Geology of the volcanic-hosted Brockman rare-metals deposit,Halls Creek Mobile Zone,northwest Australia. l. Volcanic environment,geochronology and petrography of the Brockman volcanics

Summary Rare-metals mineralization of the Brockman deposit (Halls Creek Mobile Zone, NW Australia) is hosted in a fluorite-bearing, rhyolitic volcaniclastic unit informally termed the Niobium Tuff. The Tuff, more correctly described as a tuffaceous volcaniclastic deposit, is the lowermost unit of a sequence of trachyte-to-rhyolite lavas, trachyandesite subvolcanic rocks, and volcaniclastic units of the Brockman volcanics located within the Halls Creek Group, a thick, early Proterozoic volcano-sedimentary sequence. High precision SHRIMP ion-microprobe zircon dating of the Niobium Tuff gives an eruption age of 1870 ± 4 Ma. Regional geochronological constraints indicate the Niobium Tuff was deposited about 15 Ma before major orogenic activity affected the area. Despite folding, faulting and low-grade metamorphism, the Brockman volcanics show excellent preservation of primary volcanological features, including pillow-lavas and pillow-breccias, that suggest a dominantly subaqueous, below-wave-base emplacement environment. The style of eruption products and magma volume constraints suggest the trachyte-dominated volcanics were erupted from a small shield volcanic complex probably in a rift-related basin in a shallow-marine setting. The tectonic setting was intraplate but differs from most Tertiary to recent trachyte volcanic complexes which are largely subaerial, are built on relatively thick continental crust, and show no post-eruptive orogenic history. Brockman-style rare-metal deposits are characterized by preservation of subaqueous volcanics beneath a thick sedimentary sequence, eruption of early incompatible-element enriched products followed by less differentiated magmas, and fine-grained mineralogy influenced by alteration processes. Prospects exist for discovery of analogous deposits, particularly in early Proterozoic mobile belts and Tertiary intraplate shield volcanic provinces.

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Geologie der an Vulkanite gebundenen Seltene-Metalle-Lagerstätte Brockman, Halls Creek Mobile Zone, Nordwest-Australien. I. Vulkanologie, Geochronologie und Petrographie der Brockman-Vulkanite

Zusammenfassung Selten-Metall-Vererzung der Brockman-Lagerstätten (Halls Creek Mobile Zone, NW Australien) sitzt in einer Fluorit-führenden, rhyolitischen vulkanoklastischen Einheit auf, die informell als der Niob-Tuff bezeichnet wird. Es handelt sich hier um ein vulkanoklastisches Tuff-Sediment; dieses ist die unterste Einheit einer Abfolge vor Trachyt bis Rhyolit-Laven, trachyandesitischen Subvulkaniten and vulkanoklastischen Einheiten der Brockman Vulkanite innerhalb der Halls Creek Gruppe, einer mächtigen frühproterozoischen vulkanosedimentdren Abfolge. Prüzisionsdatierungen des Niob Tuffs mit der SHRIMP Ionen-Mikrosonde ergeben ein Eruptionsalter von 1870 +-4 Millionen Jahren. Regionale geochronologische Zusammenhänge zeigen, daß der Niob Tuff etwa 15 Millionen Jahre vor einer größeren Orogenese, die das Gebiet betroffen hat, abgelagert wurde. Trotz Faltung, Bruchtektonik and niedriggradiger Metamorphose zeigen die Brockman-Vulkanite einen hervorragenden Erhaltungszustand primärer vulkanologischer Erscheinungen. Diese urnfassen auch Kissenlaven und KissenBreckzien, die eine vorwiegend subaquatische Ablagerung in ruhigem Wasser erkennen lassen. Die Art der Eruptionsprodukte and das Magmavolumen zeigen, daß die Trachytdominierten Vulkanite von einem kleinen Schildvulkan stammer, wahrscheinlich in einem Becken in einer Rift-Situation im seichten marinen Milieu. Die tektonische Situation war intraplate, aber unterscheidet sich von den meisten tertiären bis rezenten trachytischen Vulkan-Komplexen, die hauptsächlich subaerisch sind, auf einer relativ mächtigen kontinentalen Kruste aufsitzen, and keine post-eruptive orogene Entwicklung zeigen. Seltene-Metalle-Lagerstatten des Brockman-Typs rind durch die Erhaltung subaquatischer-Vulkanite unterhalb einer machtigen sedimentdren Abfolge gekennzeichnet; welters durch frühe Eruptionsprodukte, die an inkompatiblen Elementen angereichert sind, auf die dann weniger differenzierte Magmen folgten, und schließlich durch einen feinkörnigen Mineralbestand, der vor Umwandlungsprozessen betroffen war. Es besteht die Möglichkeit der Entdeckung analoger Lagerstätten, besonders in frühproterozoischen mobilen Gürteln und in tertidren intraplate Schildvulkan Provinzen.

