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131.
Sorption of Ni2+ on Na-rectorite as a function of contact time, temperature, pH and fulvic acid (FA)/humic acid (HA) was studied under ambient conditions. A pseudo-second-order rate equation was used to simulate the kinetic sorption. The removal of Ni2+ increased with increasing pH. The presence of FA/HA enhanced the sorption of Ni2+ at low pH values, whereas no drastic effect of FA/HA on Ni2+ uptake to rectorite was found at high pH values. The diffuse layer model (DLM) fitted the experimental data of Ni2+ sorption in the absence and presence of FA/HA very well with the aid of FITEQL 3.2. The Langmuir, Freundlich and Dubinin–Radushkevich (D–R) models were used to simulate the sorption isotherms of Ni2+ at different temperatures. The thermodynamic data (ΔH0, ΔS0, ΔG0) were calculated from the temperature dependent sorption isotherms and the results suggested that the sorption process of Ni2+ on rectorite was spontaneous and endothermic. The sorption and species of Ni2+ on rectorite in the presence and absence of FA/HA was also investigated and characterized by XPS. The spectroscopic analysis indicated no drastic structural changes of Na-rectorite and the sorption of Ni2+ mainly occurred on the surface and at the edge position of Na-rectorite. 相似文献
132.
Identification of sources and causes of leakage on a zoned earth dam in northern Taiwan: Hydrological and isotopic evidence 总被引:3,自引:0,他引:3
Seepage through an earth dam body must be regulated as a well–planned process, if it is not properly managed, the abnormal seepage may cause dam failure. This study employed stable isotopic and statistical methods to identify the source and cause of an abnormal leakage on the zoned earth dam of the Xin–Shan reservoir located in northern Taiwan. Water samples from the dam area over a 2-a period were collected and analyzed for their stable O and H isotope compositions. In addition, a 4-a period of hydrological data, including rainfall, reservoir level, well level, seepage of filter drainage and leakage, were statistically analyzed with a stepwise multiple regression approach. Both the stable isotopic and hydrological results indicate that the abnormal leakage on the dam shell comes from the filter drainage in the dam. The reason for abnormal leakage is due to unexpected and significant precipitation–sourced water flowing into the dam’s body. The dam filter fails to drain out the incoming water sufficiently, thus generating the abnormal seepage. In addition, the defect in the dam filter may also cause the drainage filter to drain off reservoir seepage inadequately. Therefore, it is suggested that checking the filter function and preventing excessive precipitation–sourced water from flowing into the dam are the two top priorities for the follow-up remedial strategy of the dam. 相似文献
133.
Li Miao Ruisong Xu Yueliang Ma Jinhong Xu Jie Wang Rui Cai Yu Chen 《Journal of Geochemical Exploration》2008,96(1):43-52
In the Hetai goldfield, Guangdong Province, China, samples including rocks, soils and leaves of four plants (Pinus massoniana, Rhodomyrms tomenlosa, D. linearis var. dichotoma and Embelia laeta) collected from the gold mineralization zone and the background area were analyzed for Au, Ag, Cu, Pb, Zn, Hg, As and physiological parameters. The objective of this investigation is to study the geochemical and biogeochemical characteristics of studied plants, aiming at biogeochemical methods in Au exploration. The goldfield region shows geochemical and biogeochemical anomalies. Abundances of Au in rocks, soils, plants and the leaf pigments in the mineralized area are much higher than those in the surrounding region. The plants display unhealthy physiological and ecological characteristics in the Hetai goldfield area. The cell structures of the goldfield plants were anomalous and aberrant, and there were many nano-metal particles diffused in mitochondria and chloroplasts. Macro- and microscopic evidences of the vegetation in the goldfield areas are distinctly different from the background regions. The strongly anomalies in responses to Au are profound in further geochemical and botanic exploration studies. 相似文献
134.
依据渤海湾盆地2000余口测温井的地温梯度数据、地层岩性描述、分层数据以及钻井资料,计算了该盆地各生油岩系底界面的温度。统计结果表明:渤海湾盆地沙河街组大部分凹陷区地层底界面温度介于90℃至150℃,目前仍具有大量生油的温度条件,而在隆起或一些凸起地区,该地层组段温度普遍小于90℃,未能达到生油的温度指标。东营组和孔店组地层也仍具有一定的生油温度条件。研究还表明:地层温度与地层界面埋深密切相关,温度随界面埋深的增大而升高,沉积厚度大的凹陷区地层界面温度大于沉积厚度小的凸起区或斜坡地带,说明地层界面埋深是决定地温高低的主要控制因素,而地温梯度对地层界面温度的影响相对较小。 相似文献
135.
136.
137.
基于GF-1卫星数据对2013年11月22日青岛黄潍输油管道爆炸造成的海面溢油进行定量监测。研究首先采用2013年11月26日GF-1卫星数据对海面溢油进行提取,其统计面积为0.67 km2;其次,结合肖剑伟提出的油膜厚度单波段反演模型估算油膜厚度,最终计算得到溢油量为0.28 t;最后,对Band 1反射率与油膜厚度结果进行灰度分割,将溢油污染程度分为6级,对比发现两者分级结果较为一致。由此得出,通过反射率直接进行灰度分割可以对溢油污染进行有效的等级评定。 相似文献
138.
从统计分析看控制东海重矿物分布的因素 总被引:1,自引:0,他引:1
任何地质作用过程都是复杂的,东海也不例外,其沉积过程具有长期性、继承性和叠加性的特点.因而反映在矿物组合及其分布变化上较为复杂,影响因素颇多.然而,运用数学地质方法却可帮助我们寻找和确定其主要的影响因素,查明它们的相互关系,甚至建立定量描述的模式.而这正是传统地质学研究中的难题之一. 相似文献
139.
根据1986—1990中美热带西太平洋海气相互作用8个航次合作综合调查资料,分析了1987年10月赤道中西太平洋165°E(10°N-6°S)次表层水形成溶解氧最大值的原因。1986-1987年E1Nino衰退时期,该海域赤道附近在E1Nino强盛时期下沉的次表层水开始回升,短时期内形成了类似于中、高纬度海域的理化环境,使浮游生物在混合层内聚集生长,最终导致溶解氧含量在次表层出现最大值和过饱和含量。 相似文献
140.