Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996     

A Holocene record of climate change,fire ecology and human activity from montane Flat Top Bog,Maui

A sediment core from a high-elevation bog on Maui in the Hawaiian Islands contains evidence for drier conditions between 9.4–5.8 kyr BP, followed by a wetter interval between 5.8–2.2 kyr BP, and a variable late Holocene. These precipitation changes may be a reflection of vertical displacements of the upper boundary of the mid-Pacific Trade Wind Inversion (TWI) cloud layer. Fires, probably volcanically ignited, occurred in the forests prior to human arrival. Polynesian activity in this high-elevation, remote site was apparently limited, with no pollen, charcoal, or sedimentological evidence for local anthropogenic disturbance. After European contact, grass fires increased and introduced plant species invaded the site. Values for Cd, Cu, Pb, and Zn in sediments throughout the Holocene indicate low trace-metal deposition from atmospheric particulates at the site, even in the twentieth century.This paper is one of a series of papers guest edited by Dr. Mark Brenner on tropical paleolimnology     

Wide-angle vibroseis test across the Rhine graben

Summary. As a joint operation of ECORS and DEKORP, a deep wide-angle seismic experiment using vibrators was carried out in the autumn of 1984. The object was to get information on the deep crust under the Rhine graben without crossing through sedimentary layers. Offsets were in the range of 50 to 89 km. In the first phase, two vibration points were executed in the Vosges mountains. A signal was received in the Black Forest from solely the farthest VP. In the second phase, fourteen VPs were executed in the Black Forest. No stacking or correlation was performed in the field in France. The quality of the results is good only if an equalization is applied before vertical stacking and correlation in the computing centre.     

Toroidal versus poloidal magnetic fields in Sun-like stars: a rotation threshold

From a set of stellar spectropolarimetric observations, we report the detection of surface magnetic fields in a sample of four solar-type stars, namely HD 73350, HD 76151, HD 146233 (18 Sco) and HD 190771. Assuming that the observed variability of polarimetric signal is controlled by stellar rotation, we establish the rotation periods of our targets, with values ranging from 8.8 d (for HD 190771) to 22.7 d (for HD 146233). Apart from rotation, fundamental parameters of the selected objects are very close to the Sun's, making this sample a practical basis to investigate the specific impact of rotation on magnetic properties of Sun-like stars.
We reconstruct the large-scale magnetic geometry of the targets as a low-order  (ℓ < 10)  spherical harmonic expansion of the surface magnetic field. From the set of magnetic maps, we draw two main conclusions. (i) The magnetic energy of the large-scale field increases with rotation rate. The increase in chromospheric emission with the mean magnetic field is flatter than observed in the Sun. Since the chromospheric flux is also sensitive to magnetic elements smaller than those contributing to the polarimetric signal, this observation suggests that a larger fraction of the surface magnetic energy is stored in large scales as rotation increases. (ii) Whereas the magnetic field is mostly poloidal for low rotation rates, more rapid rotators host a large-scale toroidal component in their surface field. From our observations, we infer that a rotation period lower than ≈12 d is necessary for the toroidal magnetic energy to dominate over the poloidal component.     

Relationships between Holocene sea-level variations,trophic development,and climatic change in Negra Lagoon,Southern Uruguay

Paleolimnological data are presented on trophic development, climatic change and sea level variations in Negra Lagoon, a 142 km² coastal lagoon in southern Uruguay. Using a sediment core that extended to the early Holocene, analyses of organic matter, carbonate, diatoms and opal phytoliths allowed us to track changes in trophic state and paleosalinity levels, which were closely related to Holocene sea level variation, temperature and humidity. Diatom Association Zones (DAZ) corresponding to transgressive events were dominated by marine/brackish taxa and relatively low organic matter values, while those DAZ corresponding to regressive events showed increases in brackish/freshwater diatoms and organic matter. Opal Phytoliths Association Zones (OPAZ) also were identified, temperature and humidity indices were calculated, and climatic trends were inferred. During the middle Holocene (i.e., ~5000–4000 yr BP), cool–dry climatic conditions were established. After ~4000 yr BP, a transition from cool to warm–humid conditions was observed, but fully warm humid conditions established only after ~1700 yr BP. Such climatic amelioration led to increases in trophic state.     

Photoelectric device for monitoring the movement of a torsion balance beam

Manufactured and tested in his work is a photoelectric device that makes it possible to automatically determine the relative angular position of the beam of a miniature torsion balance, angular readings being discretized with various time step values and stored in a computer. Measurements were taken with this device that captured the occurrence of the partial solar eclipse on September 11, 2007, and confirmed the fact, established previously through visual observation, that the position of torsion balance beams changed at the instant an eclipse took place.     

Regularized derivatives of potential fields and their role in semi-automated interpretation methods

Evaluation of higher derivatives (gradients) of potential fields plays an important role in geophysical interpretation (qualitative and/or quantitative), as has been demonstrated in many approaches and methods. On the other hand, numerical evaluation of higher derivatives is an unstable process – it has the tendency to enlarge the noise content in the original data (to degrade the signal-to-noise ratio). One way to stabilize higher derivative evaluation is the utilization of the Tikhonov regularization. In the submitted contribution we present the derivation of the regularized derivative filter in the Fourier domain as a minimization task by means of using the classical calculus of variations. A very important part of the presented approach is the selection of the optimum regularization parameter – we are using the analysis of the C-norm function (constructed from the difference between two adjacent solutions, obtained for different values of regularization parameter). We show the influence of regularized derivatives on the properties of the classical 3D Euler deconvolution algorithm and apply it to high-sensitivity magnetometry data obtained from an unexploded ordnance detection survey. The solution obtained with regularized derivatives gives better focused depth-estimates, which are closer to the real position of sources (verified by excavation of unexploded projectiles).     

Synchrotron spectra of short-period pulsars

A model with synchrotron radiation near the light cylinder is proposed to explain the observed spectra of short-period pulsars (P≤0.1 s). These spectra can be described if a power-law energy distribution of the emitting electrons with exponent γ=2–8 is assumed. For most pulsars, the peak frequency ν_m is below 10 MHz. The ν_m(γ) dependence is derived, and shows that the peak frequencies for pulsars with spectral indices α<1.5 may fall in the observable range. In particular, ν_m may be ν_m ～ 100 MHz for PSR J0751 + 1807 and PSR J1640 + 2224. The observed radio spectrum of Geminga (PSR J0633 + 1746) can be described by a synchrotron model with a monoenergetic or Maxwellian distribution of relativistic electrons and a small angle β between the spin axis and magnetic moment (β ～ 10°).     

Observation of the solar eclipse 1966 May 20 in the region between 3.2 cm to 2.7 m wavelength

The solar eclipse 1966 May 20 was observed at 3.2, 10, 15, 20, 54, 59 cm, 1.05, 1.34 and 2.7 m wavelength by the observatories of the Heinrich-Hertz-Institut. The meter-wavelength observations were superposed by a noise storm. The result shows a region of enhanced radiation from the plages near the central meridian at the short wavelengths. Consulting additionally the observations made at Kiel, NERA, and Ondejov in the region of about 1.2 m wavelength it is possible to localize the source of the noise storm.