配位滴定法同时测定金属离子浓度的研究

将多元校正分析法应用于配位滴定中，以ＥＤＴＡ为滴定剂，玻璃电极为指示电极，饱和甘汞电极为参比电极。依据电位滴定原理，对混合三组分：Ｃｕ￣（２＋）、Ｃｄ￣（２＋）、Ｚｎ￣（２＋）、及Ｃｕ￣（２＋）、ＣＯ￣（２＋）、Ｎｉ￣（２＋）进行测定，各金属离子之间的△ｌｏｇＫ在０．０４～２．３４之间，计算误差一般小于土１０％。     

相干体技术在煤矿断层及陷落柱精细解释中的应用

根据相干体技术原理和主要参数选取原则,对五阳矿区进行了以断层和陷落柱为主要研究对象的解释工作。应用实例表明：相干体技术可有效解决本区断层断点较多、切割关系复杂、空间展布规律难以把握和常规解释误差较大等问题;同时,对不规则环状相邻陷落柱的边界及直径较小的陷落柱都有十分灵敏的反映,特别是对较大断层附近的微小构造也可作出较为可靠的解释。     

太原市区土壤中多环芳烃污染特征研究

采用1个样/km2的密度,1个分析组合样/25km2的方法,对太原市区土壤中多环芳烃进行了调查。结果表明,太原市区土壤中多环芳烃的平均含量为8.65μg/g;空间分布上北高南低,高值点主要位于工业区及交通要道地段;组成上以四环及四环以上的多环芳烃为主。通过与国内外城市土壤的对比可知,太原市土壤PAHs污染已相当严重,其来源主要是煤炭的燃烧。太原市工业布局、能耗类型和地理位置是造成土壤PAHs污染的主要原因。     

SH波水平入射穿越垂直断层隧道动力响应分析

结合黏弹性人工边界的时域波动输入方法和显式有限元法,设计了含垂直断层三维场地的SH波输入方法。基于建立的输入方法,研究了垂直断层对隧道地震响应的影响,并通过自由场算例验证了该方法具有较好精度。数值模拟结果表明:对于断层迎波侧的隧道结构,断层会对其地震动响应产生显著的放大作用,对于断层逆波侧的隧道结构,断层会对其产生隔离地震动的作用;相对周围围岩,断层介质的剪切波速越小,其产生的放大效应和隔震效果也会越显著;断层宽度越小,其对隧道地震动响应的影响范围也就越小,但是断层宽度的变化对于断层两侧隧道的地震动响应的影响并不明显。     

Relation between temperature changes of the mid-upper troposphere over Eurasian mid-high latitudes and solar irradiance in the twentieth century

The δ¹⁸O data obtained from an 18.7 m ice core drilled in Chongce Ice Cap at an elevation of 6,530 m a.s.l. in the West Kunlun Mountains on the northern Tibetan Plateau show a strong correlation with the summer temperature of the middle to upper troposphere over the mid-high latitudes of Eurasia. Based on this, the δ¹⁸O record can be used as a proxy of the June–September mean temperature of the mid-upper troposphere (MUT) from 1903 to 1992. The time span of the ice core record is much longer than the meteorological data available only after 1948. Using the empirical mode decomposition method (EMD), the δ¹⁸O record is decomposed into various frequency components and compared with the solar irradiance variations of the same period. The results show that (1) The June–September mean temperature of the MUT over Eurasian mid-high latitudes is completely decomposed into four IMF (intrinsic mode function) components and an increasing trend. (2) Solar irradiance is decomposed into the Schwabe cycle, the Hale cycle, the Gleissberg cycle, and an increasing trend. (3) The correlation coefficients between the June and September mean temperatures of the MUT over Eurasian mid-high latitudes and solar irradiance on the longer timescales (at least more than 11-year) show the significant correlations; their phase changes are basically identical in general, and (4) the 11-year Schwabe cycle exists in the June–September mean temperature of the MUT over Eurasian mid-high latitudes during most of the time from 1903 to 1992, and only in the two high-temperature phases (1929–1944 and from 1975 to the present) may global warming disturb this relation. A full understanding of this phenomenon would shed insight into the potential consequence of global warming on the MUT.     

CMIP5气候模式下淡水通量变化

基于全球降水气候态计划(GPCP)的降水资料和美国伍兹霍尔海洋研究所(WHOI)的客观分析海气通量(OAFlux)的蒸发数据,对CMIP5的13个耦合模式的淡水通量历史模拟结果进行评估。结果表明:模式能够模拟出淡水通量的气候态空间分布,但普遍存在双热带辐合带(ITCZ)现象,热带海域是模式模拟不确定性最大的区域。模式能较好模拟出纬向平均的淡水通量的分布特征,但量值较实测偏小,且由于模式对1月10°S附近淡水通量的模拟过低,导致年平均的赤道和10°S之间的淡水通量模拟存在明显的偏差。季节尺度上,模式对北半球淡水通量的变化特征有很好的模拟能力,但对南半球的模拟能力不足。年际尺度上,模式普遍能够刻画ENSO引起的淡水通量在太平洋中部同西太平洋以及印尼贯通流反相变化的空间分布特征,但是时间特征模拟很差。从各个方面评估模式的历史模拟结果,多模式集合的结果都要优于单个模式的结果。全球变暖背景下,未来淡水通量变化最显著的区域位于热带和亚热带区域。原本蒸发(降水)占主导的海域,蒸发(降水)更强。不同气候情景下,淡水通量变化的空间形态没有显著变化,但RCP8.5气候情景下模拟的淡水通量变化幅度及模式间变化的一致性均强于RCP4.5的结果。     

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A subsurface intensity index of the cold eddy in the East China Sea

The Cold Eddy in the East China Sea (CEECS) is located about 150 km southwest of Cheju Island. This region experiences a complex current system under the influences of the Yellow Sea Warm Current (YSWC), the Yellow Sea Coastal Current (YSCC), and the northward Kuroshio residual. To identify the strength of the CEECS, a simple subsurface intensity index is developed. Because the CEECS can be traced by temperature minimum, the intensity index is determined by the difference in sea temperature averaged across cores within and surrounding the region. Based on SODA, the CEECS subsurface intensity index time series can be calculated, with which the inter-annual variation of the CEECS is analyzed.     

A 16 ka climate record deduced from δ^13C and C/N ratio in Qinghai Lake sediments, northeastern Tibetan Plateau

1 INTRODUCTION δ13C in organic matters from lacustrine sedi- ments varies with several factors including aquatic plants, vegetation type in the catchment, atmos- pheric CO2 concentration, climate (temperature and precipitation), and properties of water, …