Effect of agricultural activity on levels of organochlorine pesticides in hard corals, fish and molluscs from the Great Barrier Reef

An organochlorine baseline study of selected corals, fish and molluscs has established that lindane is the only consistently detectable persistent pesticide in Great Barrier Reef organisms sampled. Samples taken during 1976–1977 from twenty reefs between Heron Island and Lizard Island provide evidence from the distribution of lindane that the contamination is related to agricultural usage in the coastal sugar cane growing regions. Consideration is given to the possible mode of transport of lindane to the reef environment. No polychlorinated biphenyls were detected in any of the samples and only scattered samples contained levels of residues other than lindane. Inner marginal shelf reefs of the Great Barrier Reef may be the most pristine environment yet reported for organochlorine pollutants.     

不同风区海面雷达后向散射的极化特征对比分析

通过对海南省南保港附近海面ＳＩＲ－Ｃ／Ｘ－ＳＡＲ全极化数据的定量研究,对比研究了该海面不同风区海面的全极化信息特征,定量分析了海面散射的极化信息和极化状态的空间结构情况：用散射矩阵的迹解释了不同海区的散射强度对应关系：对比海面散射极化响应可以确定不同成长类型的粗糙海面类型;用极化响应图的对称特点界定“长尺度”和“短尺度”海面;建立全极化海面散射模型。讨论了海面电磁散射的贡献与雷达系统参数之间的定量     

Underwater sounds near a fuel receiving facility in western Hong Kong: relevance to dolphins

Western Hong Kong is home to two species of marine mammals: Indo-Pacific humpbacked dolphins (Sousa chinensis) and finless porpoises (Neophocaena phocaenoides). Both are threatened in many parts of their range in southeast Asia [for example, International Biological Research Institute Reports 9 (1997), 41; Asian Marine Biology 14 (1997) 111]. In 1998, when the new Hong Kong International Airport opened in western Hong Kong, small tankers (about 100 m long, cargo capacity about 6300 metric tons) began delivering fuel to the Aviation Fuel Receiving Facility (AFRF) just off Sha Chau Island, north of the airport. Calibrated sound recordings were taken over a 4-day period from a quiet, anchored boat at distances 80-2000 m from aviation fuel delivery activities at the AFRF. From the recordings, 143 sections were selected for analysis. Narrowband spectral densities on the sound pressures were computed, and one-third octave band levels were derived for center frequencies from 10 to 16,000 Hz. Broadband levels, viz. 10-20,000 Hz. were also computed. The results showed that the Sha Chau area is normally noisy underwater, with the lowest broadband levels measured corresponding to those expected during a storm at sea (sea state 6). This background noise is believed to come largely from heavy vessel traffic in the Urmston Road to the north and east of Sha Chau and from vessels in the Pearl River Estuary to the West. The sound levels from the AFRF tankers are comparable to the levels measured from similar- and smaller-sized supply vessels supporting offshore oil exploration. The strongest sounds recorded were from a tanker leaving the AFRF at distance 100 m from the hydrophone, for which the one-third octave band level at 100 Hz was 141 dB re 1 microPa (spectrum level 127 dB re 1 microPa2/Hz) and the 10-20,000 Hz broadband level was 146 dB. At distances of 100 m or more and frequencies above 300 Hz, the one-third octave band levels were less than 130 dB (spectrum level 111 dB re 1 microPa2/Hz) and decreased with increasing frequency and distance. At distances greater than about 500 m, AFRF-associated sounds were negligible, masked by the generally high noise level of the area and attenuated by poor transmission in the very shallow water (<10 m). Because it is believed that humpbacked dolphins and finless porpoises are not very sensitive to sounds below 300 Hz, the Airport Authority Hong Kong (AA) stipulated that dedicated terminal vessels not radiate underwater sounds at spectrum levels greater than 110 dB re 1 microPa2/Hz at frequencies above 300 Hz and distances greater than 300 m. The spectrum levels at 300 Hz and higher frequencies of sounds from the tankers arriving, departing, or off-loading at AFRF were less than 110 dB re 1 microPa2/Hz even at distances of 200 m or less. The AA stipulation was met. However, it is presently unknown whether the generally strong noise levels of western Hong Kong inhibit acoustically based feeding and communication, or result in increased stress or permanent shifts in hearing thresholds.     

