Trace gas measurements during aircraft flights in the tropopause region over Europe and North Africa

During aircraft flights in May 1981 from Munich (40°N) to north of the Spitsbergen Islands (82°N) and to Monrovia, Liberia (6°N), air samples were obtained in the altitude range of 8 to 11 km and during the ascents and descents near the airports. These samples have been analyzed for the trace gas mixing ratios of CH₄, CO and N₂O. The results of these analyses are presented and discussed.The results provide new evidence of tropospheric-stratospheric exchange events in the vicinity of the subpolar and subtropical tropopause foldings and possibly show a case of transport of CO-enriched air in the upper troposphere above the North Atlantic Ocean.     

Determination of Phobos’ rotational parameters by an inertial frame bundle block adjustment

A functional model for a bundle block adjustment in the inertial reference frame was developed, implemented and tested. This approach enables the determination of rotation parameters of planetary bodies on the basis of photogrammetric observations. Tests with a self-consistent synthetic data set showed that the implementation converges reliably toward the expected values of the introduced unknown parameters of the adjustment, e.g., spin pole orientation, and that it can cope with typical observational errors in the data. We applied the model to a data set of Phobos using images from the Mars Express and the Viking mission. With Phobos being in a locked rotation, we computed a forced libration amplitude of \(1.14^\circ \pm 0.03^\circ \) together with a control point network of 685 points.     

Long-term hydrology and aquatic biogeochemistry data from H. J. Andrews Experimental Forest,Cascade Mountains,Oregon

The H. J. Andrews Experimental Forest (HJA) encompasses the 6400 ha Lookout Creek watershed in western Oregon, USA. Hydrologic, chemistry and precipitation data have been collected, curated, and archived for up to 70 years. The HJA was established in 1948 to study the effects of harvest of old-growth conifer forest and logging-road construction on water quality, quantity and vegetation succession. Over time, research questions have expanded to include terrestrial and aquatic species, communities and ecosystem dynamics. There are nine small experimental watersheds and 10 gaging stations in the HJA, including both reference and experimentally treated watersheds. Gaged watershed areas range from 8.5 to 6242 ha. All gaging stations record stage height, water conductivity, water temperature and above-stream air temperature. At nine of the gage sites, flow-proportional water samples are collected and composited over 3-week intervals for chemical analysis. Analysis of stream and precipitation chemistry began in 1968. Analytes include dissolved and particulate species of nitrogen and phosphorus, dissolved organic carbon, pH, specific conductance, suspended sediment, alkalinity, and major cations and anions. Supporting climate measurements began in the 1950s in association with the first small watershed experiments. Over time, and following the initiation of the Long Term Ecological Research (LTER) grant in 1980, infrastructure expanded to include a set of benchmark and secondary meteorological stations located in clearings spanning the elevation range within the Lookout Creek watershed, as well as a large number of forest understory temperature stations. Extensive metadata on sensor configurations, changes in methods over time, sensor accuracy and precision, and data quality control flags are associated with the HJA data.     

Equilibrium and disequilibrium degassing of a phonolitic melt (Vesuvius AD 79 “white pumice”) simulated by decompression experiments

Equilibrium and disequilibrium degassing of a volatile phase from a magma of K-phonolitic composition was investigated to assess its behavior upon ascent. Decompression experiments were conducted in Ar-pressurized externally heated pressure vessels at superliquidus temperature (1050 °C), in the pressure range 10–200 MPa using pure water as fluid phase. All experiments were equilibrated at 200 MPa and then decompressed to lower pressures with rates varying from 0.0028 to 4.8 MPa/s. Isobaric saturation experiments were performed at the same temperature and at 900–950 °C to determine the equilibrium water solubility in the pressure range 30–250 MPa. The glasses obtained from decompression experiments were analyzed for their dissolved water content, vesicularity and bubble size distribution. All decompressed samples presented a first event of bubble nucleation at the capsule–melt interface. Homogeneous bubble nucleation in the melt only occurred in fast-decompressed experiments (4.8 and 1.7 MPa/s), for ΔP ≅ 100 MPa. For these decompression rates high water over-saturations were maintained until a rapid exsolution was triggered at ΔP > 150 MPa. For slower rates (0.0028, 0.024, 0.17 MPa/s) the degassing of the melt took place by diffusive growth of the bubbles nucleating at the capsule–melt interface. This process sensibly reduced water over-saturation in the melt, preventing homogeneous nucleation to occur. For decompression rates of 0.024 and 0.17 MPa/s low water over-saturations were attained in the melt, gradually declining toward equilibrium concentrations at low pressures. A near-equilibrium degassing path was observed for a decompression rate of 0.0028 MPa/s. Experimental data combined with natural pumice textures suggest that both homogeneous and heterogeneous bubble nucleations occurred in the phonolitic magma during the AD 79 Vesuvius plinian event. Homogeneous bubble nucleation probably occurred at a depth of ∼ 3 km, in response to a fast decompression of the magma during the ascent.     

