全文获取类型
收费全文 | 382篇 |
免费 | 7篇 |
国内免费 | 4篇 |
专业分类
测绘学 | 14篇 |
大气科学 | 25篇 |
地球物理 | 76篇 |
地质学 | 158篇 |
海洋学 | 12篇 |
天文学 | 91篇 |
自然地理 | 17篇 |
出版年
2023年 | 2篇 |
2020年 | 3篇 |
2019年 | 7篇 |
2018年 | 8篇 |
2017年 | 5篇 |
2016年 | 7篇 |
2015年 | 12篇 |
2014年 | 21篇 |
2013年 | 14篇 |
2012年 | 11篇 |
2011年 | 17篇 |
2010年 | 17篇 |
2009年 | 29篇 |
2008年 | 20篇 |
2007年 | 22篇 |
2006年 | 21篇 |
2005年 | 17篇 |
2004年 | 11篇 |
2003年 | 28篇 |
2002年 | 17篇 |
2001年 | 7篇 |
2000年 | 8篇 |
1999年 | 9篇 |
1998年 | 7篇 |
1997年 | 6篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1986年 | 4篇 |
1984年 | 3篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1975年 | 2篇 |
1971年 | 3篇 |
1970年 | 2篇 |
1967年 | 3篇 |
1958年 | 2篇 |
1956年 | 2篇 |
1952年 | 1篇 |
1951年 | 1篇 |
1950年 | 2篇 |
1949年 | 1篇 |
1948年 | 1篇 |
1942年 | 1篇 |
1940年 | 1篇 |
1939年 | 1篇 |
排序方式: 共有393条查询结果,搜索用时 31 毫秒
31.
32.
33.
Diego F. Torres Shu Zhang Olaf Reimer Xavier Barcons Amalia Corral Valentí Bosch-Ramon Josep M. Paredes Gustavo E. Romero Jin Qu Werner Collmar Volker Schönfelder Yousaf Butt 《Astrophysics and Space Science》2007,309(1-4):17-21
The COMPTEL unidentified source GRO J 1411-64 was observed by INTEGRAL and XMM-Newton in 2005. The Circinus Galaxy is the
only source detected within the 4σ location error of GRO J1411-64, but in here excluded as the possible counterpart. At soft X-rays, 22 reliable and statistically
significant sources (likelihood >10) were extracted and analyzed from XMM-Newton data. Only one of these sources, XMMU J141255.6-635932,
is spectrally compatible with GRO J1411-64 although the fact the soft X-ray observations do not cover the full extent of the
COMPTEL source position uncertainty make an association hard to quantify and thus risky. At the best location of the source,
detections at hard X-rays show only upper limits, which, together with MeV results obtained by COMPTEL suggest the existence
of a peak in power output located somewhere between 300–700 keV for the so-called low state. Such a spectrum resembles those
in blazars or microquasars, and might suggest at work by the models accordingly. However, an analysis using a microquasar
model consisting on a magnetized conical jet filled with relativistic electrons, shows that it is hard to comply with all
observational constrains. This fact and the non-detection at hard X-rays introduce an a-posteriori question mark upon the
physical reality of this source, what is discussed here. 相似文献
34.
Extracellular enzymatic hydrolysis of high-molecular weight organic matter is the initial step in sedimentary organic carbon degradation and is often regarded as the rate-limiting step. Temperature effects on enzyme activities may therefore exert an indirect control on carbon mineralization. We explored the temperature sensitivity of enzymatic hydrolysis and its connection to subsequent steps in anoxic organic carbon degradation in long-term incubations of sediments from the Arctic and the North Sea. These sediments were incubated under anaerobic conditions for 24 months at temperatures of 0, 10, and 20 °C. The short-term temperature response of the active microbial community was tested in temperature gradient block incubations. The temperature optimum of extracellular enzymatic hydrolysis, as measured with a polysaccharide (chondroitin sulfate), differed between Arctic and temperate habitats by about 8-13 °C in fresh sediments and in sediments incubated for 24 months. In both Arctic and temperate sediments, the temperature response of chondroitin sulfate hydrolysis was initially similar to that of sulfate reduction. After 24 months, however, hydrolysis outpaced sulfate reduction rates, as demonstrated by increased concentrations of dissolved organic carbon (DOC) and total dissolved carbohydrates. This effect was stronger at higher incubation temperatures, particularly in the Arctic sediments. In all experiments, concentrations of volatile fatty acids (VFA) were low, indicating tight coupling between VFA production and consumption. Together, these data indicate that long-term incubation at elevated temperatures led to increased decoupling of hydrolytic DOC production relative to fermentation. Temperature increases in marine sedimentary environments may thus significantly affect the downstream carbon mineralization and lead to the increased formation of refractory DOC. 相似文献
35.
