Intersector element partitioning in tourmaline: a potentially powerful single crystal thermometer

Hourglass sector zoning, and related polar overgrowths, are common features of metamorphic tourmaline, developing as a result of variations in element preference on the different growth surfaces. For sector-zoned crystals, three domains are present for each growth zone (c ⁺, c ⁻ and a), with compositional differences most distinct for Ca and Ti, and among c ⁺ and c ⁻ sectors. Intersector differences vary, commonly showing decreasing fractionation from core to rim attributed to increasing metamorphic grade. Here we show that intersector element partitioning is temperature dependent and derive empirical geothermometers based on c ⁺ –c ⁻ and c ⁺ –a partitioning of Ca and Ti. These thermometers are applicable over a range of temperatures and bulk-rock compositions. Intersector partitioning is not affected by re-equilibration and records and preserves complete T-histories of individual tourmaline grains from prograde to peak and on to retrograde growth. Information on element mobility is preserved by tourmaline composition, because intersector partitioning is independent of element concentration. These factors make intersector partitioning an ideal tool to elucidate the thermal history of tourmaline grains and thus their host environment and tourmaline’s refractory nature preserves these signatures even into the sedimentary record. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

Dynamics and contribution of karst groundwater to surface flow during Mediterranean flood

This paper describes the role of groundwater contribution to surface flow at the Causse d’Aumelas, a karst system near Montpellier (France), which is traversed by an intermittent river, the Coulazou. A first hydrologic model integrating a digital terrain model shows the inability of a standard rainfall-runoff model to replicate recorded flood hydrographs. While the flood peaks are routed through the karstic system along the Coulazou without a phase lag, the peak magnitude is somewhat modified. These results indicate an initial karst system recharge followed by a significant contribution to surface flow. A hydrodynamic analysis of ground-water flow confirms these results: the karst system first absorbs part of the rainfall, which induces a general water table rise within the aquifer, and then contributes to surface flow in the Coulazou.     

平面P波在饱和半空间中洞室周围的散射(II):数值结果

本文通过数值计算研究了入射平面P波在饱和半空间中洞室周围散射问题,分析了入射波频率和角度、边界渗透条件、孔隙率、泊松比等参数对散射的影响。研究表明,平面P波入射情况下,饱和半空间和单相(干土)半空间中洞室附近地表位移幅值的差别很大,干土情况的水平位移幅值相对较大,饱和情况的竖向地表位移幅值相对较大;由于波在洞室附近的干涉,饱和情况与干土情况的地表位移出现相位漂移。随着孔隙率的增大,洞室附近水平地表位移幅值逐渐减小,竖向地表位移幅值则逐渐增大;当孔隙率较低时,边界渗透条件对地表位移幅值的影响很小,而当孔隙率较大时,边界渗透条件的影响则不可忽视,不透水情况下,水平和竖向地表位移幅值的峰值均相对较大;随着入射频率的增加,孔隙率的影响逐渐增大,而且不透水情况下孔隙率的影响相对较大。随着泊松比的增大,洞室附近水平地表位移幅值逐渐降低,竖向地表位移幅值则逐渐增大;泊松比较小时,边界渗透条件对位移幅值的影响较大,泊松比较大时,边界渗透条件对位移幅值的影响则较小;随着入射频率的增加,泊松比的影响逐渐增大。当孔隙率较小时,半空间地表和洞室表面孔隙水压幅值较小,但空间变化比较剧烈,随着孔隙率的增大,孔隙水压逐渐增大但空间变化逐渐平缓;随着入射频率的增加,孔隙水压幅值逐渐增大,且孔隙水压的空间变化逐渐变得复杂。     

High-resolution atmospheric forcing for regional oceanic model: the Iroise Sea

This study was aimed at modeling, as realistically as possible, the dynamics and thermodynamics of the Iroise Sea by using the Model for Applications at Regional Scale (MARS), a regional ocean 3D model. The horizontal resolution of the configuration in use is 2 km with 30 vertical levels. The 3D model of the Iroise Sea is embedded in a larger model providing open boundary conditions. As regards the atmospheric forcing, the originality of this study is to force the regional ocean model with the high-resolution (6 km) regional meteorological model, Weather Research and Forecasting (WRF). In addition, as the air surface temperature is highly sensitive to the sea surface temperature (SST), this regional meteorological model is improved by taking into account a regional climatologic SST to compute meteorological parameters. By allowing a better coherence between the SST and the temperature of the atmospheric boundary layer while giving a more realistic representation of heat fluxes exchanged at the air/sea interface, this forcing constitutes a noticeable improvement of the Iroise Sea modeling. The different sensitivity tests discussed here pinpoint the importance of entering, in WRF, SST data of sufficiently high quality before the computation of meteorological forcing when the aim is a study of dynamics and thermodynamics far away from the coast. On the other hand, when the target is the reproduction of coastal small-scale features in Iroise Sea modeling, the resolution of the meteorological forcing and the quality of SST are both paramount. The simulation of reference was carried out throughout the Summer and Autumn of year 2005 to allow comparisons with a campaign of surface current measurements by high-frequency radars conducted at the same period.     

