Remote sensing of Mercury's magnetospheric plasma environment via energetic neutral atoms imaging

The potentiality of exploring the plasma dynamical behavior of Mercury via energetic neutral atom (ENA) analysis is briefly discussed. The analysis of the Hermean ENA would give clues to the global magnetospheric configuration, clarifying crucial issues like the existence of radiation belts. In order to demonstrate the feasibility of ENA imaging in the Hermean environment, an empirical model of the equatorial proton distributions, originally developed for the Earth's magnetosphere, is here modified in order to be applicable to the expected conditions, according to the present knowledge of the planet. Simulations of the ENA radiation are then presented and discussed. It is shown that the simulated radiation is significantly high, especially when pointing the field of view towards the Hermean surface. The way of determining the proton flux distributions and the cross-tail electric field characteristics by using the ENA signal is discussed. Finally, a preliminary design of an ENA detector suitable for the ESA mission to Mercury ‘BepiColombo’ is proposed and discussed.     

Regularized tomographic inversion with geological constraints

Reflection tomography is the industry standard tool for velocity model building, but it is also an ill‐posed inverse problem as its solution is not unique. The usual way to obtain an acceptable result is to regularize tomography by feeding the inversion with some a priori information. The simplest regularization forces the solution to be smooth, implicitly assuming that seismic velocity exhibits some degree of spatial correlation. However, velocity is a rock property; thus, the geometry and structure of rock formations should drive correlation in velocity depth models. This observation calls for constraints driven by geological models. In this work, we present a set of structural constraints that feed reflection tomography with geometrical information. These constraints impose the desired characteristics (flatness, shape, position, etc.) on imaged reflectors but act on the velocity update. Failure to respect the constraints indicates either velocity inaccuracies or wrong assumptions concerning the constraints. Reflection tomography with structural constraints is a flexible framework that can be specialized in order to achieve different goals: among others, to flatten the base of salt bodies or detachment surfaces, to recover the horizontalness of oil–water contacts, or to impose the co‐location of the same imaged horizon between PP and PS images. The straightforward application of structural constraints is that of regularizing tomography through geological information, particularly at the latest stages of the depth imaging workflow, when the depth migration structural setting reached a consistent geological interpretation. Structural constraints are also useful in minimizing the well‐to‐seismic mis‐ties. Moreover, they can be used as a tool to check the consistency of interpreters' hypothesis with seismic data. Indeed, inversion with structural constraints will preserve image focusing only if the interpreters' insights are consistent with the data. Results from synthetic and real data demonstrate the effectiveness of reflection tomography with structural constraints.     

Hypersaline groundwater genesis assessment through a multidisciplinary approach: the case of Pozzo del Sale Spring (southern Italy)

A tool, based on a multidisciplinary field investigation approach for studying the characteristics of a hypersaline spring, was developed and its effectiveness tested on a spring in southern Italy; a preliminary model of the aquifer system at medium and local scale was derived. Hydrologic measurements, vertical electric soundings, and chemical and isotopic (δ¹⁸O, δ²H, ³H) analyses were undertaken, along with microbiological analyses and species identification. These demonstrate the coexistence of hypersaline and fresh water, generating a significant diversification of the groundwater hydrochemical signature. The isotopic signature shows that both types of water have a meteoric origin. Microbial contamination of fecal origin indicates the mixing of hyper- and low- saline water related to local infiltration. The hypersaline groundwater flows in confined horizons within a sequence that is mainly of fractured clays. These horizons are probably concentrated where well-developed fracture network and dissolution openings within evaporitic rocks enhance fluid flow. In a wider context, this study determines that microbiological pollution of saline groundwater may not be detected if using nonhalophilic bacterial indicators such as fecal coliforms. Fecal enterococci are better indicators, due to their higher halotolerance.     

Laboratory determination of mechanical and hydraulic properties of chemically grouted sands

The purpose of this paper is to investigate mechanical and hydraulic properties of sands treated with mineral-based grouts through the results of a laboratory test programme consisting of unconfined compression tests (UCS), triaxial bender element tests (BeT) and constant flow permeability tests in triaxial apparatus. An improved apparatus was set up for obtaining high quality, multiple grouted specimens from a single column. Two selected natural sands having different grain sizes were grouted with two mineral-based silica grouts, resulting in different levels of improvement. The behaviour of the sands treated by mineral grouts, in terms of strength, initial stiffness and permeability, was compared with that exhibited by more traditional silicate grouts. The results of this study indicate that sands treated with mineral grouts result in higher strengths, higher initial shear modulus and lower permeability values than the sands treated with the silicate solution. The effect of grout type, effective confining pressure, and sand particle-size on small-strain shear modulus of grouted sand specimens was evaluated. Based on test results, the small strain shear modulus increment from treated to untreated specimens has been correlated with the unconfined compressive strength, obtaining a unique relationship regardless of grout type and grain-size of tested sands.     

