Palynology, geochemistry, and thermal history of the shales associated with the Küre massive sulfide deposits (northern Turkey)

The relationship between the palynology and geochemistry of the shales associated with the Küre massive sulfide deposits in the Kastamonu Province, northern Turkey, has been studied. SEM seems to be the most effective method to study the palynology of fusinitic particulate organic matter in these thermally-altered sedimentary rocks. Major thermal maturation indicators obtained from the organic and inorganic fractions of the shales and mineral geothermometers of the orebodies suggest that the shales indicate much lower temperatures that the ore and therefore were deposited after the formation of the massive sulfide ores in the area of study.     

Comprehensive study on automation of toxic gas measurement

The condition of the ambient air must be continuously checked to detect hazardous gas leakage and ensure the safety of employees in hazardous gas production and storage areas. Detection and elimination of hazardous gas leaks can be done with various complex measurement, safety, and disposal systems. These measurement systems consist of different types of sensor and require control and monitoring system. This leads to high investment and operating costs. In this study, semi-continuous measurement system automation with a single set of sensors working by taking air samples from different points over specific periods has been designed to reduce investment, operation, and maintenance repair costs. In the design, the measurement points are divided into zones and codes in the automation system. Thus, it is aimed to keep a constant record of what the air sample is coming from and what its content is. As a result, it has been determined that it is possible to establish a measurement and automation system similar to existing hazardous gas measurement systems with less investment and operating costs. The proposed automation system has been applied in the industrial storage area. In addition, a cost analysis has been performed and compared with conventional systems.     

Manifestations of Quaternary syn-eruptive fluid circulations on carbonate veins,Central Anatolian Volcanic Province

In this study, we investigate the geochronological, geochemical and isotopic characteristics of two travertine sites surrounded by Quaternary eruption centres in central Anatolia with ample palaeo-eruption records. High-resolution carbonate precipitation records, revealed by U-Th dating, are clustered around 5–35, 60–100 and 120–170 ka and are well correlated with the dataset on eruptions as well as the position of fractures related to the volcanic centres. Syn-eruptive carbonate precipitation seems to occur due to the circulation of CO₂-rich fluids along the extensional fracture systems aligned tangentially to the related volcanic conduit and, therefore, the study of this system could be an alternative technique for the reconstruction of palaeo-eruptions. δ¹⁸O values of the studied travertines are within the range of meteogene fluids. Oxygen isotope compositions at around 130 ka match well with Glacial Termination II that is also recorded by climate proxies in various cave and benthic deposits throughout the world. It is likely that the studied carbonates were precipitated under similar fluid circulation conditions which are represented by a high rate of dilatation followed by a meteoric water influx into the extensional fractures.     

Reply to Comment on “Analyses of Seismic Deformation at the Kibyra Roman Stadium,Southwest Turkey”

In their comment, Elitez and Yaltırak (2013) criticize our paper (Karabacak et al. 2013 ) by arguing that it contains misinterpretations and unreliable data for a fault cutting the Roman Stadium in the ancient city of Kibyra. However their comments are not based on strong arguments to disprove our geological and archeological field observations or previous data. Here we present additional data supported by new figures which validate the faulting both in the bedrock and in the stadium floor. We reject their comments and uphold our original viewpoint on the faulting at the Stadium.     

Astrometric Solution of the Multiple System Xy Leo

An astrometric solution, together with time of minimum analysis, has been made for the multiple system XY Leonis (HIP 49136) to identify the properties of the remote companion to the eclipsing pair (AB). From this solution, we derive the inclination of the wide orbit (AB-cd) as 94.4^∘± 0.2^∘, angle of nodes as 247.3^∘± 0.2^∘, and the mass of the wide component (the dwarf binary cd) as 0.98 ± 0.2 M_⊙. This study confirms that the light travel time effect can explain the sinusoidal O−C variation of the eclipsing system.     

