花岗质岩石中铜铁锌的化学分离方法

过渡族元素同位素研究是近几年才发展起来的研究领域,随着研究的范围日趋广泛,问题日渐深入,需要对更多的地质样品进行同位素组成测定和研究.尽管文献报道的有关用于多接收器等离子体质谱过渡族元素同位素分析的化学分离方法能将Cu、Fe、Zn等元素很好地分离开来,但并未对地质样品中复杂地质基体元素的分离情况进行报道.因此,笔者对花岗岩中Cu、Fe、Zn分离进行了研究.     

岩溶泉补给地表溪流二氧化碳脱气作用研究

碳酸盐岩风化作用(即岩溶作用)能够吸收大气二氧化碳(CO_2),形成溶解无机碳(DIC,dissolved inorganic carbon),被认为是一种重要的陆地碳汇,其在全球碳收支平衡和未来陆地增汇中可能会有重要贡献。然而,目前对岩溶碳汇的稳定性还存在争议,一些学者认为岩溶地下水出露地表后会发生CO_2脱气,对岩溶碳汇通量估算带来不确定性。本文以广西桂林长流水表层岩溶泉补给的溪流(约2.7km长)为例,利用水化学和同位素质谱仪测试技术,研究了溪水水化学指标和溶解无机碳同位素(δ~(13)C_(DIC))沿流程变化,探讨了溪流CO_2脱气过程、通量及其影响因素,以更好地了解岩溶碳汇的稳定性。结果表明:从泉口向下游,在陡坡地段(C1～C14段,长约270m,坡度约10°),溪水pH值、方解石饱和指数和δ~(13)C_(DIC)沿流程分别升高了0.9、0.9和1.8‰,而CO_2分压、电导率、Ca~(2+)浓度和DIC浓度分别下降了85%、34μS/cm、0.2mmol/L和0.7mmol/L,说明溪水发生了显著的CO_2脱气,并伴随碳酸钙沉淀。而在平缓地段(C18～C26段,长约2.1km,坡度1°),溪水各水化学指标和δ~(13)C_(DIC)变化较小,指示CO_2脱气作用较弱。这些发现表明溪流CO_2脱气受到了地形决定的水动力条件控制。另外,在下游渠段,受支流汇入影响,溪水pH值和方解石饱和指数有所降低,在一定程度上抑制了CO_2脱气。溪流CO_2脱气能够抵消部分岩溶作用固定的大气CO_2量,但是在长流水这一高地势、低流量且有碳酸钙沉积的环境下,其抵消的量也仅占29%。对于在低缓地区受流量很大的岩溶泉/地下河补给的河流,其CO_2脱气作用对岩溶碳汇的影响有限,加之受可能增强的水生光合生物固碳效应影响,岩溶碳汇应具有很高的稳定性。     

甘肃省明舒井地区高光谱蚀变异常及找矿分析

正明舒井地区位于甘肃省北西侧,敦煌市北侧、瓜州县北西侧。前人在该区及周边区域开展了区调、矿调及相关多金属矿的勘查工作(王瑞军等,2014,2017),在遥感地质方面,仅开展了多光谱遥感的应用工作,而针对高光谱遥感的研究工作还未开展。明舒井地区基岩出露好、地形起伏小、切割弱,地表蚀变发育,矿床、矿点分布较多,具备开展高光谱遥感技术的地质和自然地理条件,有利于发挥高光谱的技术优势。     

超高温高压流变仪的研发及应用

随着我国能源勘探及地球深部探测等向深部发展,深井越来越多,地层温度、压力越来越高。保证高温高压状态下钻井液流变性能的稳定是深井安全钻进的必要前提,测定钻井液高温高压流变性是评价和优选钻井液体系最基础的工作。依托国家科技部重大仪器设备开发专项,通过对压力控制系统、温度控制系统、剪率控制系统、粘度检测系统等方面技术难题的攻关,研制成功了国内首台超高温高压流变仪。该仪器可在高温高压及低温高压条件下对钻井液、完井液、压裂液等样品的流变性进行高精度测量。     

辽宁锦州古生物化石和花岗岩国家地质公园地质遗迹特征及其地质背景

本文在系统收集、整理阜新—义县盆地和医巫闾山地区的地质学、古生物学、地貌学和年代地质学资料的基础上,对辽宁锦州古生物化石和花岗岩国家地质公园的地质遗迹景观资源进行了系统总结.进一步的研究揭示了阜新—义县盆地和医巫闾山同属于医巫闾山变质核杂岩系统,阜新—义县盆地的发育、热河生物群兴起与医巫闾山的形成密切相关.这一结论为整...     

