2.0GPa,850～1070℃条件下多硅白云母榴辉岩脱水熔融研究——对大别早白垩富K埃达克岩成因的约束

以产出于大别新店高压变质杂岩带的含角闪石多硅白云母榴辉岩(XD963)为实验源岩,使用YJ-3000t紧装式六面顶压机装置,在2.0GPa,850～1070℃条件下,进行了脱水部分熔融实验研究。结果显示,在850～950℃下,多硅白云母通过不一致脱水熔融反应产生了≤12%的过铝质(铝饱和指数ASI>1.2)的高K钙碱性(K2O/Na2O=1.2～1.4)花岗质熔体,与其共存的残留相为石榴子石+绿辉石+石英+多硅白云母+角闪石+Fe-Ti氧化物+蓝晶石±金红石。1000～1070℃时,熔体比例陡然增大(>35%),成分变为准铝质的钙碱性花岗闪长质,残留相组合以石榴子石+绿辉石+普通辉石为主。实验熔体与早白垩世富K埃达克岩的主微量元素对比结果表明:除ASI以及Eu/Eu*值特征外,低温熔体(900～950℃)与富K埃达克岩具有很好的相似性。此外,本次实验源岩在相对低温(900和950℃)条件下形成的熔体具备富K埃达克岩的两个主要特征—高K钙碱性和花岗质。因此可认为形成高K钙碱性的花岗质岩浆不需要过高的压力以及高度富K的源岩。     

江南造山带东段旌德岩体锆石LA-ICPMS年龄和Nd-Sr-Hf同位素地球化学

提要：旌德花岗质杂岩体位于安徽南部,由花岗闪长岩和二长花岗岩组成。本研究得到岩体中锆石U-Pb年龄为(141.0±1.0) Ma,认为该年龄代表岩体的侵位年龄。岩体全岩主量元素特征显示出中偏酸性 (SiO2＝66.01%~70.87%),富Al (Al2O3＝14.91%~16.24%),富碱 (alk = 6.64%~8.01%),K2O/Na2O变化范围在0.78~1.04,镁、铁含量较低,MgO：0.68%~1.06%,TFe2O3 (2.0%~3.34%),以及低磷 (P2O5 =0.10%~0.14%)的特点;微量元素主要富集Sr (189×10-6~452×10-6),贫Nb、Ta、P、Ti、Y、Yb,高Sr/Y比值 (23~66)和 (La/Yb)N (13~58),Eu有轻微的负异常到弱的正异常 (δEu＝0.81~1.18)。旌德岩体的地球化学特征与中国东部中生代埃达克质岩相似。ISr＝0.7096~0.7101, εNd(t)＝-6.28~-7.32,εHf(t)值变化于-6.5~-1.1,两阶段模式年龄 tDM2=1.4~1.5 Ga。较年轻的Nd同位素模式年龄、较高的εNd(t)值和εHf(t)值,以及岩体中发育有岩浆混合成因的暗色包体,指示源区可能有地幔物质的贡献。幔源岩浆底侵使下地壳发生部分熔融,并发生了岩浆混合作用,形成了旌德岩体。     

重晶石沉积类型及成因评述--兼论扬子地区下寒武统重晶石的富集机制

重晶石沉积类型丰富,具有多种成因过程。通常,沉积型重晶石可分为生物、热液、成岩和冷泉重晶石四种类型。富钡与富硫酸盐的流体（海水、早成岩孔隙水或热液流体）及其相互作用过程（水柱、热液系统、沉积柱、沉积物-水界面附近）决定了重晶石的沉积环境、宏微观产出方式、同位素组成及相应的地质意义。另外,根据扬子地区下寒武统富重晶石沉积的地质特征,简述了其各种富集机制的适用性及争论。据此建议,结合埃迪卡拉纪-寒武纪转折时期的古海洋背景,对其进行详细的沉积学及地球化学分析,有助于深化成因认识,弥合分歧。     

下扬子南黄海沉积盆地构造地质特征

南黄海盆地作为下扬子块体之上的大型叠合盆地,海相构造层保存完整,陆相断拗构造层也较为发育,盆地地质结构复杂,构造变形强烈,利用最新的地质地球物理资料和解释成果,对低勘探程度的南黄海盆地进行了研究,认为盆地演化大致经历了克拉通被动陆缘初始发育阶段—南缘前陆北缘被动陆缘过渡阶段—南北对冲前陆定型阶段—滨太平洋弧后陆内调整四个阶段。南黄海盆地属于台地—断拗复合地质结构,中、新生代为具有盆内隆起带的断陷箕状结构,且中、新生代多期构造运动在盆地原型改造和后期沉积发育上起着至关重要的作用,尤其印支—燕山早期运动、燕山中期黄桥运动和喜马拉雅期盐城运动与盆地地层变形、沉积发育、断裂发育及构造样式等盆地要素演化密切相关,进而导致盆地垂向地质结构和构造变形的层次性极为显著,而中生代燕山期和新生代喜马拉雅期两期构造岩浆活动则与滨太平洋域的动力学背景相关。     

