Lattice distortion in a zircon population and its effects on trace element mobility and U–Th–Pb isotope systematics: examples from the Lewisian Gneiss Complex, northwest Scotland

Zircon is a key mineral in geochemical and geochronological studies in a range of geological settings as it is mechanically and chemically robust. However, distortion of its crystal lattice can facilitate enhanced diffusion of key elements such as U and Pb. Electron backscatter diffraction (EBSD) analysis of ninety-nine zircons from the Lewisian Gneiss Complex (LGC) of northwest Scotland has revealed five zircons with lattice distortion. The distortion can take the form of gradual bending of the lattice or division of the crystal into subgrains. Zircon lattices are distorted because of either post-crystallisation plastic distortion or growth defects. Three of the five distorted zircons, along with many of the undistorted zircons in the population, were analysed by ion microprobe to measure U and Pb isotopes, Ti and REEs. Comparison of Th/U ratio, ²⁰⁷Pb/²⁰⁶Pb age, REE profile and Ti concentration between zircons with and without lattice distortion suggests that the distortion is variably affecting the concentration of these trace elements and isotopes within single crystals, within samples and between localities. REE patterns vary heterogeneously, sometimes relatively depleted in heavy REEs or lacking a Eu anomaly. Ti-in-zircon thermometry records temperatures that were either low (~700 °C) or high (>900 °C) relative to undistorted zircons. One distorted zircon records apparent ²⁰⁷Pb/²⁰⁶Pb isotopic ages (?3.0 to +0.3 % discordance) in the range of ~2,420–2,450 Ma but this does not correlate with any previously dated tectonothermal event in the LGC. Two other distorted zircons give discordant ages of 2,331 ± 22 and 2,266 ± 40 Ma, defining a discordia lower intercept within error of a late amphibolite-facies tectonothermal event. This illustrates that Pb may be mobilised in distorted zircons at lower metamorphic grade than in undistorted zircons. These differences in trace element abundances and isotope systematics in distorted zircons relative to undistorted zircons are generally interpreted to have been facilitated by subgrain walls. Trace elements and isotopes would have moved from undistorted lattice into these subgrain walls as their chemical potential is modified due to the presence of the dislocations which make up the subgrain wall. Subgrain walls provided pathways for chemical exchange between crystal and surroundings. Only five per cent of zircons in this population have lattice distortion suggesting it will not have a major impact on zircon geochronology studies, particularly as three of the five distorted zircons are from strongly deformed rocks not normally sampled in such studies. However, this does suggest there may be a case for EBSD analysis of zircons prior to geochemical analysis when zircons from highly deformed rocks are to be investigated.     

Environmental Determinants of Emergent Macrophyte Vegetation in Pacific Northwest Estuarine Tidal Wetlands

We investigated whether within wetland environmental conditions or surrounding land cover measured at multiple scales were more influential in structuring regional vegetation patterns in estuarine tidal wetlands in the Pacific Northwest, USA. Surrounding land cover was characterized at the 100, 250, and 1,000 m, and watershed buffer scales. Vegetation communities were characterized by high species richness, lack of monotypic zonation, and paucity of invasive species. The number of species per site ranged between 4 and 20 (mean?±?standard deviation?=?10.2?±?3.1). Sites supported a high richness (mean richness of native species 8.7?±?2.8) and abundance of native macrophytes (mean relative abundance 85 %?±?19 %). Vegetation assemblages were dominated by a mix of grasses, sedges, and herbs with Sarcocornia pacifica and Distichlis spicata being common at sites in the oceanic zone of the estuary and Carex lyngbyei and Agrostis stolonifera being common at the fresher sites throughout the study area. The vegetation community was most strongly correlated with salinity and land cover within close proximity to the study site and less so with land cover variables at the watershed scale. Total species richness and richness of native species were negatively correlated with the amount of wetland in the buffer at all scales, while abundance of invasive species was significantly correlated to within wetland factors, including salinity and dissolved phosphorus concentrations. Landscape factors related to anthropogenic disturbances were only important at the 100-m buffer scale, with anthropogenic disturbances further from the wetland not being influential in shaping the vegetation assemblage. Our research suggests that the traditional paradigms of tidal wetland vegetation structure and environmental determinants developed in east coast US tidal wetlands might not hold true for Pacific Northwest wetlands due to their unique chemical and physical factors, necessitating further detailed study of these systems.     

