Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.     

Social vulnerability assessment for mitigation of local earthquake risk in Los Angeles County

Comprehensive hazard mitigation involves (1) understanding natural systems, (2) assessment of interactions within and between social systems and the built environment, and (3) understanding geo-spatial processes. To achieve this, local emergency managers must recognize variability in vulnerable populations exposed to hazards and develop place-based emergency plans accordingly. In this study, we assess whether cities in Los Angeles County are subject to disproportionally greater earthquake losses modeled from a M7.8 earthquake on the San Andreas fault. Furthermore, we analyze whether the variation in demographic and socioeconomic characteristics across cities is associated with the earthquake losses. We were able to explain 23.2?% of variance in economic losses by looking at the percentage of minority residents, income, and renter residents in a city [F(3,84)?=?8.47; p?<?.001]. Cities with primarily minority residents had greater economic losses when compared to cities with primarily White residents (b?=?1.01; p?<?.001). When looking at the association between demographic predictors and potential casualty rate, the percentage of Hispanic residents was positively associated with the potential casualty rate. We argue that knowledge of the relationship between earthquake hazard and the demographic characteristics of people in the area at risk is essential to mitigate the local impact from earthquakes. In other words, we apply social vulnerability assessment as part of a comprehensive risk management framework to accelerate recovery after an event. Local policy makers and the private sector can use this approach to gain a better understanding of a city??s social vulnerability and adapt their preparedness efforts accordingly.     

Using meteorological observer data to compare wind erosion during two great droughts in eastern Australia; the World War II Drought (1937–1946) and the Millennium Drought (2001–2010)

Australian meteorological observers started using the World Meteorological Organization (WMO) weather coding system in the 1950s. This system is still in use around the world today. However, observing and recording the weather in an organized and systematic manner had been ongoing for over 100 years prior to the adoption of this coding system, and much like Australia, most countries will have historical meteorological records. In this paper we compare the wind erosion of two of the greatest droughts in Australian recorded history; the World War II (WWII) Drought (1937–1945) and the Millennium Drought (2001–2009). To do this we analysed previously unavailable meteorological observer records from the Australian Bureau of Meteorology (ABM). Wind erosion records, mostly in long‐hand written form, were translated to the modern WMO coding system for the WWII Drought and compared with the wind erosion of Australia's recently‐ended Millennium Drought, one of the longest and harshest on record. We quantify wind erosion using Dust Event Days (DED) and a modified version of a published Dust Storm Index (DSI) to show that wind erosion during the WWII Drought was up to 4.6 times higher than during the Millennium Drought. This study has international significance because it demonstrates a methodology for tracking changes in wind erosion over the past 75 years based on observer records available in every country with a history of organized weather observation. Copyright © 2014 John Wiley & Sons, Ltd.     

Using Mesoproterozoic sedimentary geochemistry to reconstruct basin tectonic geography and link organic carbon productivity to nutrient flux from a Northern Australian large igneous Province

The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.     

Errors in turbulence measurements with a sonic anemometer

Errors in surface-layer wind data obtained by sonic anemometers are estimated as a function of relative wind direction using a comparison between two identical anemometers. The maximum errors in mean windspeed and the standard deviations of the horizontal wind components are found to be between 10 and 20%. Agreement between the size of the measured errors and those calculated from wind-tunnel data is fair.In addition, vertical velocity data are analysed to show the presence of flow distortion induced by the asymmetry in the sonic anemometer probe and the mounting of the probe on the top of a mast.     

The relation of Holocene fluvial terraces to changes in climate and sediment supply,South Fork Payette River,Idaho