大鹏湾潮流数值计算

应用分步杂交方法建立了大鹏湾边界潮流数值模型，并对其进行了模拟计算，重现了该区域潮波及潮流的分布规律，并根据实测资料对其进行了验证，从而可系统地了解这一海区的潮波系统及潮流场等海洋要素的分布情况。     

Magnitude-frequency relationship of coastal sand delivery by a southern California stream

Coastal sand delivery by a stream in southern California is estimated based on a numerical model which stimulates unsteady flow, sediment transport, and the associated channel adjustments for a stream-delta system. An average annual sediment yield of 51,400 m³/yr is estimated for the San Dieguito River, which drains a semiarid watershed controlled by dams. Of the total sand delivery by the stream, 20.5 percent is contributed from floods greater than the 100-year flood; 17.6 percent from those between the 50- and 100-year events; 28.4 percent from those between the 25- and 50 year floods; and 33.5 percent from those smaller than the 25-year flood.     

An optimized method for automated analysis of algal pigments by HPLC

A recent development in algal pigment analysis by high-performance liquid chromatography (HPLC) is the application of automation. An optimization of a complete sampling and analysis protocol applied specifically in automation has not yet been performed. In this paper we show that automation can only be successful if the various methodological aspects of the sampling and analysis protocol are considered in coherence. We introduce an optimized protocol that involves freeze-drying of the sample, subsequent extraction in 90% acetone and the application of water-packing during analysis. The method was evaluated on both natural plankton populations and a broad spectrum of microalgal cultures: Thalassiosira weisflogii (Bacillariophyceae), Emiliania huxleyi (Prymnesiophyceae), Phaeocystis globosa and Phaeocystis antarctica (Prymnesiophyceae) and Pyramimonas sp. (Prasinophyceae). Whereas pigment extracts were unstable in methanol, with recorded chlorophyll a losses from 10% to 60% per day, pigment degradation rates in acetone were generally less than 1% over 18 h storage in the autosampler (4 °C). In addition, it was found that the extraction efficiency of acetone significantly increased upon freeze-drying prior to extraction. Increases as high as 50–60% were measured in P. antarctica. The application of water-packing of the sample during injection resulted in improved peak shape and peak separation, without diluting the pigment concentrations. Automation is especially beneficial for application in the field, when mixed algal assemblages and low biomass put a high demand on the sensitivity as well as reproducibility of the method.     

Analysis of medaka cytochrome P450 3A homotropic and heterotropic cooperativity

We have previously demonstrated that medaka CYP3A is associated with metabolism of several endobiotics including steroids and bile acids. In this study, we demonstrate that medaka CYP3A catalysis exhibits unusual kinetic behaviors consistent with allosteric interaction which cannot be described by hyperbolic kinetic models. Using 7-benzyloxy-4-(trifluoromethyl)-coumarin (BFC) and nonylphenol as CYP3A substrates, we describe both homotropic and heterotropic cooperative interactions. Given the role of CYP3A in maintaining the homeostatic balance for numerous endobiotics, enzymatic activation/inhibition by endocrine disruptors (EDCs) represents a putative (non-genomic) mechanism for endocrine disruption.     

Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions

Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ¹³C_POC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C₃ plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C₄ vegetation (Spartina alterniflora) and/or marine phytoplankton.     

Numerical Solution of Lock-Release Gravity Current with Viscous Self-Similar Regime

Lock-release gravity currents with a viscous self-similar regime are simulated by use of the renormalization group(RNG) k - ε model for Reynolds-stress closure. Besides the turbulent regime with initially a slumping phase of a conslant current front speed and later an inviseid self-similar phase of front speed decreasing as t^-1/3(where t is the time measured from release), the viseous self-similar regime is satisfactorily reproduced with front speed decreasing as t^-4/5,consistent with well known experimental observations.     

The optimum control of thruster system for dynamically positioned vessels

An offshore vessel with a dynamic positioning system (DP system) needs fast response to produce thrust to counteract the environmental forces acting on it for the purpose of maintaining its position and heading as close as possible to the working position. Therefore, quick and effective modulation of the thrust is the problem to determine the thrust and the rotation angle of the thruster devices of the ship. This paper presents an effective optimum control for a thruster system, using the sequential quadratic method to achieve economical and effective modulation of the thrust and the direction of the thruster. An optimum control study of a 2280 tons DP coring vessel with five rotary azimuth thruster marine positioning is studied in detail, which can quickly and exactly estimate the thrusts and angles of direction of all the thrusters. The results can provide a valuable thruster system for a dynamically positioned vessel.