A discontinuous Galerkin method for two-phase flow in a porous medium enforcing H(div) velocityand continuous capillary pressure

We consider the slightly compressible two-phase flow problem in a porous medium with capillary pressure. The problem is solved using the implicit pressure, explicit saturation (IMPES) method, and the convergence is accelerated with iterative coupling of the equations. We use discontinuous Galerkin to discretize both the pressure and saturation equations. We apply two improvements, which are projecting the flux to the mass conservative H(div)-space and penalizing the jump in capillary pressure in the saturation equation. We also discuss the need and use of slope limiters and the choice of primary variables in discretization. The methods are verified with two- and three-dimensional numerical examples. The results show that the modifications stabilize the method and improve the solution.     

Flux and dispersion of gases from the “Drachenschlund” hydrothermal vent at 8°18' S, 13°30' W on the Mid-Atlantic Ridge

Hydrothermal emission of mantle helium appears to be directly related to magma production rate, but other processes can generate methane and hydrogen on mid-ocean ridges. In an on-going effort to characterize these processes in the South Atlantic, the flux and distribution of these gases were investigated in the vicinity of a powerful black smoker recently discovered at 8°17.9' S, 13°30.4' W. The vent lies on the shoulder of an oblique offset in the Mid-Atlantic Ridge and discharges high concentrations of methane and hydrogen. Measurements during expeditions in 2004 and 2006 show that the ratio of CH₄ to ³He in the neutrally buoyant plume is quite high, 4 × 10⁸. The CTD stations were accompanied by velocity measurements with lowered acoustic Doppler current profilers (LADCP), and from these data we estimate the methane transport to have been 0.5 mol s^− 1 in a WSW-trending plume that seems to develop during the ebb tidal phase. This transport is an order of magnitude greater than the source of CH₄ calculated from its concentration in the vent fluid and the rise height of the plume. From this range of methane fluxes, the source of ³He is estimated to be between 0.14 and 1.2 nmol s^− 1. In either case, the ³He source is significantly lower than expected from the spreading rate of the Mid-Atlantic Ridge. From the inventory of methane in the rift valley adjacent to the vent, it appears that the average specific rate of oxidation is 2.6 to 23 yr^− 1, corresponding to a turnover time between 140 and 16 days. Vertical profiles of methane in the surrounding region often exhibited Gaussian-like distributions, and the variances appear to increase with distance from the vent. Using a Gaussian plume model, we obtained a range of vertical eddy diffusivities between 0.009 and 0.08 m²m² s^− 1. These high values may be due to tidally driven internal waves across the promontory on which the vent is located.     

Structural features of Panarea volcano in the frame of the Aeolian Arc (Italy): Implications for the 2002–2003 unrest

Panarea, characterized by gas unrest in 2002–2003, is the volcanic island with the least constrained structure in the eastern-central Aeolian Arc (Italy). Based on structural measurements, we define here its deformation pattern relative to the Arc. The main deformations are subvertical extension fractures (63% of data), normal faults (25%) and dikes (12%). The mean orientation of the extension fractures and faults is N38°E, with a mean opening direction of N135° ± 8°, implying extension with a moderate component of dextral shear. These data, matched with those available for Stromboli volcano (pure opening) and Vulcano, Lipari and Salina volcanoes (predominant dextral motions) along the eastern-central Arc, suggest a progressive westward rotation of the extension direction and an increase in the dextral shear. The dextral shear turns into compression in the western arc. The recent unrest at Panarea, coeval to that of nearby Stromboli, may also be explained by the structural context, as both volcanoes lie along the portion of the Arc subject to extension.     

