Deep drilling at the Siljan Ring impact structure: oxygen-isotope geochemistry of granite

The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, ¹⁸O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5 at 5760 m depth. In contrast, feldspar ¹⁸O values decrease with depth from near 10 at the surface to 7.1 at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of ¹⁸O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar ¹⁸O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100–300° C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500° C) exchange between alkali feldspar and fluids. The high-temperature exchange may have been a post-impact event involving impact-heated fluids, or a post-magmatic event.     

Diffusion-deposition patterns in Martian streaks

The spreading angle of a number of light and dark Martian streaks is determined from selected Mariner 9 images. The resulting frequency distributions of spreading half-angles have maxima at ～5° for light, and ～7° for dark streaks; however the dark streaks have a secondary maximum spreading angle at ～14°. The smaller values, which include most streaks, are interpreted as crater-wake spreading phenomena. The larger value, found in only a few dark streaks or “tails,” may result from atmospheric diffusion and subsequent deposition of material from isolated sources such as vents or blowouts. An atmospheric diffusion-deposition analysis is presented, assuming this streak origin, from which it is possible to deduce the eddy diffusivity, K, in Mars' boudary layer. Calculated K values are found to agree with various theoretical estimates. They lie in the range 10⁷ and 10⁹ cm² sec^?1 and exhibit the proper scale dependence. Thus it appears that, in addition to streak-derived wind direction patterns and speed information, it is possible in a few cases to derive information on Mars' boundary-layer turbulence from streak-spreading measurements.     

Reconstruction of the diagenesis of the fluvial-lacustrine- deltaic sandstones and its influence on the reservoir quality evolution-- Evidence from Jurassic and Triassic sandstones, Yanchang Oil Field, Ordos Basin

The reservoir quality of Jurassic and Triassic fluvial and lacustrine-deltaic sandstones of the Yanchang Oil Field in the Ordos Basin is strongly influenced by the burial history and facies-related diagenetic events. The fluvial sandstones have a higher average porosity (14.8%) and a higher permeability (12.7×10?3 ?m2) than those of the deltaic sandstones (9.8% and 5.8 ×10?3 ?m2, respectively). The burial compaction, which resulted in 15% and 20% porosity loss for Jurassic and Triassic sandstones, respectively, is the main factor causing the loss of porosity both for the Jurassic and Triassic sandstones. Among the cements, carbonate is the main one that reduced the reservoir quality of the sandstones. The organic acidic fluid derived from organic matter in the source rocks, the inorganic fluid from rock-water reaction during the late diagenesis, and meteoric waters during the epidiagenesis resulted in the formation of dissolution porosity, which is the main reason for the enhancement of reservoir-quality.     

Causes of Geochemical Diversity of Carbon Dioxide Water in Crystalline Rock Masses

The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO₂ (P _CO2).     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.