Dust particles in the atmospheres of terrestrial planets and their roles for prebiotic chemistry: An overview

The available literature on sources, chemical composition, and importance of dust particles for the origins of life is analyzed. The most abundant sources of dust on the early terrestrial planets are sedimentation of interplanetary dust, meteoritic/cometary impacts, and volcanic eruptions. Interplanetary dust can originate directly from interstellar space, from evaporation of cometary bodies, from collisional destruction of asteroidal and meteoritic bodies, and nucleation in sunspots. Many rather complex organic species, including those of prebiotic interest, have been identified in the interstellar medium and cometary dust. Some of them are believed to formvia catalytic processes on the surfaces of dust particles. However, the mechanisms are not known, and even simulating experiments are difficult to perform due to insufficient knowledge of physical conditions in the space media and of chemical composition and properties of the dust. Besides the catalytic roles, cometary dust is believed to be the best delivery vehicle for organic matter of space origin to the atmospheres of terrestrial planets. Abundant sources of catalytically active fine dust can be volcanoes. Various organic and biological compounds have been found in terrestrial volcanic gases and ash, which are assumed to formvia the catalytic Fischer-Tropsch reactions. At present the eruptions on the Earth provide a unique opportunity to observein situ the formation of organic matter, and knowledge of the ash composition and local conditions allows to perform simulating experiments.     

Precise temperature monitoring in boreholes: evidence for oscillatory convection? Part II: theory and interpretation

In the previous part of this work (Cermak, Safanda and Bodri, this volume p.MMM) we have described experimental data and quantified the heterogeneity features of the microtemperature time series. The spectral analysis and the local growth of the second moment technique revealed scaling structure of all observed time series generally similar and suggested the presence of two temperature forming processes. The longer-scale part can be attributed to the heat conduction in compositional and structural heterogeneous solid rocks, further affected by various local conditions. Short-scale temperature oscillations are produced by the intra-hole fluid convection due to inherent instability of water column filling the hole. Here we present how the observational evidence is supported by the results of the computer simulations. The exact modes of intra-hole convection may be different, ranging from quasi-periodic (“quiescent”) state to close of turbulence. As demonstrated by numerical modeling and referred on laboratory experiments, at higher Rayleigh numbers the periodic character of oscillation characteristic for “quiescent” regime is superseded by stochastic features. This so called “oscillatory” convection occurs due to instability within the horizontal boundary layers between the individual convectional cells. In spite of the fact that the basic convective cell motion is maintained and convection is characterized by slow motion, the oscillatory intra-hole flow and corresponding temperature patterns exhibit typical features of turbulence. The idea of boundary layer instability as a source of stochastic temperature fluctuations could explain many distinct features of borehole temperatures that previously cannot be interpreted.     

Evaluation of landfill disposal boundary by means of electrical resistivity imaging

This paper deals with an employment of electrical resistivity imaging (ERI) for survey of leachate content on the waste disposal site in Northern Israel. The research consisted of conducting ten ERI lines and drilling investigation wells. Data simulation used a 2D EarthImager inversion program. Analysis of 2D ERI interpretation results shows that determination of the boundary between the landfill body bottom intensively saturated with leachates and underlying layers of highly water saturated fat nonconsolidated clays presents a challenge. However, statistical analysis of ERI data indicates that standard deviation and confidence interval of a set of resistivity data measured in the landfill body are significantly larger than those in underlying clays. Moreover, maximum changes of these parameters are found on the boundary between landfill body and underlying soil, thus reflecting natural differences in scattering of resistivity data measured in these two objects.     

Early diagenetic vivianite [Fe3(PO4)2 · 8H2O] in a contaminated freshwater sediment and insights into zinc uptake: A μ-EXAFS, μ-XANES and Raman study

The sediments in the Salford Quays, a heavily-modified urban water body, contain high levels of organic matter, Fe, Zn and nutrients as a result of past contaminant inputs. Vivianite [Fe₃(PO₄)₂ · 8H₂O] has been observed to have precipitated within these sediments during early diagenesis as a result of the release of Fe and P to porewaters. These mineral grains are small (<100 μm) and micron-scale analysis techniques (SEM, electron microprobe, μ-EXAFS, μ-XANES and Raman) have been applied in this study to obtain information upon the structure of this vivianite and the nature of Zn uptake in the mineral. Petrographic observations, and elemental, X-ray diffraction and Raman spectroscopic analysis confirms the presence of vivianite. EXAFS model fitting of the FeK-edge spectra for individual vivianite grains produces Fe–O and Fe–P co-ordination numbers and bond lengths consistent with previous structural studies of vivianite (4O atoms at 1.99–2.05 Å; 2P atoms at 3.17–3.25 Å). One analysed grain displays evidence of a significant Fe³⁺ component, which is interpreted to have resulted from oxidation during sample handling and/or analysis. EXAFS modelling of the Zn K-edge data, together with linear combination XANES fitting of model compounds, indicates that Zn may be incorporated into the crystal structure of vivianite (4O atoms at 1.97 Å; 2P atoms at 3.17 Å). Low levels of Zn sulphate or Zn-sorbed goethite are also indicated from linear combination XANES fitting and to a limited extent, the EXAFS fitting, the origin of which may either be an oxidation artifact or the inclusion of Zn sulphate into the vivianite grains during precipitation. This study confirms that early diagenetic vivianite may act as a sink for Zn, and potentially other contaminants (e.g. As) during its formation and, therefore, forms an important component of metal cycling in contaminated sediments and waters. Furthermore, for the case of Zn, the EXAFS fits for Zn phosphate suggest this uptake is structural and not via surface adsorption.     

