Glacially crushed quartz grains in loess as indicators of long-distance transport from major European ice centers during the Pleistocene

Detailed mineralogical analysis of the fine and very fine sand fractions (63–250) in the Dreihausen Loess Sequence shows the presence of numerous glacially crushed grains, including a significant amout of quartz. Previous theories regarding the origin of loesses in central Germany held that all sediments were derived locally, following short-distance transport from nearby sandstone outcrops. New data presented here show that many quartz and feldspar grains were glacially crushed, weathered, crushed again, transported, and emplaced by aeolian processes at Dreihausen. Crushing features observed are compatible with transport in both continental and alpine glaciers; some clasts show the effects of abrasion by both water and ice transport, while others are partly rounded presumably by fluvial and/or aeolian processes. Stronger palewind systems during the Pleistocene presumably contributed to the transport and emplacement of glacial grains from ice centers in both the Alps and the Baltic areas, and also possibly from the Rhine Basin.     

Development of a technique to decompose heterogeneous mapping units in a categorical map of the biotic environment using correlated categorical data

In this article a technique is presented to estimate the proportions of different map categories in a series of heterogeneous mapping units, using information on the degree of spatial correlation with other categorical data. The technique has been applied to decompose ecotope complexes in a categorical map of the biotic environment in Flanders, using secondary information on land cover and soil type. Because the conditional probability of an ecotope occurring given a certain soil type depends on the frequency with which the ecotope occurs in an area, determining the probability of occurrence of an ecotope from the conditional probabilities can lead to predictions that contradict prior knowledge about the composition of the different mapping units. A measure expressing the affinity of an ecotope for a soil type is proposed and is used as an alternative to conditional probability in the estimation procedure. The proposed method has been tested in a study area for which detailed field observations were collected, and proves to work well if reliable a priori knowledge about the composition of complex mapping units is available.     

Platinum-group Elements and Microstructures of Normal Merensky Reef from Impala Platinum Mines, Bushveld Complex

The Merensky Reef of the Bushveld Complex contains one of theworld’s largest concentrations of platinum-group elements(PGE). We have investigated ‘normal’ reef, its footwalland its hanging wall at Impala Platinum Mines. The Reef is 46cm thick and consists from bottom to top of leuconorite, anorthosite,chromitite and a very coarse-grained melanorite. The footwallis leuconorite and the hanging wall is melanorite. The onlyhydrous mineral present is biotite, which amounts to 1%, orless, of the rock. All of the rocks contain 0·1–5%interstitial sulphides (pyrrhotite, pentlandite and chalcopyrite),with the Reef rocks containing the most sulphides (1–5%).Lithophile inter-element ratios suggest that the magma fromwhich the rocks formed was a mixture of the two parental magmasof the Bushveld Complex (a high-Mg basaltic andesite and a tholeiiticbasalt). The Reef rocks have low incompatible element contentsindicating that they contain 10% or less melt fraction. Nickel,Cu, Se, Ag, Au and the PGE show good correlations with S inthe silicate rocks, suggesting control of the abundance of thesemetals by sulphides. The concentration of the chalcophile elementsand PGE in the silicate rocks may be modelled by assuming thatthe rocks contain sulphide liquid formed in equilibrium withthe evolving silicate magma. It is, however, difficult to modelthe Os, Ir, Ru, Rh and Pt concentrations in the chromititesby sulphide liquid collection alone, as the rocks contain 3–4times more Os, Ir, Ru, Rh and Pt than the sulphide-collectionmodel would predict. Two possible solutions to this are: (1)platinum-group minerals (PGM) crystallize from the sulphideliquid in the chromitites; (2) PGM crystallize directly fromthe silicate magma. To model the concentrations of Os, Ir, Ru,Rh and Pt in the chromitites it is necessary to postulate thatin addition to the 1% sulphides in the chromitites there isa small quantity (0·005%) of cumulus PGM (laurite, cooperiteand malanite) present. Sulphide liquids do crystallize PGM atlow f_S2. Possibly the sulphide liquid that was trapped betweenthe chromite grains lost some Fe and S by reaction with thechromite and this provoked the crystallization of PGM from thesulphide liquid. Alternatively, the PGM could have crystallizeddirectly from the silicate magma when it became saturated inchromite. A weakness of this model is that at present the exactmechanism of how and why the magma becomes saturated in PGMand chromite synchronously is not understood. A third modelfor the concentration of PGE in the Reef is that the PGE arecollected from the underlying cumulus pile by Cl-rich hydrousfluids and concentrated in the Reef at a reaction front. Althoughthere is ample evidence of compaction and intercumulus meltmigration in the Impala rocks, we do not think that the PGEwere introduced into the Reef from below, because the rocksunderlying the Reef are not depleted in PGE, whereas those overlyingthe Reef are depleted. This distribution pattern is inconsistentwith a model that requires introduction of PGE by intercumulusfluid percolation from below. KEY WORDS: Merensky Reef; platinum-group elements; chalcophile elements; microstructures     

