The fate and transport of As was examined at an industrial site where soil- and groundwater contamination are derived from the application of As2O3 as a herbicide. Application of arsenical herbicides was discontinued in the 1970s and soils in the source area were partially excavated in 2003. Arsenic contamination (up to 280 mg/kg) remains in the source area soils and a plume of As-contaminated groundwater persists in the surficial aquifer downgradient of the source area with maximum observed As concentrations of 1200 μg/L near the source area. The spatial extent of As contamination as defined by the 10 μg/L contour appears to have remained relatively stable over the period 1996–2006; the boundary of the 1000 μg/L contour has retreated over the same time period indicating a decrease in total As mass in the surficial groundwater.In column experiments conducted with source area soil, the As concentrations in the column effluent were comparable to those observed in groundwater near the source area. A substantial fraction of the As could be leached from the source area soil with ammonium sulfate and ammonium phosphate. Exhaustive extraction with background groundwater removed most of the total As. These results indicate that As in the source area soils is geochemically labile. Source area soils are low in extractable Fe, Mn and Al, and characterization by X-ray absorption spectroscopy and electron microscopy indicated that As is present primarily as arsenate sorbed to (alumino)silicate minerals. Batch sorption experiments showed much less sorption on surficial aquifer sediments than on sediments from the Jackson Bluff Formation (JBF), a presumed confining layer. This limited capacity of the surficial aquifer sediments for As sorption is consistent with the similar As contents observed for these sediments within and upgradient of the As plume. The apparent stability of the As plume cannot be explained by sequestration of As within the surficial aquifer. Sorption to JBF sediments may contribute to As sequestration, but As enrichment in JBF sediments within the plume (i.e., as compared with JBF sediments upgradient) was not observed. These results indicate that neither the persistence of As in the source area soils or the apparent stability of the plume of As-contaminated groundwater at this site can be explained by geochemical controls on As mobility. The absence of demonstrable geochemical bases for such observations suggests that possible hydrologic controls should be further investigated at this site. 相似文献
The long-term variation of the semiannual amplitude in the geomagnetic activity index aa is analyzed with the purpose of contributing to the understanding of solar variability, directly linked to geomagnetic variability. The time series of the semiannual oscillation amplitude, obtained through a wavelet analysis of the daily aa series, presents a long-term variation similar to that shown by solar and geomagnetic indices, like aa itself or Dst. However, the maximum in the semiannual amplitude series occurs around 1947, almost 10 years before it occurs in solar and geomagnetic indices time series. The phase of the semiannual oscillation fluctuates around the values predicted by the equinoctial and Russell–McPherron models, with a predominance of the equinoctial mechanism during the period of maximum semiannual amplitude. A possible source of changes in the equinoctial mechanism would be the secular variation of the Earth's dipole tilt. But, since it does not follow the semiannual amplitude trend, at first sight, it seems not to be responsible for the equinoctial predominance around 1947. The analysis of quiet and disturbed days separately indicates that only disturbed days present the semiannual annual amplitude maximum around 1947, so the 10 year time shift could be due to the mechanism responsible for the semiannual variation in geomagnetically active periods. 相似文献
If the orientation of the principal compressive stress is oblique to layering, viscous multilayers fold in response to the layer-parallel shortening and develop asymmetric interfaces in response to the layer-parallel shear. A theoretical analysis of folding of viscous multilayers with different slip laws at layer contacts shows that the sense of asymmetry of folds is determined largely by the behavior of the layer contacts and the sense of layer-parallel shear during folding.
For a given sense of layer-parallel shear, the sense of asymmetry of folds can be reversed by changing only the behavior of the layer contacts. If the slip rate is linearly proportional to the shear stress at layer contacts, the resistance to slip is the same everywhere along interfaces, and the folds develop the sense of asymmetry of drag folds. If the slip rate is a nonlinear function of the shear stress at layer contacts, however, the resistance to slip varies with position along interfaces, and folds develop the sense of asymmetry of monoclinal kink folds.
For a given variable resistance to slip at layer contacts, the sense of asymmetry depends on the sense and magnitude of the layer-parallel shear and on the thickness-to-wavelength ratio of the multilayer.
For finite multilayers with variable resistance to slip at contacts, an increase in the layer-parallel shear stress decreases the dominant wavelength and increases the amplification factor for the initial perturbation of the interface.
