Dissolution kinetics of fosteritic olivine at 90-150 °C including effects of the presence of CO2

The steady state dissolution rate of San Carlos olivine [Mg_1.82Fe_0.18 SiO₄] in dilute aqueous solutions was measured at 90, 120, and 150 °C and pH ranging from 2 to 12.5. Dissolution experiments were performed in a stirred flow-through reactor, under either a nitrogen or carbon dioxide atmosphere at pressures between 15 and 180 bar. Low pH values were achieved either by adding HCl to the solution or by pressurising the reactor with CO₂, whereas high pH values were achieved by adding LiOH. Dissolution was stoichiometric for almost all experiments except for a brief start-up period. At all three temperatures, the dissolution rate decreases with increasing pH at acidic to neutral conditions with a slope of close to 0.5; by regressing all data for 2 ? pH ? 8.5 and 90 °C ? T ? 150 °C together, the following correlation for the dissolution rate in CO₂-free solutions is obtained:

     

Behavior of the broad Hα component in the Seyfert galaxy NGC 4151 in 1976–2003

Variations in the flux and profile of the broad Hα component in the Seyfert galaxy NGC 4151 are analyzed based on spectral observations acquired from 1976 to spring 2003. The procedure used to distinguish components is described. There is a strong correlation between the flux of the broad Hα component and the U flux of the galactic nucleus. There was an appreciable increase in the intensity of the broad Hα in 1990–2000, with the flux reaching a maximum in 1996. The intensity and shape of an emission feature that appeared in the red wing of the broad Hα component at the end of 2002 are estimated.     

Proxies for land plant biomass: closed system pyrolysis of some methoxyphenols

Methoxyphenols can be used as proxies for terrestrial biomass when investigating the chemical changes in lignin during hydrothermal alteration. The closed system microscale pyrolysis of 2-methoxyphenol (2-MOP) and 2,6-dimethoxyphenol (2,6-DMP), in the presence of water vapour, has been studied in borosilicate glass vessels. 2-MOP was heated isothermally at temperatures of 330°C for 96 h and 2,6-DMP was heated isothermally at 300°C for 118 h. Pyrolysis of the model compound 2-MOP gave a simple product distribution which was composed mainly of 1,2-dihydroxybenzene with lower amounts of 2-methylphenol and phenol. The prominent reaction products from heating 2,6-DMP were 1,2-dihydroxy-6-methoxybenzene and 2-methoxy-6-methylphenol, with minor amounts of 2-MOP, 1,2-dihydroxybenzene and 2-methylphenol. The decreasing amounts of 2,6-DMP with heating time and the concomitant increase in the amounts of 1,2-dihydroxy-6-methoxybenzene suggested that demethylation had occurred.     

Abundance Gradients in the Outer Galactic Disk

Radial abundance gradients of the element ratios O/H, Ne/H, S/H, and Ar/H are determined for a sample of disk planetary nebulae, emphasizing the behaviour of the gradients at large galactocentric distances. This revised version was published online in July 2006 with corrections to the Cover Date.