Alexandra V. Turchyn Volker Brüchert Gregory S. Engel Daniel P. Schrag 《Geochimica et cosmochimica acta》2010,74(7):2011-6698
Kinetic isotope effects related to the breaking of chemical bonds drive sulfur isotope fractionation during dissimilatory sulfate reduction (DSR), whereas oxygen isotope fractionation during DSR is dominated by exchange between intercellular sulfur intermediates and water. We use a simplified biochemical model for DSR to explore how a kinetic oxygen isotope effect may be expressed. We then explore these relationships in light of evolving sulfur and oxygen isotope compositions (δ34SSO4 and δ18OSO4) during batch culture growth of twelve strains of sulfate-reducing bacteria. Cultured under conditions to optimize growth and with identical δ18OH2O and initial δ18OSO4, all strains show 34S enrichment, whereas only six strains show significant 18O enrichment. The remaining six show no (or minimal) change in δ18OSO4 over the growth of the bacteria. We use these experimental and theoretical results to address three questions: (i) which sulfur intermediates exchange oxygen isotopes with water, (ii) what is the kinetic oxygen isotope effect related to the reduction of adenosine phosphosulfate (APS) to sulfite (SO32−), (iii) does a kinetic oxygen isotope effect impact the apparent oxygen isotope equilibrium values? We conclude that oxygen isotope exchange between water and a sulfur intermediate likely occurs downstream of APS and that our data constrain the kinetic oxygen isotope fractionation for the reduction of APS to sulfite to be smaller than 4‰. This small oxygen isotope effect impacts the apparent oxygen isotope equilibrium as controlled by the extent to which APS reduction is rate-limiting. 相似文献
36.
Volker Kahlenberg Daniela Girtler Erik Arroyabe Reinhard Kaindl Daniel M. Többens 《Mineralogy and Petrology》2010,100(1-2):1-9
Single crystals of devitrite (Na2Ca3Si6O16) were synthesized as pale-yellow transparent needle shaped crystals using a Na2MoO4-flux. Experiments aiming to prepare the K-equivalent of devitrite from the corresponding K2MoO4-flux were unsuccessful. The crystal structure of devitrite was determined from single-crystal X-ray diffraction data (Mo-Kα radiation, 2θmax.?=?25.34°, Rint?=?2.66%) and refined in space group P $ \bar{1} $ (no. 2) to R(|F|)?=?3.08% using 2,513 observed reflections with I?>?2σ(I). Unit-cell parameters are: a?=?7.2291(8), b?=?10.1728(12), c?=?10.6727(12) Å, α?=?95.669(9), β?=?109.792(10), γ?=?99.156(9)°, V?=?719.19(14) Å3, Z?=?2. The structure belongs to the group of multiple chain silicates consisting of dreier quadruple chains, i.e. the crystallochemical formula can be written as $ {\hbox{N}}{{\hbox{a}}_2}{\hbox{C}}{{\hbox{a}}_3}\left\{ {{\mathbf{uB}}{,4}_\infty^1} \right\}\left[ {^3{\hbox{S}}{{\hbox{i}}_6}} \right.\left. {{{\hbox{O}}_{16}}} \right\} $ . Linkage between the bands running along [100] is provided by double chains of edge sharing CaO6-octahedra as well as additional more irregularly coordinated Na- and Ca-cations located in the tunnel-like cavities of the mixed tetrahedral-octahedral framework. Structural investigations were completed by Raman and infrared spectroscopical studies. The allocation of the bands to certain vibrational species was aided by density functional theory (DFT) calculations. 相似文献
37.
