The acquisition of thermoremanent magnetization by multidomain single-crystal titanomagnetite

Summary. Large, well-characterized single-crystals of titanomagnetite of approximate composition Fe_2.4Ti_0.6O₄ were ground into spheres and orientated along specific crystallographic axes. The field dependences of the thermoremanent magnetization (TRM) and the temperature dependences of the magnetic hysteresis properties were measured and evaluated against the available theoretical models. The models, of necessity simplifications of real materials, were unable to account for many features of the experimental curves. The discrepancies were partly resolved by consideration of the mode of blocking of each individual coercivity fraction. It was deduced that the domain-walls were pinned by both dislocation lines and by inclusions or voids. A fraction of the walls were not thermally blocked. They could however be thought of as being blocked isothermally as the applied field was relaxed. The proportion of remanence blocked in by each process was found to be dependent on the strength of the inducing field through the field dependence of the blocking temperatures. A simplified model, taking these effects into account, was developed. This predicts the main features of the TRM acquisition curve and of the alternating field and thermal demagnetization spectra.     

Geomorphology of unique reefs on the western Canadian shelf: sponge reefs mapped by multibeam bathymetry

Multibeam imagery of siliceous sponge reefs (Hexactinellida, Hexactinosida) reveals the setting, form, and organization of five reef complexes on the western Canadian continental shelf. The reefs are built by framework skeleton sponges which trap clay-rich sediments resulting in a distinctive pattern of low intensity backscatter from the reefs that colonize more reflective glacial sediments of higher backscatter intensity. Bathymetry and backscatter maps show the distribution and form of reefs in two large complexes in the Queen Charlotte Basin (QCB) covering hundreds of km², and three smaller reef complexes in the Georgia Basin (GB). Ridges up to 7 km long and 21 m in height, together with diversely shaped, coalescing bioherms and biostromes form the principal reef shape in the QCB whereas chains of wave-form, streamlined mounds up to 14 m in height have developed in the GB. Reef initiation is dependent on the distribution of high backscatter-intensity relict glacial surfaces, and the variation in reef complex morphology is probably the result of tidally driven, near seabed currents.     

Iron and Sulfur Chemistry in a Stratified Lake: Evidence for Iron-Rich Sulfide Complexes

A four month study of a man-made lake used for hydroelectric power generation in northeastern Pennsylvania USA was conducted to investigate seasonal anoxia and the effects of sulfide species being transported downstream of the power generation equipment. Water column analyses show that the system is iron-rich compared to sulfide. Total Fe(II) concentrations in the hypolimnion are typically at least twice the total sulfide levels. In situ voltammetric analyses show that free Fe(II) as [Fe(H₂O)₆]²⁺ or free H₂S as H₂S/HS^- are either not present or at trace levels and that iron-rich sulfide complexes are present. From the in situ data and total Fe(II) and H₂S measurements, we infer that these iron-rich sulfide complexes may have stoichiometries such as Fe₂SH³⁺ (or polymeric forms of this and other stoichiometries). These iron-rich sulfide complexes appear related to dissolution of the iron-rich FeS mineral, mackinawite, because IAP calculations on data from discrete bottle samples obtained from bottom waters are similar to the pK_sp of mackinawite. Soluble iron-sulfide species are stable in the absence of O₂ (both in lake waters and the pipeline) and transported several miles during power generation. However, iron-sulfide complexes can react with O₂ to oxidize sulfide and can also dissociate releasing volatile H₂S when the waters containing them are exposed to the atmosphere downstream of the powerplant. Sediment analyses show that the lake is rich in oxidized iron solids (both crystalline and amorphous). Fe concentrations in FeS solids are low (<5 μmole/gr_{dry wt}) and the pyrite concentration ranges from about equal to the solid FeS to 30 times the solid FeS concentration. The degree of pyritization is below 0.12 indicating that pyrite formation is limited by free sulfide, which can react with the iron-rich sulfide complexes.     

Metoz: Total ozone from meteorological parameters

Abstract

On the basis of two well‐known ozone‐weather relationships, an algorithm is proposed that estimates total ozone amounts using readily available meteorological information. The technique has been labelled METOZ from Meteorological Total Ozone. A rationale and derivation of the technique is presented.

METOZ total ozone amounts were generated for Toronto and Edmonton locations and compared with ground‐based Brewer spectrophotometer measures for these two stations in the Canadian ozone monitoring network for data from January to April 1989. Per cent differences between METOZ and Brewer total ozone measurements were calculated and are presented.

This mid‐latitude wînter metoz algorithm was also used to produce a hemispherical total ozone field for 16 March 1986, which was compared with the corresponding TOMS data to demonstrate other potential applications of the technique.     

Filters for linear sea-wave prediction

Deterministic sea-wave prediction (DSWP) models are appearing in the literature designed for quiescent interval prediction in marine applications dominated by large swell seas. The approach has focused upon spectral methods which are straightforward and intuitively attractive. However, such methods have the disadvantage that while the sea is aperiodic in nature, the standard discrete spectral processing techniques force an absolutely periodic structure onto the resulting sea surface prediction models. As it is the shape of the sea surface that is important in such applications, particularly near the end of the domain which is important, the standard windowing techniques used in signal processing work to reduce leakage artifacts cannot be employed. This has necessitated the use of end matching methods that can be both inconvenient and may reduce the fraction of the time for which legitimate predictions are available. As a result, an investigation has been undertaken of the use of finite impulse response prediction filters to provide the necessary dispersive phase shifting required in DSWP systems. The present work examines the theoretical basis for such filters and explores their properties together with their application to both long and short crested swell seas. It is shown that wide band forms of such filters are only convergent in the sense of distributions having both infinite duration impulse responses and asymptotically divergent first derivatives. However, appropriate band limitation can produce useful finite impulse responses allowing implementation via standard discrete convolution methods. It is demonstrated that despite the prediction filters having a non-causal impulse response such filters can be used in practice due to a combination of the asymmetric nature of the impulse response and the fundamental nature of the prediction process. The findings are confirmed against actual sea-wave data.     

Environmental Factors Contributing to the Development and Demise of a Toxic Dinoflagellate (<Emphasis Type="Italic">Karlodinium veneficum</Emphasis>) Bloom in a Shallow,Eutrophic, Lagoonal Estuary

A dense bloom of the ichthyotoxic dinoflagellate Karlodinium veneficum was discovered in the Neuse River Estuary, North Carolina, on 19 October 2006 and was associated with four subsequent fish kills. Microscopic, photopigment, DNA, and toxicological techniques confirmed bloom identity and toxicity. High-resolution spatio-temporal data from ship-board and fixed automated sampling stations provided a unique opportunity to investigate the environmental conditions that initiated, maintained, and terminated the K. veneficum bloom. Bloom initiation and growth were favored by high nutrient availability and reduced dispersal during the period of declining riverine discharge after Tropical Storm Ernesto. K. veneficum out-competed other co-occurring dinoflagellates, perhaps because of the production of karlotoxins that are known to act as grazing deterrents and to facilitate mixotrophic feeding. Once the bloom was established, small-scale hydrodynamic processes, coupled with vertical migration, concentrated cells along a frontal convergence to high densities (>200,000 cells per milliliter). By 26 October 2006, wind mixing and possible nutrient stress disrupted the bloom. Release of cell-bound toxins during the bloom collapse likely accounted for the associated fish kill events where fish were reported as exhibiting typical symptoms of karlotoxin poisoning. The dynamics of this bloom underscore the tight control of harmful algal blooms by meteorological forcing, hydrology, and sediment nutrient input in this shallow lagoonal estuary.