Groundwater and surface water connectivity within the recharge area of Guarani aquifer system during El Niño 2014–2016

Recharge areas of the Guarani Aquifer System (GAS) are particularly sensitive and vulnerable to climate variability; therefore, the understanding of infiltration mechanisms for aquifer recharge and surface run‐off generation represent a relevant issue for water resources management in the southeastern portion of the Brazilian territory, particularly in the Jacaré‐Pepira River watershed. The main purpose of this study is to understand the interactions between precipitation, surface water, and groundwater using stable isotopes during the strong 2014–2016 El Niño Southern Oscillation event. The large variation in the isotopic composition of precipitation (from ?9.26‰ to +0.02‰ for δ¹⁸O and from ?63.3‰ to +17.6‰ for δ²H), mainly associated with regional climatic features, was not reflected in the isotopic composition of surface water (from ?7.84‰ to ?5.83‰ for δ¹⁸O and from ?49.7‰ to +33.6‰ for δ²H), mainly due to the monthly sampling frequency, and groundwater (from ?7.04‰ to ?7.76‰ for δ¹⁸O and from ?49.5‰ to ?44.7‰ for δ²H), which exhibited less variation throughout the year. However, variations in deuterium excess (d‐excess) in groundwater and surface water suggest the occurrence of strong secondary evaporation during the infiltration process, corresponding with groundwater level recovery. Similar isotopic composition in groundwater and surface water, as well as the same temporal variations in d‐excess and line‐conditioned excess denote the strong connectivity between these two reservoirs during baseflow recession periods. Isotopic mass balance modelling and hydrograph separation estimate that the groundwater contribution varied between 70% and 80%, however, during peak flows, the isotopic mass balance tends to overestimate the groundwater contribution when compared with the other hydrograph separation methods. Our findings indicate that the application of isotopic mass balance methods for ungauged rivers draining large groundwater reservoirs, such as the GAS outcrop, could provide a powerful tool for hydrological studies in the future, helping in the identification of flow contributions to river discharge draining these areas.     

Recharge seasonality based on stable isotopes: Nongrowing season bias altered by irrigation in Nebraska

The sustainability of groundwater resources for agricultural and domestic use is dependent on both the groundwater recharge rate and the groundwater quality. The main purpose of this study was to improve the understanding of the timing, or seasonality, of groundwater recharge through the use of stable isotopes. Based on 768 groundwater samples collected from aquifers underlying natural resources districts in Nebraska, the isotopic composition of groundwater (δ²H and δ¹⁸O) was compared with that of precipitation by (a) mapping the isotopic composition of groundwater samples and (b) mapping a seasonality index for groundwater. Results suggest that for the majority of the state, groundwater recharge has a nongrowing season signature (October–April). However, the isotopic composition of groundwater suggests that in some intensively irrigated areas, human intervention in the water cycle has shifted the recharge signature towards the growing season. In other areas, a different human intervention (diversion of Platte River water for irrigation) has likely produced an apparent but possibly misleading nongrowing season recharge signal because the Platte River water differs isotopically from local precipitation. These results highlight the need for local information even when interpreting isotopic data over larger regions. Understanding the seasonality of recharge can provide insight into the optimal times to apply fertilizer, specifically in highly conductive soils with high leaching potential. In areas with high groundwater nitrate concentrations, this information is valuable for protecting the groundwater from further degradation. Although previous studies have framed nongrowing season recharge within the context of future climate change, this study also illustrates the importance of understanding how historical human intervention in the water cycle has affected groundwater recharge seasonality and subsequent implications for groundwater recharge and quality.     

Lysimeter soil water balance evaluation for an experiment developed in the Southern Brazilian Atlantic Forest region

This study aims at monitoring the behaviour of the rainfall, runoff, drainage, soil water storage, and evapotranspiration variables involved in the water balance measured by lysimeter data. The evaluation of the water balance considered different time scales, where the components were monitored daily and in 10‐day accumulated period intervals. The results demonstrated that in wet periods the soil water content was greater at a depth of 10 cm, whereas in the dry periods a greater concentration was observed at 70 cm depth. At the depth of 30 cm, the lowest values of soil water content were observed for both wet and dry periods. The results, obtained through the use of tensiometers and time domain reflectometry installed internally and externally to the lysimeter, were very close, which was more noticeable during the periods of lower water loss by the soil. The water balance, calculated from the lysimeter data, demonstrated that 70% of the total rainfall was lost by the process of evapotranspiration. The drainage accounted for 27·5% of the precipitated water, highlighting the fact that this component should not be disregarded in the water balance calculation. Copyright © 2011 John Wiley & Sons, Ltd.     

The use of geoprocessing to assess vulnerability on the east coast aquifers of Rio de Janeiro State,Brazil

The east coast of Rio de Janeiro State, Brazil, shows a worrying overlap between areas with intrinsic groundwater vulnerability and the most significant urban expansion zones. It experienced a rapid population growth in recent years, mainly due to the tourism industry, resulting in a significant pressure on drinking groundwater resources. In this regard, development and use of techniques to control and protect areas susceptible to contamination is crucial. The elaboration of aquifer vulnerability maps is thus extremely helpful to support water resources management. The aim of the work is to present the methodological approach in the use of Geoprocessing techniques to obtain a suitable groundwater vulnerability model in Rio de Janeiro east coast. Considering the existing problems and the current land use and characteristics of the study region, it is clear that the most vulnerable areas (that is, “extreme” and “very high” vulnerability areas), coincide with the most significant zones of urban occupation, corresponding to 11% of the total study area, demanding adoption of urgent measures in the near future. Geoprocessing tools and remote sensing for characterization of Rio de Janeiro’s east coast aquifer vulnerability gave good results, representing a satisfactory method for management actions at low cost.     