金川铜镍硫化物矿床中铂族矿物的主要类型和产出特征: 热液蚀变过程中铂族元素的富集机理

金川铜镍硫化物矿床是我国最主要的铂族元素（PGE）资源产地,其矿石受热液蚀变作用影响明显,并产出多种铂族矿物（PGM）。岩浆演化和热液蚀变过程中PGE的迁移富集机制和PGM的成因,一直是研究PGE地球化学行为非常关注的问题。本文对金川铜镍硫化物矿床中PGM的研究发现,其主要类型包括含PGE的硫砷化物（硫砷铱矿）和砷化物（砷铂矿）,Pd的铋化物、碲化物和硒化物,以及少量其他铂族矿物。其中,硫砷铱矿可包裹于各种贱金属硫化物（镍黄铁矿、磁黄铁矿和黄铜矿）中,表明硫砷铱矿可能结晶于早期的含As硫化物熔体,随后被包裹于硫化物熔体冷凝分异产生的单硫化物固溶体（MSS）和中间硫化物固溶体（ISS）中。硫化物熔体中的As可能主要通过地壳混染作用加入幔源岩浆。大量铋钯矿（PdBi）呈微细乳滴状包裹于黄铜矿中,为晚期ISS冷凝形成黄铜矿过程中出溶的产物。少量铋钯矿（PdBi₂）呈不规则状充填于矿物裂隙,与次生磁铁矿脉紧密共生,并随矿石的蚀变程度增加,铋钯矿的化学成分由PdBi逐渐向PdBi₂转变,表明这部分铋钯矿为后期热液蚀变产物。铋碲钯矿和钯的硒化物则主要产出于镍黄铁矿裂隙且与次生磁铁矿紧密共生,指示明显的热液成因。钯的硒化物的出现表明,岩浆期后酸性、高盐度、高氧逸度的富Cl^-流体对金川铜镍硫化物矿床中Pd的迁移和富集起到了关键控制作用。

     

The U-Pb Geochronology and Lu-Hf Isotope Compositions of Detrital Zircons from the Nanhua Group of the Longsheng Region, South China and their Implications for Pan-African Events

It is unclear whether the South China blocks have an affinity with continental Gondwana due to a lack of direct Pan-African magmatic and metamorphic features. In this study, we conducted U-Pb geochronological and Lu-Hf isotopic analyses for detrital zircons from a sandstone of the Chang’an Formation of the Nanhua Group in the Longsheng region of northern Guangxi, with the aim of constraining the timing of sedimentation and information as to its source, as well as seeking evidence for Pan-African events in the South China blocks. The results show that the ages of detrital zircons peaked at 654.7 ± 6.2 Ma, 773.2 ± 4.1 Ma and 821.9 ± 6.5 Ma, with some at 920–870 Ma; the youngest age indicates the existence of the Pan-African thermal event. The εHf(t) and TDM2 values demonstrate that the study area has experienced three stages of crustal growth at 3.0–2.4 Ga, 2.1–1.5 Ga and 1.3–0.9 Ga. With intensively distributed Neoproterozoic mafic-ultramafic and granitic plutons emplaced at 830–810 Ma along the southwestern section of the Jiangnan Orogenic Belt and positive εHf(t) values from a large group of zircon grains, it is proposed that the sediments of the Chang’an Formation (of Nanhua Group) were largely sourced from the southeastern margin of the Yangtze block. Comparison with the zircon age spectra of the Cathaysian block shows that about 79% of the Pan-African aged detrital zircon grains that have TDM2 = 1352–1031 Ma and εHf(t) = 3.68–8.79, were sourced from the recycled Grenvillian crust of the Cathaysian block, suggesting that the Cathaysian block had a close connection with Gondwana.     

Genesis of Geothermal Fluid in Typical Geothermal Fields in Western Sichuan,China

The hydrogeochemical characteristics of geothermal fluids can reveal the genesis of geothermal systems and act as important references for developing and using geothermal resources.This study presents hydrogeochemical processes and thermal cycle mechanisms of typical geothermal fields in Western Sichuan.Based on the geological conditions in Western Sichuan,29 hot springs in three geothermal fields in the Batang and Litang areas were selected for hydrochemical and isotopic (δD andδ~(18)O) analyses.Furthermore,the temperature of the thermal reservoir was calculated and the upflow cooling process of the hot springs was analyzed.Most of the subterranean hot waters in Batang and Litang are of the HCO_3-Na hydrochemical type.The ion variation in Batang is primarily affected by water-rock interactions.There is a strong positive correlation between Na~+,B~-,and Cl~-in Litang,suggesting that they have the same material source.The Na~+and metaboric acid content is relatively high,which indicates that the groundwater runoff in both areas is relatively long-lasting,with reduced flow velocity;moreover,the metasilicic acid content is relatively high,which supports this conclusion.Both hydrogen and oxygen isotopes plot near the atmospheric precipitation line,indicating that groundwater recharge is functionally obtained from precipitation.The calculated thermal storage temperatures in Batang and Litang were 88–199°C and 96–154°C,respectively.The proportion of cold water mixing in Batang was 64%–67%,while that in Litang was 60%–68%.According to the calculated results,the initial thermal cycle depth of the Batang area (4540–4780 m) was greater than that of the Litang area (3150–3960 m).The enthalpy of the deep parental geothermal fluid in Batang was 1550 J/g with a Cl~-concentration of 37 mg/L,while that in Litang was 2100 J/g with a Cl~-concentration of 48 mg/L.     

岩土钻掘设备的液压步履机构

因液压步履移位最方便，辅助时间短，换向灵活，移位对孔准确，大型岩土钻掘设备施工的群孔现场实现近距离的自行迁移多采用液压步履机构。详细叙述了双向移动和单向移动加转向步履机构的结构和特点。     

武当地块基性岩墙群的Sm-Nd定年及其相关问题讨论

武当地块是卷入南秦岭构造带的前震旦纪基底岩块,该基底岩块中广泛发育变形变质的基性岩墙群,获得岩墙群的ＳｍＮｄ全岩等时年龄为ｔ＝７８２±１６４（２σ）Ｍａ,ＩＮｄ＝０．５１１７１±１６（２σ）,εＮｄ（ｔ）＝＋１．５±１．０。据此并综合区域地质实际,对南秦岭元古代古陆块的存在及其裂解等相关问题进行了讨论。