Composition of hydrous melts in equilibrium with quartz eclogites

Summary Compositions of the hydrous melts in equilibrium with garnet, omphacitic clinopyroxene and quartz have been investigated experimentally at 28.5 and 35 kbar. They are represented by silica-rich liquids (> 70% SiO₂) with low MgO, FeO and CaO contents. The removal of ca 10–15% of the magma of this composition may be sufficient to convert quartz eclogite formed after subduction of altered MORB into a quartz-free bimineralic eclogite assemblage, which is a common type of xenoliths in kimberlites.At 28.5 kbar the solidus temperature is between 700 and 750° C in the system quartz eclogite—water, and the high pressure amphibole-out boundary lies at ca 25 kbar in accord with the previous studies.

---

Die Zusammensetzung wasserhältiger Schmelzen im Gleichgewicht mit Quarz-Eklogiten

Zusammenfassung Um Prozesse zu simulieren, die bei der Subduktion von Ozeanbodenbasalten durch partielle Anatexis im Stabilitätsfeld von Eklogiten ablaufen, wurde die Zusammensetzung wasserhältiger Schmelzen in Gleichgewicht mit Granat, Omphacit und Quarz bei 28.5 und 35 Kbar experimentell untersucht. Diese Schmelzen sind reich an SiO₂ (> 70 Gew%) und arm an Mg0, Fe0 and CaO. Die Extraktion von ca. 10–15% derartiger Schmelzen würde genügen, um quarzführende Eklogite, die durch die Subduktion von alteriertem MORB Material entstanden sind, in quarzfreie bimineralische Eklogite umzuwandeln wie sie häufig als Xenolithe in Kimberliten beobachtet werden.Im System Quarz-Eklogit-Wasser liegt die Solidustemperatur bei 28.5 Kbar zwischen 700 und 750°C. Die obere Stabilitätsgrenze von Amphibol liegt in diesem Temperaturbereich bei ca. 25 Kbar.

---

---

With 1 Figures     

A new, instantaneous aeolian sand trap design for field use

A new aeolian sediment trap is described which can give up to 1 Hz measurement frequency in field conditions. The trap adopts a circular, horizontal trap design with a load cell connection to give continuous, unobtrusive trap measurement of sediment flux. Simultaneous velocity recording is carried out using an anemometer. Trap construction costs are approximately £200. Initial results in field conditions using a direct comparison of wind velocity data, sampled at an equivalent frequency, have given a first-order relationship between sediment flux and velocity. The trap enables simultaneous sampling of wind velocity and sediment flux at a sufficiently short interval to enable investigation of sediment transport dynamics under a variety of field conditions.     

Ice wastage and landscape evolution along the southern margin of the Laurentide Ice Sheet, north-central Wisconsin

The Chippewa and Wisconsin Valley Lobes of the Laurentide Ice Sheet reached their maximum extent in north-central Wisconsin about 20 000 years ago. Their terminal positions are marked by a broad area of hummocky topography, containing many ice-walled-lake plains, which is bounded on the up-ice and down-ice sides by ice-contact ridges and outwash fans. The distribution of these ice-disintegration landforms shows that a wide zone of stagnant, debris-covered, debris-rich ice separated from the active margins of both lobes as they wasted northward during deglaciation. Accumulation of thick, uncollapsed sediment in ice-walled lakes high in the ice-cored landscape indicates a period of stability. In contrast, hummocky disintegration topography indicates unstable conditions. Thus, we interpret two phases of late-glacial landscape evolution. During the first phase, ice buried beneath thick supraglacial sediment was stable. Supraglacial lakes formed on the ice surface and some melted their way to solid ground and formed ice-walled lakes. During the second phase, buried ice began to melt rapidly, hummocky topography formed by topographic inversion, and supraglacial and ice-walled lakes drained. We suggest that ice wastage was controlled primarily by climatic conditions and supraglacial-debris thickness. Late-glacial permafrost in northern Wisconsin likely delayed wastage of buried ice until after about 13 000 years ago, when climate warmed and permafrost thawed.     

