Zircon LA-ICP-MS U-Pb dating and Sr-Nd isotope study of the Guposhan granite complex, Guangxi, China

Zircon U-Pb dating by the LA-ICP-MS method was applied to determining the ages of different units of the Guposhan granite complex, among which the East Guposhan unit is 160.8±1.6 Ma, the West Guposhan unit is 165.0±1.9 Ma, and the Lisong unit is 163.0±1.3 Ma in age. Much similarity in ages of the three units has thus proved that the whole Guposhan granite complex was formed in the same period of time. They were the products of large-scale granitic magmatism through crust-remelting in the first stage of the Middle Yanshanian in South China. However, the three units have differences both in petrology and in geochemistry. Besides the differences in major, trace and rare-earth elements, they are distinct in their Rb-Sr and Sm-Nd isotopic compositions. The East Guposhan unit and Lisong unit and its enclaves have a similar (87Sr/86Sr)i value of 0.7064 with an average of εNd(t)=-3.03, indicating that more mantle material was evolved in the magma derivation; whereas the West Guposhan unit has a higher (87Sr/86Sr)i value of 0.7173 but a lower εNd(t) value of -5.00, and is characterized by strong negative Eu anomalies and higher Rb/Sr ratios, suggesting that its source materials were composed of relatively old crust components and new mantle-derived components. In addition, an inherited zircon grain in the East Guposhan unit (GP-1) yielded a 206Pb/238U age of 806.4 Ma, which is similar to the ages of the Jiulin cordierite granite in northern Jiangxi and of the Yinqiao migmatic granite in Guangxi in the HZH granite zone. All this may provide new evidence for Late Proterozoic magmatism in the HZH granite zone.     

对建筑场地类别划分方法的探讨

判定场地类别是岩土工程勘察要解决的主要问题之一。科学地确定场地类别可以用来指导建筑抗震设计。判定场地类别的方法目前主要依据规范法进行。在按规范法进行判定场地类别时,由于场地沉积土层的差异、建筑物基础埋深的不同或采用基础型式的不同、场地标高的不同,有时会产生一些矛盾。对这些矛盾提出了初步解决的建议,供业内人士参考及批评指正。     

初论塔里木盆地砂岩储层中SiO2的溶蚀类型及其机理

根据显微镜观察,塔里木盆地砂岩储层中SiO₂溶蚀分为石英颗粒边缘溶蚀、次生加大边溶蚀和交代溶蚀。通过对石英颗粒和加大边溶蚀特征及其与粘土矿物组合、与碳酸盐胶结、与古油藏破坏以及现今油田水中Si离子含量等关系的综合研究,这些SiO₂溶蚀可能存在两种机理:碱性环境下的SiO₂溶蚀和有机酸(烃类微生物降解产生的有机酸以及有机质成熟产生的有机酸)引起的SiO₂溶蚀。第一种溶蚀类型较普遍,但程度微弱;第二种溶蚀类型主要发生在古油藏破坏和有机质成熟过程中,这种溶蚀较强烈但很局限。SiO₂的溶蚀作用可以为油气提供一定量的储集空间,这对于深埋的时代较老的志留-泥盆系储层具有重要意义。在古油藏中尽管烃类已经充注储层孔隙,但只要孔隙中存在有机酸或碱性孔隙水,SiO₂的溶蚀和石英次生加大的胶结等作用仍可进行。     

榍石：U－Pb定年及变质P－T－t轨迹的建立

榍石在各类岩石中普遍存在，其稳定性受全岩成分、氧逸度和水活度以及温度和压力等因素影响。它在岩浆岩中主要存在于高Ca/Al比值的岩石中，在变质岩中常见于绿片岩相、蓝片岩相和角闪岩相岩石，在钙质变质岩中其稳定范围可达榴辉岩相或高压麻粒岩相。一般榍石结构中U含量较高，且具有高达高角闪岩相上限的U Pb同位素体系封闭温度，是理想的U-Pb定年矿物。由于榍石的组成元素均为岩石中的主要元素，很容易与其它矿物、熔体及流体发生反应，所以榍石的U-Pb年龄记录的更可能是结晶年龄，而不是简单的扩散重置年龄；也因为它容易反应，变质榍石复杂的U Pb体系可能记录了岩石的整个变质历史信息。通过与榍石平衡共生的矿物组合或利用榍石Zr温压计可确定岩石的P T条件，结合相关的榍石年龄信息即可建立变质过程的P T t轨迹。利用SHRIMP、LA MC ICP MS以及LA ICP MS方法可对不均一榍石颗粒内部进行原位微区分析得到有意义的U Pb年龄；利用榍石中Zr含量对温度，尤其是对压力比较敏感，可建立榍石Zr含量温压计。     

Geological analysis and FT dating of the large-scale right-lateral strike-slip movement of the Red River fault zone

