To what extent can atmospheric deposition influence the natural background of metals in ground waters? A case study in the Czech Republic

In harmony with requirements of Water Framework Directive the natural backgrounds of selected metals were established on the territory of Czech Republic. This paper is intended to provide characteristics and results of testing methods focused on quantification of the impacts of anthropogenic activities based on data of regional monitoring and their separation from acid atmospheric deposition including an appropriate discussion regarding the natural backgrounds of relevant metals. The results indicate that even in regions extremely affected by acid atmospheric deposition as is the territory of the Czech Republic this acid deposition will not have direct impact on the quality of ground waters on a regional scale. Consequently, the proved changes in quality of ground waters seem to have been caused by secondary processes, specifically by mobilization of metals in a rock environment due to increased acidity.     

Deposition of trace substances via cloud interception on a coniferous forest at Kleiner Feldberg

A resistance model to calculate the deposition of cloud droplets on a coniferous forest and some improved parameterizations of the indispensable input parameters are described. The deposition model is adapted to the coniferous forest at the Kleiner Feldberg site and verified by the data of a drip water monitoring station below the forest canopy. The measurements of liqud water content, wind speed and trace substance compounds in cloud water of the Ground-based Cloud Experiment (GCE) at Kleiner Feldberg in 1990 are used to calculate the cloud water deposition fluxes and the deposition of trace substances via cloud water interception. The calculated deposition of trace substances via cloud water interceptions is three to six times higher than via rain during the experiment. On a long term data basis the yearly amount of cloud water deposition is 180 mm year^–1 at Kleiner Feldberg site (840 m a.s.l.) while the precipitation amount is 1030 mm year^–1. Due to higher trace substance concentrations in cloud water compared to rain the ionic deposition via cloud water interception and via precipitation were assessed to be of comparable magnitude.     

Li_2S─B_2O_3（─LiBr）玻璃的结构表征

用ＮＭＲ和ＸＰＳ技术研究了Ｌｉ２Ｓ─Ｂ２Ｏ３（─ＬｉＢｒ）体系硫氧化物玻璃的结构，结果指出，４─配位硼分数Ｎ４仅仅由玻璃Ｌｉ２Ｓ／Ｂ２Ｏ３摩尔比决定．而与ＬｉＢｒ含量无关，这表明Ｌｉ２Ｓ作为变形剂参与了玻璃网络形成，而ＬｉＢｒ仅作为参杂剂溶解于玻璃基体中，并进入网络间隙。含ＬｉＢｒ玻璃７ＬｉＮＭＲ谱运动变窄说明Ｌｉ＋离子是移迁离子．Ｓ２ｐ的ＸＰＳ解析谱证实了玻璃中桥硫和非桥硫的存在．Ｌｉｌｓ结合能值显示出Ｌｉ＋离了迁移的化学环境。     

基于IPA法的传统型景区游客满意度评价——以琅琊山景区为例

游客满意度评价对景区规划、建设和管理很重要。结合文献分析与德尔菲法,构建了传统型景区游客满意度评价指标体系,并以琅琊山景区为例采用IPA模型进行案例分析。结果表明:琅琊山景区7个要素测度层——资源特色、景区环境、景区产品、景区交通、景区服务、景区设施、景区价格及30项因子测度指标感知均值都为满意度重要性,游后感知实绩(满意度)全低于游前期望(重要性);IPA矩阵分析30项因子分布为:优势区域6项、修补区域4项、机会区域15项、维持区域5项,游后满意度(实绩)与游前重要性(期望)感知评价"双高项"占20.0%,"双低项"占50.0%。总体上游客期望值较高而满意度不高,各评价因子的满意度评价差异较大,景区需提升产品与服务。     

The collision singularity in a perturbed two-body problem

It is shown that, in the neighborhood of a collision singularity, the motion in a perturbed two-body problem \(\ddot r = - \mu r^{ - 3} r + P\) , whereP remains bounded, has the same basic properties as the motion in the neighborhood of a collision in the unperturbed two-body problemP=0.     

ESRO-1 AND ESRO-4: A model of the U.T. effect in electron density at middle latitudes of the southern hemisphere

The electron density observations made using ESRO-1 and ESRO-4 near solar maximum and solar minimum, respectively, show a strong longitudinal variation at middle latitudes in the southern hemisphere. The peak of this sinusoidal variation occurs at around 7 hr U.T. and decreases exponentially in size from about 300 km (depending on local time, season, solar flux) with increasing or decreasing altitude. During local summer conditions the amplitude is larger than during local winter conditions and particularly high values occur near the solar maximum. Selecting data from magnetically quiet periods, a quantitative model is constructed of the UT-eflect in the topside electron densities.     

鄂尔多斯盆地南部延长组富铀凝灰岩地球化学特征及形成机制

本文系统地研究了鄂尔多斯盆地南部延长组凝灰岩元素和同位素地球化学特征。结果表明：凝灰岩主量元素具有高K、高Al、Si中等至高、低Na的特征; REE总体特征为轻稀土富集、重稀土亏损,∑REE在4857～40212 μg/g 之间变化,Eu呈现出负异常,在034～082内变化,δCe范围在080～208之间; 微量元素中U含量在312～144 μg/g 之间,Ba、U、Th、Hf和Ce呈明显正异常,Nb、P、Ti和Rb呈现负异常。详细的分析表明：U的富集和一些微量元素如Ta、Dy、Lu等相关,Th与∑REE存在明显的正相关性,这些变化可能和盆地中铀矿的富集有关; 凝灰岩的硫同位素总体呈现深源特征。根据以上的研究对凝灰岩的形成原因及形成环境进行了探讨。鄂尔多斯盆地南部延长组凝灰岩来源于秦岭造山带火山作用,其中的铀元素富集是由于砂岩型铀矿中铀向凝灰岩迁移而被还原所致。本研究对盆地砂岩型铀矿的铀运移和富集机理认识具有一定指导意义。     

Discontinuity controlled probabilistic slope failure risk maps of the Altindag (settlement) region in Turkey

The evaluation of potential rock slope problems using stereographic projection techniques known as kinematic analysis is one of the most important parts of a slope stability investigation to be carried out in jointed rock media. In conventional stereoprojection techniques for the assessment of possible rock slope failures, the peak orientations of joints together with the slope geometry and the friction angle of the weakness planes are used. Other possible joint orientations which may be encountered in the rock media are ignored, although they belong to the group of joint peak orientations. In this study, nearly vertical jointed andesites cropped out at the Altindag settlement region in Ankara were studied in order to evaluate the relevance of this ignored discontinuity orientation data on slope stability. As a result, probabilistic risk maps for planar, toppling and wedge failures were produced using the kinematic rules and digital elevation model of the study area. The comparison of the distribution of the actual failures in the area and the probabilistic risk maps prepared for the study area revealed that all of the identified failures are found to be located in the higher risk zones on the probabilistic risk maps.