U–Pb and Sm–Nd geochronology of amphibolites from the Curaçá Belt, São Francisco Craton, Brazil: Tectonic implications

The Curaçá terrane is part of the Itabuna–Salvador–Curaçá (I–S–C) Paleoproterozoic orogen in the São Francisco craton, northeastern Brazil, and comprises supracrustal rocks, gneisses of their probable basement, amphibolites, and mafic-ultramafic Cu-bearing bodies (including the Caraíba Cu-Mine), all affected by D₁-D₃ deformation events associated to M₁-M₃ metamorphism under high-T granulite and amphibolite facies, and assisted by G₁-G₃ tonalitic-granodioritic-granitic intrusions. U–Pb and Sm–Nd Thermal Ionization Mass Spectrometry (TIMS) isotopic data from amphibolite, tonalite, and granite, sampled in a well-known outcrop, indicate partial reset and heterogeneous modification of the original isotopic systems, attributable to deformation and metamorphism. The ages obtained from these systems agree with each other, and also with other previously published U–Pb data, and imply that 2.6 Ga is the crystallization age of the protolith of the amphibolite. Together with key structural relationships, they also indicate a 2.08–2.05 Ga interval for M₃ metamorphism, and make even a less precise age (2.2–2.3 Ga) acceptable, as it suggests contamination in the amphibolite with material in a syn-D₂ tonalite crystallized 2248 ± 36 Ma ago. The new data demonstrate the existence of Neoarchean fragments of both oceanic and continental crusts and constrain the Archean-Paleoproterozoic development of the Curaçá belt, the I–S–C orogen, and the São Francisco craton.     

Atmospheric wave propagations in the mesopause region observed by the OH(8,3) band,NaD, O2A(8645Å) band and OI 5577 Å nightglow emissions

Simultaneous measurements of the upper mesospheric NaD and OH(8,3) band emissions by meridional scanning photometers, and the OI 5577 Å, O₂ Atmospheric band at 8645 Å, NaD and OH(8,3) band emissions by multi-channel tilting filter type zenith photometers have been carried out at Cachoeira Paulista (22.7°S, 45.0°W), Brazil. On two nights during the period May–August 1983, the meridional scanning observations showed horizontal intensity gradients and phase propagations. The nocturnal intensity variations on one of these occasions 13–14 June 1983, which was a magnetically disturbed night with 4 ?k_p? 8, also showed vertical phase propagation. In this paper, we present these observations and discuss the possible effects of the horizontal wind system and of gravity wave propagation.     

Observations and model calculations of an additional layer in the topside ionosphere above Fortaleza, Brazil

Calculations using the Sheffield University plasmasphere ionosphere model have shown that under certain conditions an additional layer can form in the low latitude topside ionosphere. This layer (the F3 layer) has subsequently been observed in ionograms recorded at Fortaleza in Brazil. It has not been observed in ionograms recorded at the neighbouring station São Luis. Model calculations have shown that the F3 layer is most likely to form in summer at Fortaleza due to a combination of the neutral wind and theE × B drift acting to raise the plasma. At the location of São Luis, almost on the geomagnetic equator, the neutral wind has a smaller vertical component so the F3 layer does not form.     

High efficacy on diclofenac removal by activated carbon produced from potato peel waste

In the present study, a novel porous carbon obtained by K₂CO₃ activation of potato peel waste under optimized conditions was applied for the first time as liquid-phase adsorbent of sodium diclofenac in parallel with a commercial activated carbon. The biomass-activated carbon presented an apparent surface area of 866 m² g^?1 and well-developed microporous structure with a large amount of ultramicropores. The obtained carbon presented leaching and ecotoxicological properties compatible with its safe application to aqueous medium. Kinetic data of laboratory-made and commercial sample were best fitted by the pseudo-second-order model. The commercial carbon presented higher uptake of diclofenac, but the biomass carbon presented the higher adsorption rate which was associated with its higher hydrophilic nature which favoured external mass transfer. Both adsorbents presented adsorption isotherms that were best fitted by Langmuir model. The biomass carbon and the commercial carbon presented adsorption monolayer capacities of 69 and 146 mg g^?1, and Langmuir constants of 0.38 and 1.02 L mg^?1, respectively. The better performance of the commercial sample was related to its slightly higher micropore volume, but the most remarkable effect was the competition of water molecules in the biomass carbon.     

Diurnal and seasonal variations of the oh (8, 3) airglow band and its correlation with OI 5577 Å

In this paper the results of OH (8,3) emission intensity and rotational temperature measurements made in the Brazilian sector (23°S) from 1972 to 1974 are presented. Diurnal variations of both the parameters are found to fall into distinct classes, showing significant seasonal effects. A correlative study with the OI 5577 Å emission measured simultaneously is also presented. It is shown that both the phase and amplitude of the major part of the mean nocturnal intensity variations of the two emissions can be explained by the density and temperature perturbations caused by the solar semidiurnal tide. The OH emission is found to increase slightly during magnetic disturbances.     

Discussion of “Geopolymers Based on Recycled Glass Powder for Soil Stabilization” Jair de Jesús Arrieta Baldovino; Ronaldo dos Santos Izzo; Juliana Lundgren Rose; Mônica Angélica Avanci

Geotechnical and Geological Engineering - Discussers offered comments to enhance results analysis. An alternative evaluation was proposed using the η/Biv index, where the Biv parameter, named...