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The influence of salinity on the solubility of Zn and Cd sulphides in the Scheldt estuary

In the estuary of the river Scheldt, where an oxygen gradient exists in addition to the salinity gradient, redox processes will be of major importance for trace metal mobilisation. In this study, the influence of salinity and pH on the redox processes of dissolved Zn and Cd sulphides is investigated together with the effects on the ratio of the dissolved Zn and Cd concentrations. The speciation of these metals is calculated with the chemical equilibrium programme +. Zn sulphides are oxidised at lower oxygen concentrations than Cd sulphides, due to lower stability constants, causing a sudden increase or peak in the dissolved Zn/Cd ratio. The formation of dissolved Cd chloride complexes when oxidation occurs at high salinities (S=15) increases the mobility of Cd, causing a decrease in the Zn/Cd peak of the total dissolved concentrations. The peak is three to four times smaller at S=15 than when oxidation occurs at S=2. The simple model calculations compare very well with field data. The Scheldt estuary is suitable to illustrate these calculations. In the 1970s, the anoxic part of the estuary reached S=15–20, but since the early 1980s it has dropped to S=2–10. Historic data on metals in the estuary from 1978, 1987 and the 1990s were used to compare with the equilibrium calculations. The increase of the dissolved Zn/Cd peak at low salinity as a consequence, of the decreasing anoxic region is confirmed well by the data. The good agreement between model calculations and field data is a proof of the extreme importance of redox processes for the solubility of Zn and Cd sulphides in the estuary.     

Debris flow deposits of early miocene age,deadman stream,Marlborough, New Zealand

Detailed analysis is presented of a conformable succession of Early Miocene conglomerates and sandstones lying between massive marine mudstones. The coarse sediments reflect deposition by a spectrum of subaqueous debris-flow mechanisms during an early pulse of tectonism that ultimately resulted in Plio-Pleistocene eversion of the Kaikoura Mountains.Sparse pebbly mudstones and rare sandy conglomerates show disoriented clasts and reflect high-viscosity flows and slurry-creep flow mechanisms. Other deposits have little mud matrix, hence appear to reflect low-viscosity flow processes. The largest clasts in these have a preferred planar orientation, probably reflecting dispersive grain pressure, and a preferred long-axis orientation parallel to flow direction. Common sorted sandstones and some conglomeratic sandstones show diffuse parallel lamination; with rare exceptions neither grading nor traction structures are present. Other conglomeratic sandstones show trough cross-bedding which we attribute to entrained bedload movement during intersurge episodes of debris flow.Microfossil data from the mudstones indicate sedimentation in an environment of outer neritic to upper bathyal aspect. Most detritus is abraded, suggesting derivation from terrestrial or inner neritic sources, but angular calcilutitic clasts and irregular sandstone and mudstone clasts and rafts were probably derived from submarine erosion between the emergent source area and the site of accumulation. Deposits generally appear to infill broad shallow channels. Paleocurrent and fabric analysis indicate a markedly uniform flow direction throughout succession, and suggest that the locus of channeling remained relatively fixed in space throughout accumulation of hundreds of metres of superimposed, commonly amalgamated debris-flow deposits. Although lateral control away from the measured sequence is limited, we infer that the locus of deposition lay shoreward of any submarine canyon or fan.     

Estuary/ocean exchange and tidal mixing in a Gulf of Maine Estuary: A Lagrangian modeling study

A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m²/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.     