Well-preserved Holocene terraces along the South Fork Payette River in central Idaho provide a record of fluvial system behavior in a steep mountain watershed characterized by weathered and erodible Idaho Batholith granitic rocks. Terrace deposit ages were provided by ¹⁴C dating of charcoal fragments and optically stimulated luminescence (OSL) dating of sandy sediments. Along with pairing of many terrace tread heights, these data indicate episodic downcutting during the Holocene, with a mean incision rate of ～0.9 m/ka from ～7 ka to present. Prior to 7 ka, the river incised to within～3 m of current bankfull, but then aggraded by ～5 m over at least a ～10 km-long reach in an episode centered ～7–6 ka. Aggradation may relate to (1) increased hillslope sediment input from landslides and debris flows in steep tributary basins with abundant grussified granitic bedrock, (2) possible local landslide-damming of the channel, (3) decreased peak discharge, or (4) a combination of these factors. Middle Holocene channel aggradation ca. 7–6 ka corresponds with a period of prolonged and widespread aridity in the northern Rocky Mountains. Between ～5 and 1.3 ka, the river aggraded slightly and then remained stable, forming a prominent terrace tread at ～3 m above current bankfull. Modest aggradation to vertical stability of the South Fork Payette River at the 1.5 m terrace level ～1.0–0.7 ka corresponds with large fire-related debris flows in tributaries during Medieval droughts. Three intervals of incision (～5.5–5 ka, 1.3–1.0 ka and 0.5 ka) correspond with frequent but small fire-related sedimentation events and generally cooler, wetter conditions suggesting increased snowmelt runoff discharges. Other possible drivers of channel incision include an increase in stochastic or climate-modulated large storms and floods and a reduction in delivery of hillslope sediment to the channel. Aggradation is more confidently tied to climate through increases in hillslope sediment delivery and (or) decreased stream power, both likely related to warmer, drier conditions (including high-severity fires) that reduce snowmelt and decrease vegetation cover on steep slopes. Thus, the Holocene terraces of the South Fork Payette River do not reflect simple stepwise incision with periods of vertical stability and lateral migration, but record substantial episodes of aggradation as well. We infer that increases in hillslope erosion and mass movements combined with reduced discharges during prolonged droughts episodically reverse the post-glacial trend of downcutting, in particular during the middle Holocene. The present bedrock-dominated channel implies a strong tendency toward incision in the late Holocene.     

The geothermal potential of the basal clastics of Saskatchewan,Canada

The Winnipeg and Deadwood formations form deep clastic reservoirs in Saskatchewan, Canada, with temperatures exceeding 40 °C over most of southern Saskatchewan and reaching 100 °C in southwestern Saskatchewan. At these temperatures, the formations have geothermal potential for development of direct use and electricity generation systems. Numerous disposal wells operating at rates of 30 L/s or more are currently installed in these formations, suggesting that electricity could be generated at rates exceeding 2 megawatts of electrical output (MW_e) from individual wells. These basal clastic units, thus, could provide significant energy supply over a broad region of Saskatchewan.     

Soil organic carbon enrichment of dust emissions: magnitude,mechanisms and its implications for the carbon cycle

Soil erosion is an important component of the global carbon cycle. However, little attention has been given to the role of aeolian processes in influencing soil organic carbon (SOC) flux and the release of greenhouse gasses, such as carbon dioxide (CO₂), to the atmosphere. Understanding the magnitude and mechanisms of SOC enrichment in dust emissions is necessary to evaluate the impact of wind erosion on the carbon cycle. This research examines the SOC content and enrichment of dust emissions measured using Big Spring Number Eight (BSNE) wind‐vane samplers across five land types in the rangelands of western Queensland, Australia. Our results show that sandy soils and finer particulate quartz‐rich soils are more efficient at SOC emission and have larger SOC dust enrichment than clay‐rich aggregated soils. The SOC enrichment ratios of dusts originating from sites with sand‐rich soil ranged from 2·1–41·9, while the mean enrichment ratio for dusts originating from the clay soil was 2·1. We hypothesize that stronger inter‐particle bonds and the low grain density of the aggregated clay soil explain its reduced capacity to release SOC during saltation, relative to the particulate sandy soils. We also show that size‐selective sorting of SOC during transport may lead to further enrichment of SOC dust emissions. Two dust samples from regional transport events were found to contain 15–20% SOC. These preliminary results provide impetus for additional research into dust SOC enrichment processes to elucidate the impact of wind erosion on SOC flux and reduce uncertainty about the role of soil erosion in the global carbon cycle. Copyright © 2013 John Wiley & Sons, Ltd.     

A tilted Bianchi type-V perfect fluid solution for stiff matter

We present a solution to the Einstein field equations for a massless scalar field in a Bianchi type-V spacetime, which can be interpreted as a solution for a perfect fluid with the equation of state of stiff matter. This solution complements a solution previously given by us for an anisotropic fluid.