Detection of a new interstellar molecule, H2CN

We have detected a new interstellar molecule, H2CN (methylene amidogen), in the cold, dark molecular cloud TMC-l. The column density of H2CN is estimated to be approximately 1.5 x 10(11) cm-2 by assuming an excitation temperature of 5 K. This column density corresponds to a fractional abundance relative to H2 of approximately 1.5 x 10(-11). This value is more than three orders of magnitude less than the abundance of the related molecule HCN in TMC-1. We also report a tentative detection of H2CN in Sgr B2(N). The formation mechanism of H2CN is discussed. Our detection of the H2CN molecule may suggest the existence of a new series of carbon-chain molecules, CH2CnN (n = 0, 1, 2,...).     

Chemistry of the organic-rich hot core G327.3-0.6

We present gas-phase abundances of species found in the organic-rich hot core G327.3-0.6. The data were taken with the Swedish-ESO Submillimetre Telescope (SEST). The 1-3 mm spectrum of this source is dominated by emission features of nitrile species and saturated organics, with abundances greater than those found in many other hot cores, including Sgr B2 and OMC-1. Population diagram analysis indicates that many species (CH3CN, C2H3CN, C2H5CN, CH3OH, etc.) have hot components that originate in a compact (~2") region. Gas-phase chemical models cannot reproduce the high abundances of these molecules found in hot cores, and we suggest that they originate from processing and evaporation of icy grain mantle material. In addition, we report the first detection of vibrationally excited ethyl cyanide and the first detection of methyl mercaptan (CH3SH) outside the Galactic center.     

Cyanide and isocyanide abundances in the cold, dark cloud TMC-1

We have observed emission from HCN, H13CN, HC15N, HN13C, H15NC, HC3N, CH3CN, and possibly CH3NC, and determined an upper limit for NH2CN, toward the cold, dark cloud TMC-1. The abundance ratio [HNC]/[HCN] = 1.55 +/- 0.16 is at least a factor approximately 4 and approximately 100 greater than that observed toward the giant molecular clouds DR 21(OH) and Orion KL, respectively. In contrast, for the corresponding methylated isomers we obtain [CH3NC]/CH3CN] < or approximately 0.1. We also find [NH2CN]/[CH3CN] < or approximately 0.1 and [HC3N]/[CH3CN] = 30 +/- 10. We find no evidence for anomalous hyperfine ratios for H13CN, indicating that the ratios for HCN (cf. recent work of Walmsley et al.) are the result of self-absorption by cold foreground gas.     

Tricarbon monoxide in TMC-1

We report the measurement of three new lines of C3O in TMC-1. The observed peak antenna temperatures, appropriately corrected for atmospheric and telescope losses, are found to be consistent with a large velocity gradient radiative transfer model whose parameters span the range of standard values for this cloud. The derived fractional abundance for C3O is 1.4 x 10(-10), comparable with the results predicted from a model calculation based on a gas-phase ion-molecule reaction scheme. The results of negative searches for C3O in six other sources are not inconsistent with expected conditions in these clouds.     

The C3H2 2(20)-2(11) transition: absorption in cold dark clouds

The first observations of the 2(20)-2(11) transition of cyclopropenylidene (C3H2) at 21.6 GHz are described. In all cases where it has been detected, the line appears in absorption, showing that this transition is "refrigerated" (i.e., Tex < 2.7 K) in cold dust clouds. These results are compared with those for the 1(10)-1(01) transition of C3H2, and the consequences for the excitation of C3H2 qualitatively discussed.     

New interstellar masers in nonmetastable ammonia

We report the astronomical detections of several ammonia inversion transitions involving nonmetastable levels with energies as high s 1090 K above the ground state. The (J, K) = (9, 6) inversion transition shows maser-like emission in the directions of W51, NGC 7538, W49, and DR 21(OH). The NH3 (6, 3) line exhibits similar characteristics in W51 but is seen in absorption in NGC 7538. These are the first definite detections of ammonia masers in space. The intensities and narrow line widths (0.5-1.5 km s-1) for the emission features are in contrast to the previously detected broad, weak, nonmetastable lines attributed to thermal emission in these sources. Temporal variability appears to be evident in the (9, 6) emission in W49 over a 4 month period. The highly excited (J, K) = (9, 6) and (6, 3) ammonia lines are found in regions containing compact H II regions and strong infrared sources with associated H2O and OH masers; i.e., in regions of active star formation.     

浙江沿岸贝类生物体中Hg、Cd、Pd、As含量的分析

运用冷原子荧光法、无火焰原子吸收分光光度法及分光光度法对1998年5－6月所采集的浙江沿岸14个测站23个贝类生物样品中的重金属Hg,Cd,Pb,As含量进行了分析。结果表明：贝类生物样品中重金属平均含量，Hg为0．020&#215;20^-6，Cd为1．54&#215;10^-6，Pb为0．49&#215;10^-6，As为1．73&#215;10^-4，贝类不同科间重金属含量存在明显差异，蚶科含Cd量最高，帘蛤科含As量最高，同时对不同海区的贝类生物体中重金属含量进行了比较。     

Slope variations on the surface of Phobos

It has been suggested that slope fluctuations on the scale of pixel dimensions could be determined by statistical photoclinometry. A closer study of the surface of Phobos reveals variations in the scattering properties of single particles and micro-structures formed by the particles. In the present context, the photoclinometric method of brightness moments is extended to account for these variations by allowing statistical fluctuations in the phase function of the assumed Lommel-Seeliger scattering law. The mean slope on the investigated regions of Phobos has been found to vary from approximately 12 degrees on a 61m scale to approximately 7 degrees on a 216-272m scale. On the same scales, a value of the order of 2% has been obtained for the standard deviation of the scattering phase function. Hints of a fractal-like scale-invariance have been noticed in the covariance function of brightness.