Characterisation of brown coal humic acids and modified humic acids using pyrolysis gcms and other techniques

It has been proposed that Victorian brown coal can be considered as a two-component structure — a lignocellulosic “host”, containing various amounts of weakly bound or entrapped “guest” material together with very small amounts of inorganic and/or mineral matter. The latter predominantly consists of wax esters and/or terpenoid material. In this paper we describe attempts to gain structural information regarding the more complex, “host” component of the coal. Our initial model compound has been humic acid that can be readily obtained from the coal by alkaline extraction. It has been found that “pure” humic acid, free from material associated with the “guest” components of the coal, can be obtained by a highly selective, low-yielding alkaline extraction. This humic acid has been studied by nmr spectroscopy and pyrolysis gas chromatography-mass spectroscopy (py-gc/ms). The products arising from py-gc/ms have been compared with those obtained from similar pyrolysis of whole coals. Alkylation of humic acids using alkyl halides in the presence of base has been successfully carried out and reactivity of the resulting materials compared with those of the parent coal and humic acid.     

Leucoxene fish as a micro-kinematic indicator

Asymmetric aggregates of fine-grained leucoxene and quartz are reported from siliceous L-S tectonites deformed by progressive simple shear. The leucoxene fish, morphologically similar to mica fish, consistently yield shear senses in agreement with other kinematic criteria. We interpret the leucoxene as a pre- or early syntectonic alteration product of detrital heavy-minerals in a siliciclastic protolith. The leucoxene fish behave as passive markers, and they record kinematics by modification of pre-existing aggregates rather than syndeformational mineral growth. For siliceous metasedimentary rocks otherwise lacking in micro-kinematic indicators, leucoxene fish may provide an alternative to quartz c-axis analysis.     

Neogene volcanism and Holocene earthquakes in the Tanlu fault zone, eastern China

In this paper, we study the relationship between Neogene volcanism and Holocene earthquakes in the Tanlu fault, eastern China. We find that fault segments through which Neogene and Quaternary magma have extruded do not show Holocene slip because they are covered by unfaulted basalts. In contrast, fault branches that are away from the Quaternary volcanic centers display Quaternary faulting and are responsible for earthquakes as recorded both historically and geomorphologically. Therefore, magma intrusion appears to modify fault activity in two different ways: (1) within the faults, the cooling magma serves as a cohesion or barrier, welding the faults so that they become stronger in resisting slip; (2) beneath the faults, the upwelling magma promotes slip of faults above the magma body, and hence generation of earthquakes. Physically, the first case results from contraction of the cooling magma, which causes a relative increase in fault-normal stress so that the fault failure resistance is enhanced. The second case results from the upward dynamic force and the heat brought in by the magma body, both of which cause the effective fault-normal stress to decrease so that the fault failure resistance is reduced. That could explain why earthquakes occur on faults bypassing the volcanic centers as typified in the Yishu fault zone and in the regions where heat flows are relatively high as shown in the Bohai Bay area.     

A traverse through the western Kunlun (Xinjiang,China): tentative geodynamic implications for the Paleozoic and Mesozoic

The northern part of the western Kunlun (southern margin of the Tarim basin) represents a Sinian rifted margin. To the south of this margin, the Sinian to Paleozoic Proto-Tethys Ocean formed. South-directed subduction of this ocean, beneath the continental southern Kunlun block during the Paleozoic, resulted in the collision between the northern and southern Kunlun blocks during the Devonian. The northern part of the Paleo-Tethys Ocean, located to the south of the southern Kunlun, was subducted to the north beneath the southern Kunlun during the Late Paleozoic to Early Mesozoic. This caused the formation of a subduction-accretion complex, including a sizeable accretionary wedge to the south of the southern Kunlun. A microcontinent (or oceanic plateau?), which we refer to as “Uygur terrane,” collided with the subduction complex during the Late Triassic. Both elements together represent the Kara-Kunlun. Final closure of the Paleo-Tethys Ocean took place during the Early Jurassic when the next southerly located continental block collided with the Kara-Kunlun area. From at least the Late Paleozoic to the Early Jurassic, the Tarim basin must be considered a back-arc region. The Kengxiwar lineament, which “connects” the Karakorum fault in the west and the Ruogiang-Xingxingxia/Altyn-Tagh fault zone in the east, shows signs of a polyphase strike-slip fault along which dextral and sinistral shearing occurred.     