The multilayer consists of linear viscous layers and is confined by thick, viscous media. Resistance to slip at layer contacts is modeled theoretically by a powerlaw relationship between rate of slip and contact shear stress. The equations, derived to 2nd order in the slopes of the interfaces, describe the growth of asymmetric folds from initial, symmetric perturbations. 相似文献
Longitudinal dunes occur in all major sand areas in the world. Their dominant mode of migration or extension is considered to be either prevailing- or resultant wind-parallel, the dunes extending downwind via accretion of the terminal nose. In the Qaidam Pendi in Northwest China a series of active longitudinal dunes extend downwind at 5–10 m yr?1. Internal sedimentary structures examined in the dunes, however, display beds dipping in one direction rather than two opposed directions as is expected. Analysis of aerial photographs confirms that these dunes migrate laterally up to three metres per year, whilst maintaining a symmetrical longitudinal dune morphology. 相似文献
Interactions between pairs of numerically dominant species collected at inlet and creek shorezone and channel habitats within a high salinity estuary in northeastern South Carolina were examined using two-way contingency tables and binomial tests. Of the significant species interactions, over 71% were positive and these primarily occurred within shorezone habitats. The strongest positive interactions were between young-of-the-year spot (Leiostomus xanthurus) and blue crab (Callinectes sapidus) juveniles in both shorezone habitats, and between striped killifish (Fundulus majalis), white mullet (Mugil curema), and striped anchovies (Anchoa hepsetus) in the inlet shorezone habitat. One of the most positive species associations in channel habitats was between the bay anchovy (Anchoa mitchilli) and the Atlantic brief squid (Lolliguncula brevis). These positive relationships between species may be explained by one species enhancing the habitat for another, both species responding to similar environmental conditions, cooperative social interactions such as mixed schooling, or the attraction of predators to prey. Negative interactions were found between schools of Atlantic silversides (Menidia menidia) and striped killifish in the inlet shorezone and between schools of Atlantic silversides and bay anchovies in the creek shorezone. Schools of Atlantic silversides may either displace or compete with other common shorezone species. Positive and negative interactions suggest that relationships between some species pairs did not occur randomly within certain habitats and may have contributed to the organization of the estuarine nekton community. Differences in the strengths and direction of interactions of certain species pairs among habitats and seasons were probably related to the differences in the physical characteristics of those habitats and/or changes in the relative abundance of dominant species and life stages over time. 相似文献
Models that address the impacts of climate change on forests are reviewed at four levels of biological organization: global, regional or landscape, community, and tree. The models are compared for their ability to assess changes in fluxes of biogenic greenhouse gases, land use, patterns of forest type or species composition, forest resource productivity, forest health, biodiversity, and wildlife habitat. No one model can address all of these impacts, but landscape transition models and regional vegetation and land-use models have been used to consider more impacts than the other models. The development of landscape vegetation dynamics models of functional groups is suggested as a means to integrate the theory of both landscape ecology and individual tree responses to climate change. Risk assessment methodologies can be adapted to deal with the impacts of climate change at various spatial and temporal scales. Four areas of research needing additional effort are identified: (1) linking socioeconomic and ecologic models; (2) interfacing forest models at different scales; (3) obtaining data on susceptibility of trees and forest to changes in climate and disturbance regimes; and (4) relating information from different scales.The U.S. Government right to retain a non-exclusive, royalty-free license in and to any copyright is acknowledged.Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy under contract DE-AC05-84OR21400. 相似文献
More above-ground biomass (kg m−2) grows in the northern Appalachian Mountains (USA) in forests on shale than on sandstone at all landscape positions other than ridgetops. This has been tentatively attributed to physical (rather than chemical) attributes of the substrates, such as elevation, particle size, and water capacity. However, shales have generally similar phosphorus (P) concentrations to sandstones and, in the Valley and Ridge province, they erode more quickly. This led us to hypothesize that faster replenishment of the lithogenic nutrient P in shale soils through erosion + soil production could instead control the differences in biomass. To test this, soils and foliage from 10 sites on shales and sandstones in the northern Appalachians from roughly the same elevation and aspect were analysed. We discovered that, when controlling for location, concentrations of bioavailable P in soils and P in foliage were higher and P resorbed from senescing red oak leaves was lower on slower-eroding sandstone than on faster-eroding shale. Lower resorption generally can be attributed to lower P limitation for trees. Further investigation of weathering and erosion on one of the sandstone–shale pairs within a larger, paired watershed study revealed that the differences in P concentrations in biomass and foliage between lithologies likely developed because sandstones act as ‘collectors’ that trap nutrients from residual and exogenous sources, while shales erode quickly and thus promote production of soil from bedrock that releases P to ecosystems. We concluded that the combined effects of differential rates of dust collection and erosion results in roughly equal biomass growing on sandstone and shale ridgetops. This work emphasizes the balance between a landscape's capacity to collect dust versus produce soil in controlling bioavailability of nutrients. 相似文献
Many geomorphologists who are mothers find it challenging to balance field research alongside pregnancy and caring for young children. We offer perspectives on the challenges to conducting fieldwork as mothers and possible solutions, as a means of promoting conversations and highlighting issues that are less commonly considered in field-based geomorphic research. Although every mother's experience and needs are different, we discuss strategies for conducting fieldwork, addressing childcare issues, and dealing with financial considerations. We call for our community to support geomorphologists who are pregnant or caring for young children in carrying out fieldwork to help enhance the diversity of voices and perspectives within our discipline. 相似文献