Geochemische Untersuchungen im Kalkalpinen Bleizinkerzbezirk

Zusammenfassung Eine geochemische Beprobung des triadischen Nebengesteines der kalkalpinen Blei-Zinklagerstätten ließ Zinkspurenhöfe von mehreren Metern Ausdehnung um die Erzkörper erkennen. Dies führte in der Grube zur Auffindung von Erz. Die regionale Aufnahme im Gelände zeigte die Bindung des Metallgehaltes an Verwerfungen.

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The triassic wallrocks of the Pb-Zn-deposits in the Kalkalpen are showing halos of zinc around the deposits. The halos have an extension of several meters and could be used for finding new ore bodies in the Mine of Bleiberg. A geochemical field survey proved the connection of the anomalies with certain faults.

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Résumé Les roches triasiques encaissant les gisements de plomb et zinc dans les Kalkalpen sont caractérisées par des auréoles de zinc, de quelques mètres d'épaisseur. Cela a conduit à la découverte du minerai dans les mines de Bleiberg. Le prélèvement géochimique sur le terrain a démontré la relation des anomalies avec certaines failles.

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On the sensitivity of the sedimentary system in the East Frisian Wadden Sea to sea-level rise and wave-induced bed shear stress

The paper addresses the individual and collective contribution of different forcing factors (tides, wind waves, and sea-level rise) to the dynamics of sediment in coastal areas. The results are obtained from simulations with the General Estuarine Transport Model coupled with a sediment transport model. The wave-induced bed shear stress is formulated using a simple model based on the concept that the turbulent kinetic energy (TKE) associated with wind waves is a function of orbital velocity, the latter depending on the wave height and water depth. A theory is presented explaining the controls of sediment dynamics by the TKE produced by tides and wind waves. Several scenarios were developed aiming at revealing possible trends resulting from realistic (observed or expected) changes in sea level and wave magnitude. The simulations demonstrate that these changes not only influence the concentration of sediment, which is very sensitive to the magnitude of the external forcing, but also the temporal variability patterns. The joint effect of tides and wave-induced bed shear stress revealed by the comparison between theoretical results and simulations is well pronounced. The intercomparison between different scenarios demonstrates that the spatial patterns of erosion and deposition are very sensitive to the magnitude of wind waves and sea-level rise. Under a changing climate, forcing the horizontal distribution of sediments adjusts mainly through a change in the balance of export and import of sediment from the intertidal basins. The strongest signal associated with this adjustment is simulated North of the barrier islands where the evolution of sedimentation gives an integrated picture of the processes in tidal basins.     

Upper Cretaceous Magmatic Series and Associated Mineralisation in the Carpathian – Balkan Orogen

Abstract: The Alpine Orogen contains in South East Europe, from the Carpathians to the Balkans–Srednogorie, an Upper Cretaceous, ore bearing igneous belt: a narrow elongated body which runs discontinously from the Apuseni Mountains in the North, to the western part of the South Carpathians (Banat) in Romania, and further South to the Carpathians of East Serbia and still further East to Srednogorie (Bulgaria). This results in a belt of 750 km/30–70 km, bending from N-S in Romania and Serbia, to E-W in Bulgaria. Using the well established century-old terminology of this region, we describe it in this paper as the Banatitic Magmatic and Metallogenetic Belt (BMMB). Plate tectonics models of the Alpine evolution of South East Europe involve Mesozoic rifting, spreading and thinning of the continental crust or formation of oceanic crust in the Tethian trench system, followed by Cretaceous-Tertiary convergence of Africa with Europe and opening of Eastern Mediterranean and Black Sea troughs. The result of successive stages in the collision process is not only the continental growth of Europe from N to S by the docking of several microplates formerly separated from it by Mesozoic palaeo–oceans, but also the rise of mountain belts by overthickening of the crust, followed by orogenic collapse, lateral extrusion, exhumation of metamorphic core complexes and post-collisional magmatism connected to strike-slip or normal faulting. The BMMB of the Carpathian-Balkan fold belt is rich in ore deposits related to plutons and/or volcano-plutonic complexes. Serbian authors have proposed an Upper Cretaceous Paleorift in Eastern Serbia for the Timok zone and some Bulgarian geologists have furnished geologic, petrological and metallogenetic support for this extensional model along the entire BMMB. The existence and importance of previous westwards directed subductions of Transilvanides (=South Apuseni = Mure? Zone) and Severin-Krajina palaeo–oceans, popular in Roman ian literature, seems to have little relevance to BMMB generation, but the well documented northwards directed subduction of the Vardar-Axios palaeo–ocean during Jurassic and Lower Cretaceous is a good pre-condition for the generation, during the Upper Cretaceous, of banatitic magmas in extensional regime, by mantle delamination due to slab break–off. Four magmatic trends are found: a tholeiitic trend, a calc-alkaline trend, a calc-alkaline high–K to shoshonitic trend and, restricted to East Srednogorie, a peralkaline trend. For acid intrusives, the typology is clearly I-type and magnetite–series, pointing to sources in the deep crust or the mantle; however, some high ⁸⁷Sr/⁸⁶Sr ratios recorded in banatites prove important contamination from the upper crust. The calc-alkaline hydrated magmas, most common for banatitic plutons, can be considered as recording three stages of evolution: more primitive – the monzodioritic, dioritic to granodioritic trend (S Apuseni, S Ba–nat, Timok, C and W Srednogorie); more evolved – the granodioritic-granitic trend (N Apuseni, N Banat, Ridanj–Krepoljin); the alkaline trend (E and W Srednogorie, western part of N Banat). Correlating the composition of the host plutons with the types of mineralisation, several environments can be found in the BMMB, function of timing of fluid separation (porphyry versus non-porphyry environments), depth of emplacement, size of intrusion and geology of intruded rock pile, biotite versus hornblende crystallisation, involving the evolution of K/Na ratio in fluids, i. e. development of potassic and phyllic alteration zones: a) non-porphyry environment with granodioritic to granitic magmas, plutonic level, skarn mineralisation prevails; b) porphyry environment with monzodioritic or dioritic to granodioritic magmas, subvolcanic–hypabyssal–plutonic level; porphyry Cu with skarn halo at hypabyssal-subvolcanic level; c) porphyry environment with monzodioritic or dioritic to granodioritic magmas, volcano-plutonic complexes with porphyry copper plus massive sulfide mineralisation at subvolcanic-volcanic level; d) non-porphyry environment with magmas of alkaline tendency, volcanic level, vein (“mesothermal” and “epithermal”) mineralisation.     

