothermal vein-type deposit containing Sn, Cu, Pb, Zn, Ag, and minor components Co and In. The deposit consists of more than 690 veins hosted within Upper Permian sedimentary rocks.Three mineralization stages and six ore types are recognized with cassiterite constituting the dominant tin mineral. The SnO₂ content of cassiterite increases in the sequence of mineralization stages shear-deformation→cassiterite–quartz→cassiterite–sulfide (or chalcopyrite–pyrite) stage, while the content of FeO, TiO₂, Nb₂O₅, Ta₂O₅, and In₂O₅ tends to decrease with increases in NiO and Ga₂O₅. It is considered that the negative correlation between SnO₂ and FeO, Nb₂O₅, Ta₂O₅, and In₂O₅ results from elemental substitutions. The early stage cassiterite is much richer in Ta and the later stage cassiterite is much poorer in Ti and Fe than is usual in hydrothermal vein type tin deposits. This is interpreted to indicate that the component of early stage cassiterite reflects a granitic magma source while the composition of later stage cassiterite has a more obvious strata source. The compositional variation of cassiterite corresponds to decreasing crystallization temperatures within each stage and between sequential stages with time. The characteristics of REE in cassiterite from two stages are in accord with that of subvolcanic rocks and the Linxi formation. It suggests that tin transported during the cassiterite–quartz stage may have originated from subvolcanic dikes (e.g., dacite porphyry), while in the cassiterite–sulfide stage, tin may have been derived from wallrock (e.g. siltstone) of the Upper Permian-age Linxi Formation.     

乐德矿带成矿系列与成矿规律

乐华—德兴矿带是指江西省内呈NE走向的有色金属和贵金属成矿带,带内有丰富的Cu、Pb、Zn、Au、Ag等矿产资源,其中铜储量约占我国总储量的17.5％。 矿带位于扬子地台南缘关帽山地背斜内,广泛发育中元古代双桥山下亚群和轴向呈EW向或NE向的线状基底褶皱。矿带两侧为断层或地块。矿带内有许多韧性剪切带和燕山期中酸性火成岩,呈NE向分布。 矿带有5个矿田,15个矿床,划分为两个成矿系。是根据其成矿控制因素,矿床物质组分,REE含量,S、Pb、O等稳定同位素,以及黄铁矿中的Co、Ni含量和Co/Ni比值。两个成矿系为:(1)Cu-Pb-Zn-Ag(Au);(2)Au。矿系(1)呈简单的水平分带,矿化与燕山期中酸性岩浆活动有关,而矿系(2)的矿化则与韧性剪切带和晚期断层作用直接有关。     

北秦岭丹凤地区产铀花岗岩稀土元素地球化学特征

针对北秦岭丹凤地区产铀花岗岩的区域地层、赋矿围岩、蚀变岩和铀矿石进行稀土元素地球化学研究,结果表明:各类样品具有大体类似的LREE富集及Eu负异常的稀土配分模式,表明它们之间稀土元素特征具有继承性;赋矿黑云母二长花岗岩与区域地层(丹凤岩群变质基性火山岩)稀土元素特征指示,二者均形成于岛弧环境;蚀变花岗岩和铀矿石主要继承了赋矿花岗岩的特征。各类样品Y/Ho值变化范围狭窄,为25.09~33.46,显示它们具有共同的源区。铀矿石具有最高的w_B(∑HREE),且与铀矿石的品位存在正相关关系,暗示HREE与铀的迁移具有同步性。     

Sr,Nd,Pb Isotope Geochemistry and Magma Evolution of the Potassic Volcanic Rocks,Wudalianchi,Northeast China

Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition.     

山东开元洞发现典型"北方型"石笋微生长层

石笋中微层的形成一般认为与地表气候环境具有明显的季节变化有关~([1,2]).石笋微层的发育不仅具有明确的年代学意义~([2]),还具有重要的气候环境变化指示意义~([2,3]).