The Evolution of the Interstellar Medium over Cosmic Time

C23 UV spectroscopy of the PG1159-type star NGC7094 C26 Variations of the radio synchrotron spectral index in the interstellar medium of M33 C38 Angular Momentum Evolution of Young Brown Dwarfs and Low Mass Stars C48 The radio halo of the nearby starburst galaxy NGC 253 C95 Signatures of early metal enrichment in Damped-Lyman Alpha systems C113 CO 4 → 3 and [CI] 1 → 0 in the centers of NGC4945 and Circinus C115 Ratio of atomic and molecular gas and gravitational stabilty in the disk of M51 C130 The Interstellar Mediumat Early Cosmic Times: Molecular Gas in Distant Quasar Host Galaxies C188 Probing the interstellar medium in distant galaxies with SPICA/ESI C191 The evolution of spectral energy distributions of galaxies over cosmic times C197 Observations of 60Fe in the Galaxy with INTEGRAL/SPI C204 Evolution of Interstellar Clouds in a hot Gas Environment C205 The effect of clouds in a galactic wind on the evolution of gas-rich dwarf galaxies C206 Energy and element deposit into the interstellar medium during the lives of massive stars C209 The distribution and kinematics of massive stars in the inner Galaxy mapped with SPI/INTEGRAL 26Al 1.8 MeV line observations C213 PDR modelling of the Galactic FIR line emission C239 Towards a complete picture of the molecular ISM in local Luminous Infrared Galaxies: first results from the JCMT/IRAM line survey C242 The Search for the Very High-redshift Tail of Submillimeter Galaxies     

Albite crystallographic preferred orientation and grain misorientation distribution in a low-grade mylonite: implications for granular flow

Crystallographic orientation data from pure albite domains in a low-grade sheared metagabbro from the Combin Zone of the western Italian Alps were measured by electron backscatter diffraction. Crystallographic preferred orientations (CPOs) in four high-strain domains are non-random and have a triclinic symmetry. The clusters of [100], [010] and [001] show an angular relationship that corresponds to that of the albite crystal lattice. However, the orientations of axis clusters to the kinematic axes vary from domain to domain. CPOs from a low-strain domain also show clustered axes with triclinic symmetry, but with more intense clustering than those in the high-strain domains. Grain misorientation distributions are presented both for the low-strain domain and one of the high-strain domains. In the high-strain domain, the distribution of misorientation angles between neighbouring grains displays a peak at about 70°. The equivalent distribution in the low-strain domain has a peak at 30°. For both domains, the misorientation axis distributions, between neighbouring and non-neighbouring grains, are random, except for some of axes with 160–180° misorientation that exhibit a slight concentration around [010]. The diversity of CPOs among the domains suggests that these CPOs could not be produced by dislocation creep. They are likely to have been inherited from plagioclase parents, as a result of host control on the nucleation of the new albite grains. These CPOs do not contain any direct information about the deformation kinematics. We interpret that deformation of these domains occurred by granular flow. Crystallographic axis dispersion due to grain boundary sliding (GBS) caused weakening of CPOs, modification of misorientation angle distributions and randomisation of misorientation axis distributions. The fact that a CPO can survive GBS even after a high strain indicates that CPO is not always a sensitive indicator of deformation mechanisms. Misorientation distribution may provide a complementary, and possibly a more sensitive indicator of deformation mechanisms.     

Part II. Discontinuous Galerkin method applied to a single phase flow in porous media

Discontinuous Galerkin numerical simulations of single phase flow problem are described in this paper. The simulations show the advantages of using discontinuous approximation spaces. hp convergence results are obtained for smooth solutions. Unstructured meshes and unsmooth solutions are also considered.     

上部地壳的流体作用与大理岩的低温塑性

本文应用光学显微镜、透射电子显微镜和阴极发光显微镜系统研究了Ｗａｔｅｒｂｅｒｇ断层带（纳米比亚）内粗晶大理岩中发育的构造岩,宏观碎裂结构与微观糜棱装结构是断层构造岩的主要特点。巨大的孪形碎屑与弥漫的细小粒质形成了鲜明的反差,广泛发育的压溶颖合线与多阶段方解石细脉遍布构造带不同部位,ＴＥＭ亚微粒粒度具有简单的峰值分布（～０．３～０．４μｍ）,但动态重结晶颗粒的粒度却具有较大的变化范围（０．１～３．０