Multiproxy record for the last 4500 years from Lake Shkodra (Albania/Montenegro)

A multi‐proxy record is presented for approximately the last 4500 cal a BP from Lake Shkodra, Albania/Montenegro. Lithological analyses, C/N ratio and δ¹³C of the organic and inorganic carbon component suggest that organic matter and bulk carbonate are predominantly authigenic. The δ¹⁸O record of bulk carbonate indicates the presence of two prominent wet periods: one at ca. 4300 cal a BP and one at ca. 2500–2000 cal a BP. The latter phase is also found in southern Spain and Central Italy, and represents a prominent event in the western and central Mediterranean. In the last 2000 years, four relatively wet intervals occurred between ca. 1800 and 1500 cal a BP (150–450 AD), 1350–1250 (600–700 AD), 1100–800 (850–1150 AD), and at ca. 90 cal a BP (1860 AD). Between ca. 4100 and 2500 cal a BP δ¹⁸O values are relatively high, with three prominent peaks indicating drier conditions at ca. 4100–4000 cal a BP, ca. 3500 and at ca. 3300 cal a BP. Four additional drier events are identified at 1850 (ca. 100 AD), 1400 (ca. 550 AD), 1150 (800 AD) and ca.750 cal a BP (1200 AD). The pollen record does not show changes in accordance with these episodes owing to the poor sensitivity of vegetation in this area, which is dominated by an orographic rainfall effect and where changes in altitudinal vegetation belts do not affect the pollen rain in the lake catchment. However, since ca. 900 cal a BP a significant decrease in the percentage arboreal pollen and in pollen concentrations suggest major deforestation produced by human activities. Copyright © 2012 John Wiley & Sons, Ltd.     

Application of the exact constitutive relationship of modified Cam clay to the undrained expansion of a spherical cavity

The modified Cam clay (MCC) model is used to study the response of virgin‐compressed clay subjected to undrained triaxial compression. The MCC constitutive relationship is obtained in a closed form. Both elastic and plastic deviatoric strains are considered in the analysis. The solution allows to obtain total and effective stress paths followed by the clay in undrained spherical expansion. Pore water pressures are determined from the difference between total and effective mean stresses. For illustration purposes, the analysis is also applied to the well‐known reconstituted normally consolidated London clay and the results are compared with the recently published data obtained by a numerical approach. In addition, the Almansi large strains are used in the analysis, as these allow to obtain limit expansion and pore pressures, whereas both small‐strain and logarithmic‐strain approaches do not permit to determine them. Copyright © 2010 John Wiley & Sons, Ltd.     

Subsidence due to crack closure and depressurization of hydrothermal systems: a case study from Mt Epomeo (Ischia Island,Italy)

Levelling surveys carried out between 1990 and 2003 on the Mt Epomeo resurgent block (Ischia Island) record negative dislocations on its northern and southern flanks with a maximum subsidence rate of 1.27 cm yr⁻¹. This deformation is not associated with the cooling, crystallization or lateral drainage of magma and cannot be explained by a pressure point or prolate ellipsoid source. Results from dislocation models and the available structural and geochemical information indicate that the subsidence is due to crack closure processes along two main ENE–WSW and E–W preexisting faults, which represent the preferred pathway of CO₂ degassing from the hydrothermal system located beneath Mt Epomeo. The monitoring of the dislocations and CO₂ flux along these faults could give useful information on the dynamics of the hydrothermal system.     

The transition between ‘orogenic’ and ‘anorogenic’ magmatism in the western Mediterranean area: the Middle Miocene volcanic rocks of Isola del Toro (SW Sardinia,Italy)

The Isola del Toro is a small island (∼1 km²) about 5 nautical miles SW of Sardinia entirely made up of mildly alkaline sodic evolved rocks (benmoreites and trachytes) related to each other by fractionation processes. ⁴⁰Ar/³⁹Ar dating of an anorthoclase mineral separate from a trachyte gave an age of 11.83 ± 0.10 Ma. This age estimate falls within an interval previously considered a‐magmatic in Sardinia. The results of this study shift the beginning of the Middle Miocene–Quaternary anorogenic volcanism of Sardinia back to the Late Serravalian. The transition between orogenic and anorogenic activity in Sardinia is markedly different from that recorded in the rest of the circum‐Mediterranean area, where this transition is much more gradual, both in time and in terms of magma composition. On the other hand, the transition between orogenic and anorogenic magmatism in Sardinia is rather sharp and lacks hybrid compositions. The Isola del Toro volcanic rocks represent the first anorogenic products produced during the opening of the western Mediterranean Sea.     

Implicit integration of a mixed isotropic–kinematic hardening plasticity model for structured clays

In recent years, a number of constitutive models have been proposed to describe mathematically the mechanical response of natural clays. Some of these models are characterized by complex formulations, often leading to non‐trivial problems in their numerical integration in finite elements codes. The paper describes a fully implicit stress‐point algorithm for the numerical integration of a single‐surface mixed isotropic–kinematic hardening plasticity model for structured clays. The formulation of the model stems from a compromise between its capability of reproducing the larger number of features characterizing the behaviour of structured clays and the possibility of developing a robust integration algorithm for its implementation in a finite elements code. The model is characterized by an ellipsoid‐shaped yield function, inside which a stress‐dependent reversible stiffness is accounted for by a non‐linear hyperelastic formulation. The isotropic part of the hardening law extends the standard Cam‐Clay one to include plastic strain‐driven softening due to bond degradation, while the kinematic hardening part controls the evolution of the position of the yield surface in the stress space. The proposed algorithm allows the consistent linearization of the constitutive equations guaranteeing the quadratic rate of asymptotic convergence in the global‐level Newton–Raphson iterative procedure. The accuracy and the convergence properties of the proposed algorithm are evaluated with reference to the numerical simulations of single element tests and the analysis of a typical geotechnical boundary value problem. Copyright © 2007 John Wiley & Sons, Ltd.