人工合成烃类包裹体研究进展

人工合成烃类包裹体不仅可以作为分析仪器校正的标样,还可以增进人们对烃类包裹体形成机制和水—岩作用机理的认识。人工合成包裹体的方法主要有三种：人工晶体生长法、焊封石英管法和金刚石压腔法,其中利用愈合人工石英(水晶)单晶裂隙合成流体包裹体技术已成为标准的合成技术。目前人工合成烃类包裹体主要利用晶体生长法合成,包括高温高压利用石英（或方解石）晶体生长愈合裂缝形成流体包裹体和低温下采用过饱和溶液重结晶形成流体包裹体。由于高温高压条件下烃类可能发生裂解,母液保真是成功实现人工合成烃类包裹体的重要前提条件。国外在人工合成烃类包裹体研究方面已经取得了一些重要的认识,但远不及人工合成无机体系流体包裹体研究那样系统和完善。国内关于人工合成烃类包裹体研究尚处于起步阶段,迫切需要开展这方面的研究工作。     

西藏谢通门县雄村铜金矿主要地质体形成的时限：锆石U-Pb、辉钼矿Re-Os年龄的证据

雄村超大型铜金矿床的主要成矿作用发生在具眼球状石英斑晶的石英闪长玢岩及其外接触带强蚀变中细粒凝灰岩中,由产于斑岩体内的细脉浸染型矿体和产于凝灰岩中的细脉浸染型矿体、脉状矿体组成.文章在对含矿岩系及其侵位于含矿岩系的浅成岩和穿切矿体的花岗闪长岩等地质体进行详细的地质填图基础上,对雄村Ⅰ号、Ⅱ号矿体含矿围岩(暂定为雄村组J1-2x)、最早侵位的浅成岩-角闪石英闪长玢岩(J2δομ1)、含矿斑岩--具眼球状角闪石英闪长玢岩(J2δομ)、穿插矿体的黑云母花岗闪长岩(E2γδβ)(谢通门大岩基的一部分)、Ⅱ号矿体矿石中的辉钼矿等,开展了系统的成岩成矿年代学研究.锆石的U-Pb同位素测年结果表明,含矿围岩凝灰岩加权平均年龄为(176±5)Ma(MSWD=0.63;n=9);与成矿有关的含眼球状石英斑晶的石英闪长玢岩加权平均年龄为(173±3)Ma(MSWD=1.16;n=16);穿插侵吞矿体的谢通门大岩基花岗闪长斑岩加权平均年龄为(46.5±1.1)Ma(MSWD=0.83;n=14);所有锆石均显示岩浆成因锆石的特点.锆石U-Pb同位素研究显示含矿围岩形成于早中侏罗世,偏中性的含矿岩体侵位于中侏罗世,而侵吞穿插矿体的大岩基形成时代为始新世.雄村铜金矿Ⅱ号矿体4件辉钼矿样品的Re-Os同位素测定结果显示,辉钼矿w(187Re)为1 269～1 354μg/g,w(187Os)为3 587～3 993 ng/g.辉钼矿的模式年龄为169.5～176.8 Ma,平均模式年龄为(173.2±4.7)Ma(MSWD=5.6),显示成矿年龄为中侏罗世早期.结合多个岩体和岩脉的Ar-Ar同位素年龄测定结果和其他研究者的成果,认为雄村铜金矿属于岛弧型斑岩铜金矿床,由新特提斯洋的早期俯冲所致.雄村岛弧型斑岩铜金矿的发现和勘探、外围找矿的突破及本次系统年代学研究,提供了特提斯洋俯冲阶段成矿的信息,拓宽了西藏冈底斯成矿带新的找矿方向.     