Image classification-based ground filtering of point clouds extracted from UAV-based aerial photos

With the advent of unmanned aerial vehicles (UAVs) for mapping applications, it is possible to generate 3D dense point clouds using stereo images. This technology, however, has some disadvantages when compared to Light Detection and Ranging (LiDAR) system. Unlike LiDAR, digital cameras mounted on UAVs are incapable of viewing beneath the canopy, which leads to sparse points on the bare earth surface. In such cases, it is more challenging to remove points belonging to above-ground objects using ground filtering algorithms generated especially for LiDAR data. To tackle this problem, a methodology employing supervised image classification for filtering 3D point clouds is proposed in this study. A classified image is overlapped with the point cloud to determine the ground points to be used for digital elevation model (DEM) generation. Quantitative evaluation results showed that filtering the point cloud with this methodology has a good potential for high-resolution DEM generation.     

Physical Characteristics of Umbral Dots Derived from a High-Resolution Observations

Solar Physics - We study the features of the magnetic field variations within the 2011 June 7 eruptive event that includes a large filament eruption, a flare, and a CME formation. The magnetic...     

Spectrophotometric Determination of Gold (III) after Liquid–Liquid Extraction and Selective Pre‐concentration with a Novel Dibenzo‐18‐Crown‐6 Derivative

A selective and sensitive method for the extraction and spectrophotometric determination of gold with N,N′‐6,7,9,10,17,18,20,21‐octahydrodibenzo[b,k][1,4,7,10,13,16] hexaoxacyclo‐octadecine‐2,13–diylbis(2‐chloroacetamide) (ODBOCA) is described. The ODBOCA–Au(III) complex was extracted from a slightly acidic aqueous solution (pH 5) into a chloroform layer and then the absorbance of the extract was measured using a UV–Vis spectrophotometer with 1.0 cm quartz cells at 540 nm. An enrichment factor of 200 was achieved. In the chloroform medium at 540 nm, the molar absorptivity and Sandell’s sensitivity were 4.12 × 10³ l mol^?1 cm^?1 and 0.048 μg cm^?2, respectively. Beer’s law was obeyed in the range of 0.5–15 μg ml^?1 in the measured solution. The relative standard deviation for ten replicate samples at the 1.0 μg ml^?1 level was 3.0%. The limit of detection, based on 3s, was 0.5 μg l^?1 in the original sample. The effects of pH, ligand concentration and shaking time were studied. The ratio of the metal ion to ligand molecules in the complex was found to be 1:2 according to the Job Method. The effects of interference by a number of metal ions were investigated. The method was verified with certified reference materials and spiked tests, and quantitative recovery values were obtained. The method was fast, accurate, selective and precise, and was applied to the determination of gold in water and ore with good results.     

Spatial distribution patterns and temporal trends of heavy-metal concentrations in a petroleum hydrocarbon-contaminated site: Karaduvar coastal aquifer (Mersin, SE Turkey)

The aim of this study was to investigate spatiotemporal variations in groundwater heavy-metal concentrations at the Karaduvar agricultural-industrial district (Mersin, SE Turkey), where parts of the underlying coastal aquifer has been polluted by petroleum hydrocarbons (PHCs) from diverse sources. The water chemistry data for the present study is comprised of 275 samples collected during 2006–2010 from 55 water-supply wells. The samples were analyzed in situ for physical parameters (EC, DO, pH, and temperature) and in the laboratory for As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb and Zn using the ICP-MS method. Box–whisker plots and principal components analysis (PCA) method were employed to determine the seasonal changes occurring in heavy-metal concentrations and to identify source apportionment of pollution parameters in groundwater. During the monitoring period, in many wells, heavy-metal concentrations (except for Cd) exceeded the limit values set by Turkish Water Pollution Control Directive (No: 25687). Results from the PCA suggest that elevated Mn, Fe, Co, Ni and As concentrations may be linked to oxidation–reduction of geogenic Mn/Fe oxyhydroxides in PHC-contaminated parts. The high concentrations of Cu, Mo and probably Cd in background areas result from the agricultural and petrochemical activities conducted in the recent past. At the site, high Pb and Zn concentrations are probably related to agricultural activities in PHC-contaminated areas, whereas Cr can be solely attributed to lithogenic sources. At the Karaduvar site, heavy-metal pollution in groundwater is found to be much more persistent than PHC contamination.