The age and thermal history of Cerro Rico de Potosi, Bolivia

 Cerro Rico de Potosi, Bolivia, is the world’s largest silver deposit and has been mined since the sixteenth century for silver, and for tin and zinc during the twentieth century, together with by-product copper and lead. The deposit consists primarily of veins that cut an altered igneous body that we interpret to be a dacitic volcanic dome and its underlying tuff ring and explosion breccia. The deposit is compositionally and thermally zoned, having a core of cassiterite, wolframite, bismuthinite, and arsenopyrite surrounded by a peripheral, lower-temperature mineral assemblage consisting principally of sphalerite, galena, lead sulfosalt, and silver minerals. The low-temperature assemblage also was superimposed on the high-temperature assemblage in response to cooling of the main hydrothermal system. Both the dacite dome and the ore fluids were derived from a larger magmatic/hydrothermal source at depth. The dome was repeatedly fractured by recurrent movement on the fault system that guided its initial emplacement. The dome was extruded at 13.8±0.2 Ma (2σ), based on U-Th-Pb dating of zircon. Mineralization and alteration occurred within about 0.3 my of dome emplacement, as indicated by a ⁴⁰Ar/³⁹Ar date of 13.76±0.10 Ma (1σ) for sericite from the pervasive quartz-sericite-pyrite alteration associated with the main-stage, high-temperature, mineralization. The last thermal event able to reset zircon fission tracks occurred no later than 12.5±1.1 Ma (1σ), as indicated by fission-tract dating. Minor sericite, and magmatic-steam alunite veins, were episodically formed around 11 Ma and between 8.3 and 5.7 Ma; the younger episodes occurring at the time of extensional fracturing at Cerro Rico and widespread volcanism in the adjacent Los Frailes volcanic field. None of these younger events appear to be significant thermal/mineralizing events; the exceptionally flat thermal release pattern of ³⁹Ar from sericite and the results of the fission-tract dating of zircon show that none of the younger events was hot enough, and lasted long enough, to cause significant loss of Ar or annealing of zircon fission tracks. U-Th-Pb dating of zircon cores indicates a Precambrian progenitor for some zircons, and REE analyses of dated samples of hydrothermally altered dacite show the presence of a prominent positive Eu anomaly, which constrains interpretations of the origin and evolution of the magmatic/hydrothermal system. Received: 14 October 1995/Accepted: 29 January 1996     

An evaluation of models of apatite compositional variability using apatite from the Middle Banded series of the Stillwater Complex,Montana

 Apatite is a relatively common accessory mineral in the olivine-bearing zones (OB-III and OB-IV) of the Middle Banded series of the Stillwater complex, occurring interstitial to cumulus grains, as monomineralic inclusions in cumulus grains, and in polymineralic clusters which may or may not be included in the cumulus grains. Eighty-nine of 185 samples examined were found to contain some apatite. The F-Cl-OH content of the apatite show distinct stratigraphic variations. XClAp (mole fraction Cl in apatite) of interstitial apatite increases upsection in both OB-III and OB-IV with average values ranging from 0.15 to 0.85 in OB-III and from 0.03 to 0.60 in OB-IV. XFAp varies inversely with XClApwith average values ranging from 0.00 to 0.70, while XOHAp remains relatively constant near 0.40 or decreases slightly with height. These variations are remarkable given that no appreciable stratigraphic variations in either the major or trace element compositions of any of the cumulus minerals are found in the 800 m of section that comprise OB-III and OB-IV. Within-sample variation of XClAp for samples containing Cl-rich apatite is substantially larger (up to 0.65 XClAp) than for samples with more F-rich apatite (XClAp varies by approximately 0.15). Although interstitial apatite is found throughout OB-III and OB-IV, apatite occurring as monomineralic inclusion in cumulus grains or in polymineralic clusters is almost exclusively found in samples with Cl-rich apatite. The data are best explained by a model involving the degassing of a Cl-rich volatile phase from the crystallizing interstitial liquid. The up-section migration of this fluid resulted in the crystallization of F-rich apatite in the lower portion and progressive Cl-enrichment in the apatite with height. The presence of hornblende-bearing dikes, veins and pegmatoids at the level of maximum Cl-enrichment is consistent with a fluid migration model. Received: 5 October 1995 / Accepted: 19 March 1996