Tectonically, the large-scale right-lateral strike-slip movement along the Red River fault zone is char-acterized at its late phase with the southeastward extension and deformation of the Northwestern Yunnan normal fault depression on its northern segment, and the dextral shear displacement on its central-southern segment. Research of the relations between stratum deformation and fault movement on the typical fault segments, such as Jianchuan, southeast Midu, Yuanjiang River, Yuanyang, etc. since the Miocene Epoch shows that there are two times dextral faulting dominated by normal shearing occurring along the Red River fault zone since the Miocene Epoch. The fission track dating (abbrevi-ated to FT dating, the same below) is conducted on apatite samples collected from the above fault segments and relating to these movements. Based on the measured single grain’s age and the con-fined track length, we choose the Laslet annealing model to retrieve the thermal history of the samples, and the results show that the fault zone experienced two times obvious shear displacement, one in 5.5 ± 1.5 MaBP and the other in 2.1± 0.8 MaBP. The central-southern segment sees two intensive uplifts of mountain mass in the Yuanjiang River-Yuanyang region at 3.6―3.8 MaBP and 1.6―2.3 MaBP, which correspond to the above-mentioned two dextral normal displacement events since the late Miocene Epoch.     

Microbialite of anoxic condition from Permian-Triassic transition in Guizhou,China

Spherical microfossils are present in the Hindeodus parvus zone of the Lower Triassic in Ziyun,Guizhou Province. They generally range from 0.15 to 0.30 mm across,with micritic wall and filled by micro-sparry calcites,and are evenly scattered in micritic matrix. Their abundance makes the rock as-signed to microbialites. The accompanied organisms include ostracods and algal mat,but no gastro-pods or bivalves. Presence of small (<7 μm) pyrite framboids indicates that this bed formed in anoxic conditions. In some sections,this bed is overlain and underlain by tidal-flat micritic limestone with microgastropods and small burrows. Occurrence only in deposits on reef top indicates that the micro-bial organism was benthic,and needed sunlight in life. The size of the microbial fossil exceeds that of any bacteria or cyanobacteria. Thus,it does not belong to these two phyla. It may belong to lower green algae,and is assigned to a new species in a new genus,Ziyunosphaeridium sinensis gen. et sp. nov. Up to now,the rocks described as microbialites from the Permian-Triassic transition include six types: (1) porous micritic limestone such as that descried from Japan by Sano and Nakashima (1997),(2) limestone with rich globular microfossils such as that described from the Nanpanjiang Basin in China by Lehrmann (1999),(3) dendroidal limestone such as that described from the vicinity of Chongqing by Kershaw et al. (1999),(4) spherical microbial limestone adapted to anoxic environments described from Ziyun,Guizhou reported in this paper,(5) limestone with cyanobacterial fossils such as that described by Wang et al. (2005),and (6) stromatolites. All these microbialites are not reefs in the proper sense,and the argument that Permian reef ecosystems extended into the Mesozoic is incorrect.     

哈萨克斯坦地震地下流体监测、预测的现状及其震兆异常特征的分析

40多年来,哈萨克斯坦地震地下流体观测台网历经初期建网、系统清理、政策调整和优化提高4个阶段,目前已形成与中国北京地区流体监测网相当的规模。分析了哈萨克斯坦流体监测台网的地位、台站分布、观测项目、仪器配置及地震分析预测情况。最后,分析了哈萨克斯坦地震地下流体观测资料的特点,并就哈萨克斯坦流体交换资料的震兆异常特征进行了初步总结。     

基于小波包变换的面波分离技术研究

依据面波视速度的分布范围,提出一种新的叠前面波分离技术,即把地震波场分成不受面波影响的波场和受面波影响的波场,然后利用小波包变换对受面波影响的波场进行时频分析,通过分解与重构,从中提取有效波,再将其与不受面波影响的波场合并,就可得到面波分离后的地震波场。该方法在成功分离面波的同时,可使有效波的能量(尤其是其低频能量)不受损失,既有效地保持信号的频宽不变,又提高了记录的信噪比。实际资料的处理结果表明:此方法在叠前面波分离方面具有有良好的效果。     

GDX-502树脂富集高效液相色谱法测定地表水中酚类化合物

采用自制GDX-502固相萃取小柱萃取水中苯酚、对硝基酚、间甲酚、2，4-二氯酚、2，4，6-三氯酚、五氯酚等6种酚类化合物，以乙腈作为洗脱剂，选择280nm和290nm双波长紫外高效液相色谱进行检测。结果表明，方法检出限为0．01-0．05mg／L，IL水的平均加标回收率为82．5％-95．0％，精密度（RSD，n=7）为3．6％-9．2％。方法用于实际地表水中痕量酚类化合物的检测，操作简单，有机溶剂用量少，分析效率高；萃取小柱可多次重复使用，分析成本低。     

长河煤矿充水因素分析及防治水措施

长河煤矿为地质构造中等复杂区，其矿区地质及水文地质条件表明，地表水、直接充水含水层煤系砂岩裂隙水、老窑水、构造断裂带水都可构成该矿井开采的充水因素，且其涌水量大小与大气降水关系密切。针对矿井开采的具体情况提出了一系列的防治措施，并取得了良好的效果，对煤矿水害的防治有一定的指导意义。