Giant Holocene Freshwater Microbialites,Laguna Bacalar,Quintana Roo,Mexico

With more than 10 km of total length, Holocene microbialites in Laguna Bacalar, Mexico, belong to the largest freshwater microbialite occurrences. Microbialites include domes, ledges and oncolites. Domal forms can grow to diameters and heights of 3 m. Microbialites are composed of low magnesium calcite which is, to a large extent, precipitated due to the metabolic activity of the cyanobacteria Homeothrix and Leptolyngbya, and associated diatoms. Photosynthesis removes carbon dioxide and triggers carbonate precipitation. Also, an elevated carbonate concentration in lagoon waters, derived from dissolution of Cenozoic limestone in a karst system, supports carbonate precipitation. Trapping and binding of detrital grains is also observed, but is not as common as precipitation. Bacalar microbialites are largely thrombolitic, however, stromatolitic sections occur as well. The bulk of Bacalar microbialites probably formed in the Late Holocene (ca 1 kyr BP until present). According to ¹⁴C dating, microbialites accreted 9 to 8 cal kyr BP; however, these ages may be too old as a result of a strong hard water effect. This effect is seen in ¹⁴C ages of living bivalve and gastropod mollusc shells from Bacalar Lagoon, which are 8 to 7 cal kyr BP. The modern associated fauna of microbialites is characterized by low diversity and high abundance of the bivalve mollusc Dreissena sp. and the gastropod Pomacea sp. The abundant grazing gastropods presumably hamper modern microbialite formation. A comparison of Bacalar microbialites with other modern microbialite occurrences worldwide shows only a few patterns: sizes, shapes, microbial taxa, mineralogy, type of accretion and settings including water properties of microbialite occurrences exhibit high variability. A trend may be seen in the grazing metazoa, which are rare to absent in the marine and brackish examples, but apparently present in all the freshwater occurrences of microbialites. Also, freshwater examples are usually characterized by elevated concentrations of carbonate and/or calcium ions in the surrounding waters.     

EARLY VOID-FILLING CEMENTATION IN DEVONIAN FORE-REEF LIMESTONES (GERMANY)

SUMMARY
Fibrous calcite is the main cement in the voids and cavities of Devonian fore-reef limestones in Germany. Cementation occurs in some cases simultaneously with encrustation by blue-green algae as well as internal deposition of calcarenites and calcilutites. These observations lead to the conclusion that the fore-reef voids were exposed to light and were still in free communication with the sea, when the cementation began. Furthermore, redeposited fragments of former cavity fillings indicate that the formation of cavity-filling fibrous calcium carbonate cement was already completed before the sea-ward erosion took place. It is believed that the precipitation of fibrous calcium carbonate in most of the Devonian fore-reef limestones, which show no signs of dissolution, occurred in a shallow subtidal environment. Only the voids showing larger solution phenomena were probably exposed to fresh water in the inter- to supratidal zone.     

