Calcified roasting-acid leaching process of vanadium from low-grade vanadium-containing stone coal

The low-grade vanadium-containing stone coal used in this experiment was collected from Wuxi Coun- try, Chongqing City, China. The experiment focused on the vanadium recovery from roasted residue through opti- mizing the process conditions of an effective and environmentally-friendly technology, named calcified roast- ing-sulfuric acid leaching technology. By single-factor experiments and orthogonal experiments, the effects of roast- ing temperature, roasting time, sulfuric acid concentration and leaching time on the leaching ratio of vanadium were analyzed. The results showed that the leaching ratio of vanadium reached 85.5% under the proper technological con- ditions of roasting temperature=950℃, roasting time=4 h, 40% concentration of sulfuric acid and leaching time=6 h.     

长春黄土状土的水文、工程地质特性及降水方案的确定

在镜下对长春黄土状土的微观结构进行研究，发现第三层粉质粘土含水机制在于土中具有纵横交织的空洞和管道，地下水赋存于其中；第二层棕红色粉质粘土和粘土的崩解性在于该层土具有网状裂隙，卸荷后遇水崩解，在此基础上提出基坑降水的设计方案。     

Evolution of Ore-Forming Fluids and Ag-Cu Polymetal Mineralization in the Lanping Basin, Yunnan

EVOLUTION OF ORE-FORMING FLUIDS AND Ag-Cu POLYMETAL MINERALIZATION IN THE LANPING BASIN, YUNNAN“KeyProjectforResourcesandEconomics” (95 0 2 0 0 1 0 1)oftheMinistryofLandResources     

我国科学数据共享现状的调查

本文是科学数据共享政策法规体系研究系列文章的收笔之作.撰写本文的目的,就是为说明科学数据共享政策法规体系的研究是建立在大量的基础调研之上.调查研究是谋事之基、成事之道.从实践中寻求解决现实问题的方法,才能制定出切实可行的政策、法规,调查研究是制定政策、法规的客观依据.为使制订政策、 规章制度适应社会经济发展和变化的新情况,就深入开展调查研究,认真听取各方面的意见,深入研究相应的管理规律和运行机制.本文详述了调查过程、调查方法,以佐证政策法规研究不能脱离实际.     

早期太阳星云演化历史的指示剂——不同类型陨石母体的吸积和形成过程

不同类型球粒陨石母体的形成过程,可作为早期太阳星云化学演化的指示剂,它们包含原始球粒陨石中残存的前太阳颗粒,可提供太阳系外恒星演化的信息;原始球粒陨矿物-岩石学特征,可揭示早期太阳星云的凝聚和吸积作用过程;原始球粒陨石主要组分的氧同位素组成,可为了解形成不同类型球粒陨石的初始物质和形成环境提供重要的依据;原始球粒陨石中富钙-铝包体和球粒的形成年龄,可作为早期太阳星云演化的时标;原始球粒陨石的氧化-还原作用特征,可推断不同类型球粒陨石母体在太阳星云内距日心距离等,并进一步探讨早期太阳星云的化学演化。     

影响南极海洋石油烃低温降解菌希瓦氏菌NJ49生长和降解率的环境因素研究

以柴油为唯一碳源和能源,从南极海水海冰微生物资源库中筛选到一株石油烃低温降解菌希瓦氏菌NJ49,并对影响其生长和降解率的环境因素(pH、温度、盐度、营养盐和表面活性剂)进行了初步研究。结果表明:希瓦氏菌NJ49可作为低温海域石油烃污染生物修复的菌源,其生长和降解的最适条件为:初始pH7.5,温度15℃,盐度6%,摇瓶装量80ml,最佳氮源硝酸铵,最佳磷源为磷酸二氢钾和磷酸氢二钾的混合物,添加表面活性剂可促进希瓦氏菌NJ49的生长和生物降解率。     

树冠叶面积体密度和叶面积指数的间接估值方法研究

本文论述了根据计算机断层成像的原理，对树冠的叶面积体密度和叶面积指数等构造参数进行间接估值的方法。说明了对树冠多角度底视数据的获取，对树冠外形的反投影重构，和获得冠层内叶面积体密度的空间分布的原理和方法。总结了测量工作经验，并用测量数据对估值方法进行了检验。     

内蒙武川后石花金矿床辉钼矿Re-Os同位素年龄及其地质意义

后石花金矿是华北克拉通北缘一小型石英脉型金矿床。对矿体5件辉钼矿样品的ReOs同位素分析,获得了介于280.3±3.8~283.0±3.9Ma,加权平均为282.0±1.8Ma(MSWD=0.28)的同位素模式年龄,以及一个相关性很好的等时线年龄281.9±1.8Ma(MSWD=0.57),表明矿床形成于早二叠世,推测是海西晚期古亚洲洋俯冲体制下陆缘弧背景中构造-热液成矿事件产物。综合区域资料认为,华北北缘中段在海西晚期曾发生过重要成矿作用,但多在后期被剥蚀破坏。华北北缘中段大陆弧范围内,叠加在前寒武纪结晶基底韧性剪切带之上的脆性断裂构造带,以及华北北缘早古生代增生带内部,是形成海西晚期金、钼矿床的有利部位。     

Sr,Nd,Pb Isotope Geochemistry and Magma Evolution of the Potassic Volcanic Rocks,Wudalianchi,Northeast China

Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition.     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.