Synchronous uplift of the lower crust of the Ivrea Zone and of Southern Calabria and its possible consequences for the Hercynian orogeny in Southern Europe

Along the border of the Adriatic microplate, pre-Alpine granulite-facies rocks from the deepest crust are outcropping at only two places: in the Ivrea Zone of the Southern Alps and in Southern Calabria. In these two areas the main features of the present crustal structures, i.e. overlapping of large continental crustal and upper mantle segments, are interpreted as resulting from their Hercynian geodynamic evolutions.The tilted, nearly complete crustal sections in both areas display very similar lithological sequences and experienced a common geological evolution, as deduced from petrological and radiometric dates. At the end of Hercynian time (～295 m.y.), the Ivrea body and the lower crustal rocks of Southern Calabria were contemporaneously sheared off from the upper mantle and uplifted into intermediate crustal levels, where they slowly cooled during Mesozoic time. The tectonic uplift was accompanied by granitoid plutonism and andesitic to rhyolitic volcanism, which continued after the Hercynian uplift.Considering the presently similar crustal structures and the Upper Carboniferous and Permian geological evolutions along the whole Adriatic plate boundary, the Ivrea Zone and Southern Calabria are used to resolve the pre-Alpine history of the boundary zone between the Adriatic and the Central European block: the uplift of the lower crustal/upper mantle flakes of the Adriatic block was due to flat overthrusting of these flakes on the continental crust of “Central Europe”. The material of the Central European crust underthrust (subducted) thereby melted during the re-equilibration of the geotherms which had been disturbed by the subduction process; this led to an extensive calc-alkaline plutonism and volcanism of crustal origin along the Adria boundary. In this boundary region, the overlying uppermost crustal levels (“Schiefergebirgsstockwerk”) were synchronously folded (“Asturian phase”) in response to the overlapping of the deeper crustal levels. Subsequently to the orogeny, the mountain chain was eroded and molasse basins developed on the overthrust Adriatic crustal segment during the Lower Permian.In this model, the granulite-facies flakes of the Ivrea Zone and of Southern Calabria are interpreted as pre-Hercynian lower crustal segments which were thrust into the middle crust during the Hercynian orogeny, thus giving rise to wave velocity inversions in the crust. Further, it is proposed that similar geodynamic processes have played a role in the genesis of the Conrad discontinuity which is present in many parts of the Hercynian fold belt. But only in the Ivrea Zone and in Southern Calabria the crustal discontinuities formed in Hercynian time were uplifted to the surface as a result of Alpine reactivation of the Adriatic boundary zone and due to their special positions in the bends of the Alpine-Apennine-Maghrebide mountain system.According to the present knowledge of the Carboniferous paleogeography and of the orogenic evolution on both sides of the Adria sufure zone, this fault zone was located within the European continent. Its role during the Hercynian orogeny is discussed envisaging two possibilities: an A-subduction zone or a subfluence zone (in the sense of Behr and Weber).     

Streams in the Harz National Parks (Germany) — a hydrochemical and hydrobiological evaluation

Between 1995 and 2001, 16 measuring points at small and medium sized brooks in the Harz National Parks were sampled. The samples have been evaluated by means of hydrochemistry and macroinvertebrate biology. Although nearly all streams are largely uncontaminated by oxygen-consuming substances, they are settled only by a small number of macroinvertebrate species. There is a clear correlation between this number and pH. The reduction in species number with decrease of pH is mainly caused by the absence of most Ephemeroptera, some Coleoptera and Trichoptera. Comparing biological evaluation of acidity with physico-chemical measurements, a unacceptable underestimation was found. The reason could be that different sensitivities to acidification between regional populations seem to exist.

Despite of the low species number, there is a very specific macroinvertebrate fauna that emphasizes the conservation value of the Harz National Parks.     

Self‐purification in Upland and Lowland Streams

Ecological investigations at four streams in Saxony‐Anhalt have shown that there are considerable differences between the self‐purification power of upland and lowland streams. This result is reflected in chemistry and in microbiology. The structure of the bottom substrate mainly influences the degree of self‐purification in connection with rate of flow and flow velocity. The results and differences are demonstrated using the example of Katzsohlbach in the landscape unit “Mittel‐ and Unterharz” and the stream Olbe in the landscape unit “Magdeburger Börde”.