Annotated translation of “Nota in verband met de voorgenomen putboring nabij Amsterdam [Note concerning the intended well drilling near Amsterdam]” by J. Drabbe and W. Badon Ghijben (1889)

The famous report by engineers Drabbe and Badon Ghijben (1889), on an intended well drilling near Amsterdam (the Netherlands), was one of the key documents that contributed to the Ghijben-Herzberg formula, which links water-table elevation to the depth of the freshwater–saltwater interface in coastal aquifers. The report has been often cited but no English translation has appeared in the literature to date. The aim of this annotated translation of the report is to provide the international scientific community with easier access than was hitherto the case, plus electronic access to the original in Dutch. A brief introduction to the report is provided, followed by a translation that follows the original text as closely as possible.     

A parsimonious approach for large-scale tracer test interpretation

Hydrogeology Journal - Dye tracing is an efficient method for spring watershed delineation, but is also used in surface waters to assess pollution migration over several kilometers. The aim of this...     

Enhanced pumping test using physicochemical tracers to determine surface-water/groundwater interactions in an alluvial island aquifer,river Rhône,France

Groundwater extracted from the Barthelasse Island aquifer, surrounded by the river Rhône (southeastern France), contributes to the drinking water supplies of 180,000 inhabitants. Owing to its location close to the river and the presence of two backwaters (oxbow lakes), the pumped groundwater is highly vulnerable to river pollution. A pumping test was conducted over 24 h to analyse and quantify the water exchange processes between the river, backwaters and groundwater. During the pumping test, isotopic (δ¹⁸O, δ²H and ²²²Rn), hydrochemical and hydrophysical monitoring of the groundwater was undertaken. Hydraulic heads were measured in pumping wells and at a piezometer located between the wells. Discrete water samples were collected at several observation points in the field, including the backwater and river. The results show mixing between three end-members, as defined by the deuterium excess and silica concentration, led by river Rhône water which had been affected by water–rock interactions over time and mixing with surface evaporated waters. The pumped water resulted from mixing between three end-members, all of which depended on the river Rhône but differed in terms of residence time in the system. Although the groundwater pumping wells are close to each other (<70 m) and have similar depths, the changes in the contributions from end-member waters at each well were different during the pumping test. Comparing isotopic tracers and geochemistry made it possible to quantify the different hydrological compartments that contribute to the groundwater pumped from the boreholes, which is critical in constructing a conceptual flow model.

     

平面P1波斜入射下海底洞室地震响应解析分析

基于无黏性可压缩理想流体介质波动理论和Biot流体饱和多孔介质波动理论,考虑水下饱和土的流固耦合,借助Hankel函数积分变换法(HFITM)给出入射平面P1波在海底洞室周围散射问题的解析解。相比传统研究中的"大圆弧假定",Hankel函数积分变换法可以较好地处理半空间表面边界条件。利用该解析解,计算分析了洞室表面透水条件、入射角度、入射频率、海水水深和饱和土的孔隙率等因素对水-土交界面处水平位移、竖向位移和洞室表面动水压力、环周总应力的影响。结果表明:洞室表面透水条件对水-土交界面处水平位移和竖向位移影响较小;随着斜入射角的增加,水-土交界面处竖向位移减小;随着入射频率的增加,水-土交界面处水平位移随之增加;海水水深为2.5倍SV波的波长时,水-土交界面处水平位移及洞室表面动水压力最大值最大;随着孔隙率的增加,水-土交界面处水平位移、竖向位移和洞室表面环周总应力减小,而洞室表面动水压力随之增加。     

Distribution of tritium-helium groundwater ages in a large Cenozoic sedimentary basin (North German Plain)

The travel time of groundwater plays a major role in the understanding of hydrogeological systems; however, large data sets necessary for regional studies of groundwater age are rare. In this study, a unique large data set of groundwater samples analysed for tritium and helium isotopes collected over the last 20 years from Cenozoic aquifers of the North German Plain is explored. Hereby, the variety of natural and technical influences on the tritium-helium age, including screen depth and length, groundwater recharge rate and climatic effects, are investigated. To a sampling depth of ~40 m below ground level, the median tritium-helium age increases almost linearly with depth, reaching a maximum of 40 years. Below, the portion of older, tritium-free water rises. The tritium-helium ages of the tritium-bearing portion increase only slightly to a maximum of about 46 years. The depth distribution of the tritium-helium age shows a dependency on groundwater recharge rates. Considering the same depth level, younger ages are related to higher groundwater recharge rates as compared to groundwater that infiltrated in areas with lower recharge rates. This is especially observed for shallow depths. Tritium-helium ages younger than 40 years are reflected well in the atmospheric tritium input curves, while deviations from it can be related to anthropogenic influences such as input from nuclear power plants and irrigation with deep, tritium-poor groundwater. The regional distribution for shallow wells indicates increasing tritium-helium ages from west to east, corresponding to decreasing groundwater recharge rates due to the more continental climate in the east.