Basalts interbedded with oil source rocks are discovered frequently in rift basins of eastern China, where CO2 is found in reservoirs around or within basalts, for example in the Binnan reservoir of the Dongying Depression. In the reservoirs, CO2 with heavy carbon isotopic composition (δ13C>-10‰ PDB) is in most cases accounts for 40% of the total gas reserve, and is believed to have resulted from degassing of basaltic magma from the mantle. In their investigations of the Binnan reservoir, the authors suggested that the CO2 would result from interactions between the source rocks and basalts. As the source rocks around basalts are rich in carbonate minerals, volcanic minerals, transition metals and organic matter, during their burial history some of the transition metals were catalyzed on the thermal degradation of organic matter into hydrocarbons and on the decomposition of carbonate minerals into CO2, which was reproduced in thermal simulations of the source rocks with the transition metals (Ni and Co). This kind of CO2 accounts for 55%-85% of the total gas reserve generated in the process of thermal simulation, and its δ13C values range from -11‰- -7.2‰ PDB, which are very similar to those of CO2 found in the Binnan reservoir. The co-generation of CO2 and hydrocarbon gases makes it possible their accumulation together in one trap. In other words, if the CO2 resulted directly from degassing of basaltic magma or was derived from the mantle, it could not be accumulated with hydrocarbon gases because it came into the basin much earlier than hydrocarbon generation and much earlier than trap formation. Therefore, the source rocks around basalts generated hydrocarbons and CO2 simultaneously through catalysis of Co and Ni transition metals, which is useful for the explanation of co-accumulation of hydrocarbon gases and CO2 in rift basins in eastern China. 相似文献
The paper examines the mechanics and physics of granular material responses at the macroscopic and microscopic levels during both monotonic and cyclic loadings. A numerical analysis referring to a long retaining wall is conducted using a two-dimensional discrete element model representing a granular system with a free top surface. On one of the lateral boundaries referring to the retaining wall, both active and passive loadings were applied monotonically as well as cyclically. First, the development of sheared zones and classic failure wedges resulting from active and passive monotonic displacements are discussed with respect to Rankine’s and Roscoe’s solution angles. Then, a series of loading cycles were performed using slow small-amplitude displacements at different stress states chosen before the occurrence of failure along the passive monotonic stress response curve. Particular interest is focused on the ultimate asymptotic cyclic response of the granular system, the occurrence of a high-mobility (convective) zone and a detailed macroscopic and microscopic analysis. Finally, major kinematical features that are displayed during cyclic loading from different starting stresses to eventually reach the same asymptotic state were elucidated through particle vortex-like flux formations, including contact rotations. The change in material stiffness was also investigated based on the evolution of strong and weak contact networks, together with the analysis of fabric anisotropy within the entire domain, including the high-mobility zone considered separately.