成都粘土地球化学特征及其对物源和风化强度的指示

提要：成都平原晚更新世成都粘土地球化学分析表明,不同剖面样品的化学组成具有较好的一致性,以SiO2（平均75.24%）、Al2O3（平均14.12%）、Fe2O3（平均5.81%）为主,地球化学特征与UCC基本相似。与北方黄土相比,成都粘土具有较高的TiO2/Al2O3、Zr/Al、Zr/Ti和Y/Al以及较低的Eu/Eu?鄢、LaN/SmN和LaN/YbN比值,这些特征与成都平原第四系深层土壤样品组成一致,表明成都粘土来源于当地,与北方黄土物源不同。成都粘土CIA平均值为78.59,高于北方黄土平均值（69.34）,经历了中期的K迁移阶段,在风化过程中Ca、Na、Mg和K是主要的活动性元素。与北方黄土相比,成都粘土Na、Mg、K和Ca亏损较大,表明经历了更强的化学风化。     

Dual Control of Depositional Facies on Uranium Mineralization in Coal‐bearing Series: Examples from the Tuanyushan Area of the Northern Qaidam Basin,NW China

The uranium deposits in the Tuanyushan area of northern Qaidam Basin commonly occur in coal-bearing series. To decipher the U-enrichment mechanism and controlling factors in this area, a database of 72 drill cores, including 56 well-logs and 3 sampling wells, was examined for sedimentology and geochemistry in relation to uranium concentrations. The results show that coal-bearing series can influence uranium mineralization from two aspects, i.e., spatial distribution and dynamic control. Five types of uranium-bearing rocks are recognized, mainly occurring in the braided river and braided delta sedimentary facies, among which sandstones near the coals are the most important. The lithological associations of sandstone-type uranium deposits can be classified into three subtypes, termed as U-coal type, coal-U-coal type, and coal-U type, respectively. The coal and fine siliciclastic rocks in the coalbearing series confined the U-rich fluid flow and uranium accumulation in the sandstone near them. Thus, the coal-bearing series can provide good accommodations for uranium mineralization. Coals and organic matters in the coal-bearing series may have served as reducing agents and absorbing barriers. Methane is deemed to be the main acidolysis hydrocarbon in the U-bearing beds, which shows a positive correlation with U-content in the sandstones in the coal-bearing series. Additionally, the δ13 C in the carbonate cements of the U-bearing sandstones indicates that the organic matters, associated with the coal around the sandstones, were involved in the carbonation, one important component of alteration in the Tuanyushan area. Recognition of the dual control of coal-bearing series on the uranium mineralization is significant for the development of coal circular economy, environmental protection during coal utilization and the security of national rare metal resources.     

Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing‐Shenfu Area

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.     

中国东部燕山期大火成岩省:岩浆-构造-资源-环境效应

中国东部燕山期的大规模岩浆活动,即侏罗纪—白垩纪(150—100 Ma)的碱性流纹岩-碱性玄武岩-金伯利岩-钾镁煌斑岩-碳酸岩及其管道系统,分布于江南造山带内侧和郯庐断裂带南段以西的华北地台内,累积面积超过30万km2.该期短时限内大规模活动的岩浆事件代表了中国东部地质历史演化中的一次大火成岩省(LIP)事件,实质控制着中生代以来中国华北—扬子地台的构造格局变化、资源能源形成与地质环境变迁.晚侏罗世—早白垩世(150—100 Ma)的大火成岩省,是中生代中期古太平洋大火成岩省沿中国克拉通东部边缘活动的一部分,是包括昂通爪哇(Ongtong-Java)(Mahoney et al.,1993;Ingle and Coffin,2004)—中国东部在内的超级地幔柱上涌,在岩石圈板片对流,挤压地幔物质快速上升,引起陆域内长英质地壳物质大规模重熔的结果,形成:(1)髫髻山组—张家口组碱性流纹质-玄武质双峰式火山岩及其管道系统,与华北大规模金-多金属矿成矿作用密切相关;(2)辽宁瓦房店—山东蒙阴—安徽栏杆,湖南宁乡—贵州镇远一带的金伯利岩—钾镁煌斑岩±碳酸岩±基性超基性杂岩及其管道系统,与金刚石、金-铂族元素等成矿关系密切;(3)辽东—胶东半岛、南岭—滇黔桂交界地区的连片花岗岩,是硅质大火成岩省(SLIP)的管道系统(plumbing systems),与金刚石矿、金-铂族元素矿、钨锡铌钽矿、锂-钾-铷-铯-铀矿等,以及油气等战略性关键金属成矿关系密切.同时,巨型岩浆作用引发的富含钾、磷及稀土等微量元素的基岩形成优质土壤层对生态多样性的助益等有利和/或有害的环境效应,直接关系到地球家园的生态环境.因此,中国东部燕山期大火成岩省产生深刻的岩浆-构造-资源-环境效应.