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Bildung von Kondensationskernen durch UV-Strahlung in verschiedenen Gasen

Zusammenfassung Die Erzeugung von Kondensationskernen durch UV-Licht wurde mittels eines automatischenPollakschen Kernzählers und einerWilsonkammer aus Glas untersucht. Da die UV-Kerne von einem Schwebstoffilter zurückgehalten werden, ließ sich durch Verwendung zweier Bestrahlungsgefäße mit dazwischengeschaltetem Filter die Spurengashypothese bestätigen. Bestrahlungsversuche in Luft, Stickstoff, Sauerstoff, Argon und Wasserstoff ergaben, daß durch längere Bestrahlung eines abgeschlossenen Gasvolumens die kernbildende Substanz allmählich verbraucht wird. Durch Zugabe definierter Mengen gasförmigen Ammoniaks in den Bestrahlungsraum zeigte sich, daß die von verschiedenen Autoren geäußerte Ansicht, gasförmiges Ammoniak sei die kernbildende Substanz, nicht haltbar ist. Die Untersuchung des Einflusses von Schwefelwasserstoff bzw. Schwefeldioxyd ergab, daß die atmosphärische Konzentration von H₂S zur Erklärung des UV-Effektes nicht ausreicht, während dies bei SO₂ der Fall ist. Das Ergebnis, daß SO₂ maßgebend an der Bildung der UV-Kerne in atmosphärischer Luft beteiligt ist, wird dadurch gestützt, daß der UV-Effekt einen ähnlichen Tagesgang zeigt wie das atmosphärische SO₂.

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Summary The production of condensation nuclei by UV light was investigated by means of an automaticPollak nucleus counter and aWilson glass-chamber. As the UV nuclei can be removed by an aerosol filter, the trace gas hypothesis could be confirmed by using two irradiation tubes separated by an aerosol filter. Irradiation experiments in air, nitrogen, oxygen, argon and hydrogen in a closed volume had the result that the nucleogenic substance gradually disappears after sufficiently long irradiation. By adding definite quantities of ammonia vapour into the irradiation tube it could be shown that ammonia is not the nucleogenic substance, as was supposed by some authors. The investigation of the influence of sulphur dioxide and hydrogen sulfide showed that the atmospheric concentration of H₂S is not sufficient to explain the UV effect in atmospheric air, whereas this is true with SO₂. The result that SO₂ takes part in the formation of the UV nuclei is supported by the fact that SO₂ and the UV effect show a similar diurnal variation.

     

Mean and Turbulent Flow Statistics in a Trellised Agricultural Canopy

Flow physics is investigated in a two-dimensional trellised agricultural canopy to examine that architecture’s unique signature on turbulent transport. Analysis of meteorological data from an Oregon vineyard demonstrates that the canopy strongly influences the flow by channelling the mean flow into the vine-row direction regardless of the above-canopy wind direction. Additionally, other flow statistics in the canopy sub-layer show a dependance on the difference between the above-canopy wind direction and the vine-row direction. This includes an increase in the canopy displacement height and a decrease in the canopy-top shear length scale as the above-canopy flow rotates from row-parallel towards row-orthogonal. Distinct wind-direction-based variations are also observed in the components of the stress tensor, turbulent kinetic energy budget, and the energy spectra. Although spectral results suggest that sonic anemometry is insufficient for resolving all of the important scales of motion within the canopy, the energy spectra peaks still exhibit dependencies on the canopy and the wind direction. These variations demonstrate that the trellised-canopy’s effect on the flow during periods when the flow is row-aligned is similar to that seen by sparse canopies, and during periods when the flow is row-orthogonal, the effect is similar to that seen by dense canopies.     

40Ar/39Ar Thermochronology west of the Main Uralian fault, southern Urals, Russia