Diurnal variation of the dayside, ionospheric, mid-latitude trough in the southern hemisphere at 800 km: Model and measurement comparison

Our high latitude ionospheric model predicts the existence of a pronounced “dayside” trough in plasma concentration equatorward of the auroral oval in both the Northern and Southern Hemispheres for solar maximum, winter, and low geomagnetic activity conditions. The trough in the Southern Hemisphere is much deeper than that in the Northern Hemisphere, with the minimum trough density at 800 km being 2 × 10³ cm⁻³ in the Southern Hemisphere and 10⁴ cm⁻³ in the Northern Hemisphere. The dayside trough has a strong longitudinal (diurnal) dependence and appears between 11:00 and 19:00 U.T. in the Southern Hemisphere and between 02:00 and 08:00 U.T. in the Northern Hemisphere. This dayside trough is a result of the auroral oval moving to larger solar zenith angles at those universal times when the magnetic pole is on the antisunward side of the geographic pole. As the auroral ionization source moves to higher geographic latitudes, it leaves a region of declining photoionization on the dayside. For low convection speeds, the ionosphere decays and a dayside trough forms. The trough is deeper in the Southern Hemisphere than in the Northern Hemisphere because of the greater offset between the geomagnetic and geographic poles. Satellite data taken in both the Northern and Southern Hemispheres confirm the gross features of the dayside trough, including its strong longitudinal dependence, its depth, and the asymmetry between the Northern and Southern Hemisphere troughs.     

Record of Late Pleistocene Glaciation and Deglaciation in the Southern Cascade Range. I. Petrological Evidence from Lacustrine Sediment in Upper Klamath Lake, Southern Oregon

Petrological and textural properties of lacustrine sediments from Upper Klamath Lake, Oregon, reflect changing input volumes of glacial flour and thus reveal a detailed glacial history for the southern Cascade Range between about 37 and 15 ka. Magnetic properties vary as a result of mixing different amounts of the highly magnetic, glacially generated detritus with less magnetic, more weathered detritus derived from unglaciated parts of the large catchment. Evidence that the magnetic properties record glacial flour input is based mainly on the strong correlation between bulk sediment particle size and parameters that measure the magnetite content and magnetic mineral freshness. High magnetization corresponds to relatively fine particle size and lower magnetization to coarser particle size. This relation is not found in the Buck Lake core in a nearby, unglaciated catchment. Angular silt-sized volcanic rock fragments containing unaltered magnetite dominate the magnetic fraction in the late Pleistocene sediments but are absent in younger, low magnetization sediments. The finer grained, highly magnetic sediments contain high proportions of planktic diatoms indicative of cold, oligotrophic limnic conditions. Sediment with lower magnetite content contains populations of diatoms indicative of warmer, eutrophic limnic conditions. During the latter part of oxygen isotope stage 3 (about 37–25 ka), the magnetic properties record millennial-scale variations in glacial-flour content. The input of glacial flour was uniformly high during the Last Glacial Maximum, between about 21 and 16 ka. At about 16 ka, magnetite input, both absolute and relative to hematite, decreased abruptly, reflecting a rapid decline in glacially derived detritus. The decrease in magnetite transport into the lake preceded declines in pollen from both grass and sagebrush. A more gradual decrease in heavy mineral content over this interval records sediment starvation with the growth of marshes at the margins of the lake and dilution of detrital material by biogenic silica and other organic matter.     

Richtmyer-Meshkov Experiments on the Omega Laser

Observations of the interstellar medium reveal a dynamic realm permeated by shocks. These shocks are generated on a large range of scales by galactic rotation, supernovae, stellar winds, and other processes. Whenever a shock encounters a density interface, Richtmyer-Meshkov instabilities may develop. Perturbations along the interface grow, leading to structure formation and material mixing. An understanding of the evolution of Richtmyer-Meshkov instabilities is essential for understanding galactic structure, molecular cloud morphology, and the early stages of star formation. An ongoing experimental campaign studies Richtmyer-Meshkov mixing in a convergent, compressible, miscible plasma at the Omega laser facility. Cylindrical targets, consisting of a low density foam core and an aluminum shell covered by an epoxy ablator, are directly driven by fifty laser beams. The aluminum shell is machined to produce different perturbation spectra. Surface types include unperturbed (smooth), single-mode sinusoids, multi-mode (rough), and multi-mode with particular modes accentuated (specified-rough). Experimental results are compared to theory and numerical simulations.     