Zur Adsorptionsbehandlung von Abwässern eines pharmazeutischen Betriebes

The activity of two adsorbent polymers on the basis of polystyrene and of an activated carbon for the removal of organochlorine substances as well as of substances which are characterized by the COD-Cr or the ultraviolet absorption in the wastewater of a pharmaceutical enterprise is assessed in batch and filtration experiments. The results show a good take-up of the organochlorine compounds by the polymers. Activated carbon showed partially the best values for process wastewater.     

On the Elimination of Organic Microcontaminants by Flocculation with Lime Hydrate

For the purpose of utilizing domestic flocculants for the treatment of water and of reducing by this the equivalent imports of metal salts, in this paper the result of investigations made on model waters and on a river water sample is described. The model waters contained the pesticides Atrazin, Diuron and 2,4-D, which partly were polluted in addition with different quantities of fulvic and humic acids as well as with colloidal substances causing turbidity (Friedland clay and finely dispersed cellulose). The investigations were supplemented by testing several adsorption media as γ-aluminium oxide, active carbon and diatom earth. In the presence of fulvic and humic substances one does not succeed in eliminating the investigated herbicides by flocculation with lime hydrate. Only after chemical side reactions between these contained substances the adsorbability is clearly influenced. The different elimination efficiencies at different reaction conditions are explained in detail.     

Zur Elimination organischer Verbindungen durch Adsorberpolymere

An investigation is made into the performance of a commercial product (Wofatit EP 61) and of newly-developed experimental samples of macroporous adsorption polymers (copolymers of styrene and divinyl benzene) with a much larger specific surface in batch and filter experiments. Against organic adsorptives having the character of weak electrolytes, adsorption polymers show a significantly pH-dependent elimination capacity. Non-ionic or only weakly dissociated anionic adsorptives are removed by the experimental samples to a much higher degree than by the commercial adsorption polymer. Highly dissociated anionic compounds can be removed by activated carbon better than by macroporous adsorption polymers.     

Comparison of Two Probability Distributions Used to Model Sizes of Undiscovered Oil and Gas Accumulations: Does the Tail Wag the Assessment?

Undiscovered oil and gas assessments are commonly reported as aggregate estimates of hydrocarbon volumes. Potential commercial value and discovery costs are, however, determined by accumulation size, so engineers, economists, decision makers, and sometimes policy analysts are most interested in projected discovery sizes. The lognormal and Pareto distributions have been used to model exploration target sizes. This note contrasts the outcomes of applying these alternative distributions to the play level assessments of the U.S. Geological Survey's 1995 National Oil and Gas Assessment. Using the same numbers of undiscovered accumulations and the same minimum, medium, and maximum size estimates, substitution of the shifted truncated lognormal distribution for the shifted truncated Pareto distribution reduced assessed undiscovered oil by 16% and gas by 15%. Nearly all of the volume differences resulted because the lognormal had fewer larger fields relative to the Pareto. The lognormal also resulted in a smaller number of small fields relative to the Pareto. For the Permian Basin case study presented here, reserve addition costs were 20% higher with the lognormal size assumption.