West of the Main Uralian fault, the main suture in the southern Urals, ⁴⁰Ar/³⁹Ar apparent ages of amphibole, muscovite and potassium feldspar are interpreted as cooling ages. A fast exhumation of the metamorphic complex of Kurtinsky during Upper Carboniferous time is indicated by the small age difference (15 Ma) between cogenetic amphibole and muscovite. Differentiated movement in the footwall of the Main Uralian fault along strike is indicated by the age difference of 70 Ma between the metamorphic complexes of Kurtinsky (north) and Maksyutov (south). No Upper Paleozoic (Uralian) medium- to high-temperature event is recorded in ⁴⁰Ar/³⁹Ar data from the metamorphic complex of Beloretzk (MCB). An amphibole age of 718±5 Ma and the occurrence of mafic intrusions might signal the break-up of Rodinia and therefore indicate the rifting period followed by the separate movement of the "Beloretzk terrane". Muscovite ages of approximately 550±5 Ma, the unique pre-Ordovician tectonometamorphic evolution of the MCB and the Late Vendian sedimentary history of the western Bashkirian Megaanticlinorium (BMA) imply the existence of a Neoproterozoic orogeny at the eastern margin of Baltica. This orogeny might have been initiated by the accretion of the "Beloretzk terrane". The metamorphic grade of the overlain Silurian shales and the K/Ar microcline ages from the "Beloretzk terrane" give evidence for a new thermal event at approximately 370 Ma. A microcline age of 530–550 Ma obtained for the Vendian conglomerate in the western BMA suggests that a maximum temperature of approximately 200°C was reached in Cambrian or Vendian times. An orthoclase age (590–630 Ma) of the Vendian Zigan flysch deposits might be inherited from the eastern source area, the Cadomian orogen. An orthoclase age (910–950 Ma) from the Riphean Zilmerdak conglomerate coincides with a documented decrease in the subsidence rate of the Upper Riphean basin.     

Compound‐Specific Isotope Analyses to Assess TCE Biodegradation in a Fractured Dolomitic Aquifer

The potential for trichloroethene (TCE) biodegradation in a fractured dolomite aquifer at a former chemical disposal site in Smithville, Ontario, Canada, is assessed using chemical analysis and TCE and cis‐DCE compound‐specific isotope analysis of carbon and chlorine collected over a 16‐month period. Groundwater redox conditions change from suboxic to much more reducing environments within and around the plume, indicating that oxidation of organic contaminants and degradation products is occurring at the study site. TCE and cis‐DCE were observed in 13 of 14 wells sampled. VC, ethene, and/or ethane were also observed in ten wells, indicating that partial/full dechlorination has occurred. Chlorine isotopic values (δ³⁷Cl) range between 1.39 to 4.69‰ SMOC for TCE, and 3.57 to 13.86‰ SMOC for cis‐DCE. Carbon isotopic values range between ?28.9 and ?20.7‰ VPDB for TCE, and ?26.5 and ?11.8‰ VPDB for cis‐DCE. In most wells, isotopic values remained steady over the 15‐month study. Isotopic enrichment from TCE to cis‐DCE varied between 0 and 13‰ for carbon and 1 and 4‰ for chlorine. Calculated chlorine‐carbon isotopic enrichment ratios (?_Cl/?_C) were 0.18 for TCE and 0.69 for cis‐DCE. Combined, isotopic and chemical data indicate very little dechlorination is occurring near the source zone, but suggest bacterially mediated degradation is occurring closer to the edges of the plume.     

Debris-flow-dominated sediment transport through a channel network after wildfire

Field studies that investigate sediment transport between debris-flow-producing headwaters and rivers are uncommon, particularly in forested settings, where debris flows are infrequent and opportunities for collecting data are limited. This study quantifies the volume and composition of sediment deposited in the arterial channel network of a 14-km² catchment (Washington Creek) that connects small, burned and debris-flow-producing headwaters (<1 km²) with the Ovens River in SE Australia. We construct a sediment budget by combining new data on deposition with a sediment delivery model for post-fire debris flows. Data on deposits were plotted alongside the slope–area curve to examine links between processes, catchment morphometry and geomorphic process domains. The results show that large deposits are concentrated in the proximity of three major channel junctions, which correspond to breaks in channel slope. Hyperconcentrated flows are more prominent towards the catchment outlet, where the slope–area curve indicates a transition from debris flow to fluvial domains. This shift corresponds to a change in efficiency of the flow, determined from the ratio of median grain size to channel slope. Our sediment budget suggests a total sediment efflux from Washington Creek catchment of 61 × 10³ m³. There are similar contributions from hillslopes (43 ± 14 × 10³ m³), first to third stream order channel (35 ± 12 × 10³ m³) and the arterial fourth to fifth stream order channel (31 ± 17 × 10³ m³) to the total volume of erosion. Deposition (39 ± 17 × 10³ m³) within the arterial channel was higher than erosion (31 ± 17 × 10³ m³), which means a net sediment gain of about 8 × 10³ m³ in the arterial channel. The ratio of total deposition to total erosion was 0.44. For fines <63 μm, this ratio was much smaller (0.11), which means that fines are preferentially exported. This has important implications for suspended sediment and water quality in downstream rivers. © 2019 John Wiley & Sons, Ltd.