Analysis of a large extent aeromagnetic survey near the geomagnetic equator (Minas Gerais,Brazil)

A large extent aeromagnetic survey, covering a 9°×9° degree of a Precambrian shield area in SE Brazil, was used to analyse long wavelength magnetic anomalies with the purpose of determining the magnetic structure of the lithosphere.Data analysis based on a novel approach to the estimation of the parameters in the statistical model ofSpector andGrant (1970), reveals a highly magnetized lower crust, bounded by an essentially non-magnetic upper mantle. The highly magnetized layer can be associated with a higher density lower crust model, derived from gravity and seismic data available in the area, suggesting a compositional transition from upper to lower crust.It was also verified that the operation of reduction to the pole, which is singular at the geomagnetic equator, performs quite satisfactorily at the low geomagnetic inclination of the area, bringing into accordance the long wavelength anomalies with the structural trends.     

Evaporation of perennial semi‐arid woodland in southeastern Australia is adapted for irregular but common dry periods

Measurements of water vapour flux from semi‐arid perennial woodland (mallee) were made for 3 years using eddy covariance instrumentation. There have been no previous long‐term, detailed measures of water use in this ecosystem. Latent energy flux (LE) on a half hourly basis was the measure of the combined soil and plant evaporation, ‘evapotranspiration’ (E_LE) of the site. Aggregation over 3 years of the site measured rain (1136 mm) and the estimated evaporation (794 mm) suggests that 342 mm or 30% of rain had moved into or past the root zone of the vegetation. Above average rainfall during 2011 and the first quarter of 2012 (633 mm, 15 months) would likely have been the period during which significant groundwater recharge occurred. At times immediately after rainfall, E_LE rates were the same or exceeded estimates of potential E calculated from a suitably parameterized Penman–Monteith (E_PMo) equation. Apparent free water E from plant interception and soil evaporation was about 2.3 mm and lasted for 1.3 days following rainfall in summer, while in autumn, E was 5.1 mm that lasted over 5.4 days. The leaf area index (LAI) needed to adjust a wind function calibrated Penman equation (E_PMe) to match the E_LE values could be back calculated to generate seasonal change in LAI from 0.12 to 0.46 and compared well with normalized difference vegetation index; r = 0.38 and p = 0.0213* and LAI calculated from digital cover photography. The apparently conservative response of perennial vegetation evaporation to available water in these semi‐arid environments reinforces the conclusion that these ecosystems use this mechanism to survive the reasonably common dry periods. Plant response to soil water availability is primarily through gradual changes in leaf area. Copyright © 2015 John Wiley & Sons, Ltd.     

Evaluation of the first GOCE static gravity field models using terrestrial gravity,vertical deflections and EGM2008 quasigeoid heights

Recently, four global geopotential models (GGMs) were computed and released based on the first 2 months of data collected by the Gravity field and steady-state Ocean Circulation Explorer (GOCE) dedicated satellite gravity field mission. Given that GOCE is a technologically complex mission and different processing strategies were applied to real space-collected GOCE data for the first time, evaluation of the new models is an important aspect. As a first assessment strategy, we use terrestrial gravity data over Switzerland and Australia and astrogeodetic vertical deflections over Europe and Australia as ground-truth data sets for GOCE model evaluation. We apply a spectral enhancement method (SEM) to the truncated GOCE GGMs to make their spectral content more comparable with the terrestrial data. The SEM utilises the high-degree bands of EGM2008 and residual terrain model data as a data source to widely bridge the spectral gap between the satellite and terrestrial data. Analysis of root mean square (RMS) errors is carried out as a function of (i) the GOCE GGM expansion degree and (ii) the four different GOCE GGMs. The RMS curves are also compared against those from EGM2008 and GRACE-based GGMs. As a second assessment strategy, we compare global grids of GOCE GGM and EGM2008 quasigeoid heights. In connection with EGM2008 error estimates, this allows location of regions where GOCE is likely to deliver improved knowledge on the Earth’s gravity field. Our ground truth data sets, together with the EGM2008 quasigeoid comparisons, signal clear improvements in the spectral band ~160–165 to ~180–185 in terms of spherical harmonic degrees for the GOCE-based GGMs, fairly independently of the individual GOCE model used. The results from both assessments together provide strong evidence that the first 2 months of GOCE observations improve the knowledge of the Earth’s static gravity field at spatial scales between ~125 and ~110 km, particularly over parts of Asia, Africa, South America and Antarctica, in comparison with the pre-GOCE-era.