Application of SWACI products as ionospheric correction for single-point positioning: a comparative study 总被引:1,自引:0,他引:1
In Global Navigation Satellite Systems (GNSS) using L-band frequencies, the ionosphere causes signal delays that correspond with link related range errors of up to 100 m. In a first order approximation the range error is proportional to the total electron content (TEC) of the ionosphere. Whereas this first order range error can be corrected in dual-frequency measurements by a linear combination of carrier phase- or code-ranges of both frequencies, single-frequency users need additional information to mitigate the ionospheric error. This information can be provided by TEC maps deduced from corresponding GNSS measurements or by ionospheric models. In this paper we discuss and compare different ionospheric correction methods for single-frequency users. The focus is on the comparison of the positioning quality using dual-frequency measurements, the Klobuchar model, the NeQuick model, the IGS TEC maps, the Neustrelitz TEC Model (NTCM-GL) and the reconstructed NTCM-GL TEC maps both provided via the ionosphere data service SWACI (http://swaciweb.dlr.de) in near real-time. For that purpose, data from different locations covering several days in 2011 and 2012 are investigated, including periods of quiet and disturbed ionospheric conditions. In applying the NTCM-GL based corrections instead of the Klobuchar model, positioning accuracy improvements up to several meters have been found for the European region in dependence on the ionospheric conditions. Further in mid- and low-latitudes the NTCM-GL model provides results comparable to NeQuick during the considered time periods. Moreover, in regions with a dense GNSS ground station network the reconstructed NTCM-GL TEC maps are partly at the same level as the final IGS TEC maps. 相似文献
38.
Based on a large number of energy-economic and integrated assessment models, the Energy Modeling Forum (EMF) 27 study systematically explores the implications of technology cost and availability for feasibility and macroeconomic costs of energy system transformations toward climate stabilization. At the highest level, the technology strategy articulated in all the scenarios in EMF27 includes three elements: decarbonization of energy supply, increasing the use of low-carbon energy carriers in end-use, and reduction of energy use. The way that the scenarios differ is in the degree to which these different elements of strategy are implemented, the timing of those implementations, and the associated macroeconomic costs. The study also discusses the value of individual technologies for achieving climate stabilization. A robust finding is that the unavailability of carbon capture and storage and limited availability of bioenergy have the largest impact on feasibility and macroeconomic costs for stabilizing atmospheric concentrations at low levels, mostly because of their combined ability to remove carbon from the atmosphere. Constraining options in the electric sector such as nuclear power, wind and solar energy in contrast has a much smaller impact on the cost of mitigation. 相似文献
39.
Pilar Lecumberri-Sanchez Rolf L. Romer Volker Lüders Robert J. Bodnar 《Mineralium Deposita》2014,49(3):353-369
More than 50 % of the world's total reserves of tungsten are in China and most tungsten deposits are located in the Nanling range in southeast China. This study explores the potential genetic relationship between tungsten–tin (W–Sn) mineralization and shallower Ag–Pb–Zn deposits in the Nanling range based on data from the Wutong deposit, Guangxi Province. The lead, oxygen, carbon, sulfur, and strontium isotopic compositions of minerals at Wutong indicate that a single crustal-derived fluid was responsible for mineralization. Wutong likely formed at relatively low temperatures (~200–300 °C) and low pressures, as indicated by the similarity between homogenization temperatures of fluid inclusions and those estimated from S isotopic compositions of minerals. The hübnerite age (92.3–104.4 Ma) indicates that the Wutong mineralization is likely related to nearby Late Yanshanian (Cretaceous) S-type granites derived from Proterozoic crust. This mineralization event coincides with the last W–Sn mineralization event and the Cretaceous peak of mineralization in the Nanling range. 相似文献
40.
The Neogene quartz andesites from the Oa? and Gutâi Mountains (Romania) are mid-K calc-alkaline rocks and contain plagioclase-orthopyroxene-clinopyroxene-amphibole-magnetite phenocrysts as well as quartz crystals. They are associated with a volcanic sequence ranging from basalts and basaltic andesites to dacites and rhyolites, but form a separate magma group, mostly in respect to the trace elements. Based on the geochemical data combined with inferences from complex zoning patterns in plagioclase and pyroxene, the evolution of quartz andesites is interpreted in terms of fractional crystallization, AFC and magma mixing. A parental magma deriving from a MORB- or OIB-type source modified by fluids and melts originating from sediments is envisaged. 相似文献