The early Holocene Saksunarvatn tephra found in lake sediments in NW Germany

A basaltic tephra layer consisting of brownish-olive glass shards. and about 0.2 mm thick. was found in cores from four lakes in northwest Germany. According to pollen analysis it was deposited during the early Boreal period (corresponding to about 8700 BP). The petrographic properties. the geochemical composition and the age agree with those of the Saksunarvatn tephra. which was first found on the Faroe Islands. The position of the tephra layer in the pollen stratigraphy and in the absolute time-scale is discussed. Procedures for locating the tephra in other cores are suggested.     

Retrieval of aerosol optical thickness for desert conditions using MERIS observations during the SAMUM campaign

Approximately 30% of the land surface is arid, having desert or semi-desert conditions. Aerosol originating from these regions plays a significant role in climate and atmospheric chemistry of the atmosphere. Retrieving aerosol properties from space-borne platforms above desert conditions, where the surface reflectance is usually very bright, is a challenging task. The proportion of the surface to top of atmosphere (TOA) reflectance can reach values over 90%, especially for wavelength above 500 nm. For these reasons detailed knowledge of aerosol and surface optical properties from these regions is required to separate atmosphere from intrinsically bright surfaces.
An approach to retrieve aerosol properties over arid and semi-arid regions based on the Bremen Aerosol Retrieval (BAER) has been developed and validated within the Dust Aerosol Retrievals from Space-Born Instruments (DREAMS) Project, which is part of the Saharan Mineral Dust Experiment ( SAMUM, 2006 ). Combining measurements of the backscattered radiation from the Medium Resolution Imaging Spectrometer (MERIS) instrument aboard Environmental Satellite (ENVISAT) and ground-based measurements in Morocco in radiation closure experiments yields the aerosol optical properties of mineral dust at selected locations.     

Isolated stationary carbonate platforms: the Middle Triassic (Ladinian) of the Marmolada area, Dolomites, Italy

As a result of a phase of extensional tectonics in the western Tethyan region, a horst and graben topography formed during the Middle Triassic (Ladinian) in northern Italy. Horsts were sites of shallow water carbonate sedimentation, while pelagic and volcaniclastic sediments were deposited in the grabens. Two carbonate platforms approximately 500 m thick can be distinguished in the Marmolada area of the Dolomites: the Marmolada platform proper, which covered an area of 6 km², and the Costabella platform, which extended for about 12 km in a NW-SE direction and was about 3 km across. The facies of these isolated platforms reflect the influence of storms from the SW. Windward platform margins were characterized by a marine sand belt of skeletal and aggregate grainstones with a dominant platform directed cross-stratification. The central portions of the platforms were occupied by supratidal sand cays which are made up of storm washovers. Leeward parts of the platforms are composed of shallow subtidal sand flat deposits. Laterally discontinuous reefs chiefly composed of various calcareous algae are developed at the outer margins of the platforms. Along windward margins, reefs may form a belt several hundred metres wide; along leeward margins their width is commonly reduced to some tens of metres. Foreslope talus breccias surround the platforms. Clinoform bedding showing basinward dips of 30°-40° is typical of this facies belt, which is approximately 2 km wide. Basinal sediments, only some tens of metres thick, are radiolarian micrites. Abundant sediment-gravity-flow deposits expand the basinal sequence at the toes of windward margins and were probably triggered by storm return flows. Synsedimentary faults striking both NNE-SSW and NW-SE separate the bedded platform limestones from flank deposits and reefs. They account for the stationary nature of the platforms. Neptunian dykes show preferred NNE-SSW and E-W trends. Sinistral displacements are associated with NW-SE trending faults. Depressions in the basins, filled with red, turbiditic pelagic sediments, show N-S trends and are probably compressional in origin. The structural pattern may have resulted from oblique, NW-SE oriented extension of the E-W trending Middle Triassic graben zone of the Dolomites. In the Ladinian of the Dolomites, the stationary platform type can be distinguished from a retrograding type, whereas continuously prograding platforms apparently did not develop.