Non-linear elastic behaviour of damaged rocks

The pervasive damage of rocks by microcracks and voids strongly affects their macroscopic elastic properties. To evaluate the damage effects, we derive here the macroscopic stress-strain relations for a 3-D elastic solid with non-interacting cracks embedded inside a homogeneous matrix. The cracks considered are oriented either perpendicular to the maximum tension axis, or perpendicular to the maximum compression axis. In the first case they dilate during loading and in the second case they contract during loading. We derive a solution for the elastic energy of this rock following the self-consistent scheme of Budiansky & O'Connell (1976). The solution describes the stress-strain relations in terms of Λ^d and μ^d, which are the modified Lame constants, and an additional parameter Λ. The latter accounts for the non-linear behaviour of the solid and is related to crack density. The solution predicts a non-linear elastic rheology even for an infinitesimal strain of ɛ < 0.001, and abrupt change in the elastic moduli when the loading reverses from uniaxial compression to uniaxial tension.
We use the derived solution to analyse rock-mechanics experiments in which beams of Indiana limestone were deformed under four-point loading. This configuration provides simultaneously the apparent tensile and compressive moduli for small strains. The apparent moduli fit the effective elastic moduli calculated with the present damage model well, including the differences between tensile and compressive moduli.     

Masers, Lasers and the Interstellar Medium

This paper discusses recent results obtained by myself and my colleagues in three domains of astrophysics: interstellar supersonic turbulence, circumstellar disks, and natural masers and lasers. S.A. Kaplan, S.B. Pikelner, and I.S. Shklovskii were among those who, 30-40 years ago, laid the foundation of these domains.H2O masers become an effective probe of supersonic turbulence associated with mass outflow from very young stars. They demonstrate a very low (1) fractal dimension of the spatial set on which turbulence dissipates its kinetic energy, and, thereby, a strong intermittency of the turbulence. They also indicate that supersonic turbulence, like incompressible turbulence, has an inner scale, on which the bulk of turbulent energy dissipates in low-Mach, random shocks. H2O masers themselves find thereby a new pumping source in these random shocks.Masers in hydrogen recombination lines, discovered 8 years ago, originate in a circumstellar disk surrounding a massive star MWC 349A. They give a possibility to investigate kinematics and structure of the disk. Far-infrared nydrogen recombination lines, recently detected in MWC349A from the Kuiper Airborn Observatory, proved to be amplified as well. They are the first known natural amplifiers of electromagnetic waves in the laser wavelength domain. Analysis of their radiation, along with the radiation in other recombination lines, gives a possible key to understanding the lack of optical lasers in the Universe.     

Variations of dissolved iron in the Amur River during an extreme flood event in 2013

As a key factor limiting primary productivity in marine ecosystem, dissolved iron(DFe) export from fluvial systems has increased recently. There is particular concern about discharges of DFe during extreme flooding, when they are thought to increase considerably. An extreme flood event that caused inundation of extensive areas of Far Eastern Russia and Northeastern China occurred in the basin of the Amur River during summer and autumn 2013. During this event, water samples were collected in the middle reaches of the Amur River and the lower reaches at Khabarovsk City and analyzed for DFe concentrations and other aquatic parameters. The results show that the average DFe concentrations in the middle reaches of the Amur River(right bank) and at Khabarovsk were 1.11 mg/L and 0.32 mg/L, respectively, during the extreme flood in 2013. The total discharge of DFe during the flood event was 6.25 × 104 t. The high discharge of DFe during the flood reflects the elevated discharge of the river, hydrologically connected riparian wetlands, vast quantities of terrestrial runoff, and flood discharges from the Zeya and Bureya reservoirs. These results show that long-term monitoring is needed to identify and assess the impacts of DFe transport on the downstream reaches, estuarine area, and coastal ecosystems of the Amur River.     

Rank-Size Statistical Assessments of Undiscovered Gold Endowment in the Bendigo and Stawell Zones (Victoria) and the Mossman Orogen (Queensland), Australia: Comparison with Three-Part Assessment Results

The Bendigo and Stawell zones in Victoria and the Mossman Orogen in north Queensland host numerous orogenic gold deposits and are likely to contain significant undiscovered gold resources. This paper discusses applications of Zipf’s law to estimate the scale of residual gold endowment in each of the regions. Testing various plausible scenarios on whether or not the largest deposit in each region has been discovered and its endowment adequately evaluated provided some measure of uncertainty of assessment results. The Bendigo and Stawell zones are estimated to host 12 undiscovered ore fields with >31 t (1 Moz) of contained gold and another 35 undiscovered ore fields with >10 t (0.32 Moz) of gold, containing in total 1600 t (51 Moz) of gold. The total residual orogenic gold endowment of the Mossman Orogen is estimated to be between 3 and 30 t of gold, contained in extensions of known deposits and up to six significant undiscovered gold ore fields each containing >1 t of gold. These estimates are comparable to results of recent three-part quantitative mineral resource assessments for those areas.