The behavior of fly-ash derived arsenic in seawater

With the rising cost of oil the electric power generating companies are turning to coal as a fuel source. Large amounts of fly ash are produced as a by product of coal combustion. This fly ash must then be disposed of, with the oceans being considered an alternative to land fill disposal. This research investigated the sorptive behavior of the surface-associated arsenic and utilized the results to project arsenic's impact on the water column during the ocean disposal of fly ash.Several acid digests were investigated to determine an effective method of arsenic recovery from fly ash. Of these, the HCl digest was the most effective technique, yielding 100% arsenic recoveries from fly-ash particles. The arsenic content of the fly ashes studied varied from 69 ± 11 μg g⁻¹ to 323 ± 24 μg g⁻¹, reflecting differences in the arsenic content of the source coal. In both seawater and freshwater there is an increase in arsenic desorption with increasing pH. The greatest release of arsenic occurred at pH 12 with generally over 80% of the surface arsenic released.Fly ash in contact with seawater and freshwater can exhibit either acidic or alkaline tendencies depending upon the soluble elemental composition on the surface of the flyash particle. The acidic ashes were shown to leach a greater percentage of arsenic (16.9%) than the more alkaline ashes (8.2%). During these leaching studies in seawater, arsenic was found to leach in both the pentavalent and trivalent oxidation state. The pentavalent state was predominant, comprising 77% of the arsenic initially desorbed.The dissolution in seawater of arsenic was utilized to assess the possible impact of the ocean disposal of fly ash. Based upon these data it appears that the natural levels of arsenic in the water column would not be significantly increased. Further research is needed on the fate of fly-ash particles in marine sediments.     

Size and composition of inorganic colloids in a peri-alpine, glacial flour-rich lake

From June 2004 to October 2005, particle size distributions (PSD) and the mineralogy of inorganic colloids in Lake Brienz, a glacial flour-rich Swiss lake, and in its tributaries (the Aare and Lütschine rivers), were quantified by single particle counting based on light scattering (0.1-2 μm) combined with transmission electronic microscopy coupled with energy dispersive spectroscopy and selected area electron diffraction. The two lake tributaries differ in terms of the geology of their catchment area and in their hydrology: the River Lütschine’s glacial regime is unperturbed, while the River Aare has been significantly modified by hydroelectric installations. The dependence of the colloid concentration numbers on colloid diameters can be described by a power-law distribution in all cases. The power-law slopes in the River Aare were consistently smaller, and the total colloid number concentrations consistently higher, (mean values: −3.89 and 6.2 × 10⁸ mL⁻¹, respectively) than in the River Lütschine (−3.61 and 1.7 × 10⁸ mL⁻¹). The measured PSD in the lake were dependent on season and depth: homogenous in the whole epilimnion in winter and modified by river intrusions in summer. In this season, the presence of a river turbid plume above the thermocline is a significant source of colloids in the epilimnion, where their concentration was high (mean value: 5.1 × 10⁷ mL⁻¹). The same main mineral types were found in the different systems: 2:1 minerals, feldspars, chlorite and quartz; with a few particles of oxides. Differences in their relative concentrations in the rivers, essentially reflecting the geological differences of the respective catchment areas, made it possible to trace the origin of the mineral colloids present in lake surface waters throughout the year. The relationship between colloid size and mineralogy was assessed, showing that different minerals have distinct size distributions. In the rivers, where almost no aggregates were observed, PSD would essentially be the result of the nature (particle formation and mineralogy) of the colloids, whereas in the lake, aggregation and sedimentation processes would also play a role, particularly in summer.     

Origin of groundwater salinity and hydrogeochemical processes in a confined coastal aquifer: Case of the Rhône delta (Southern France)

The Rhône delta, South of France (Camargue, 750 km²) is a coastal saline wetland located along the Mediterranean Sea. The confined aquifer of this delta shows high values of electrical conductivity rising from the north (4 mS/cm) to the shoreline (58 mS/cm). This work aims to identify the origin of groundwater salinity and the geochemical processes occurring in this coastal confined aquifer according to the degree of salinity. A natural tracing approach is considered using monthly sampling in 8 piezometers for chemical and isotopic analyses (¹⁸O, ²H, ¹³C_TDIC). Ionic and isotopic ratios demonstrate that strong salinities are due to a simple mixing between Mediterranean seawater and freshwater; seawater contribution reaches up to 98% at 8 km from the shoreline. Seawater intrusion induces a particular groundwater chemistry which varies with the degree of seawater contribution: (1) In the less saline part of the aquifer (seawater contribution <20%), the intrusion induces an increase of Na⁺ in groundwater leading to Ca²⁺/Na⁺ exchange processes. The δ¹³C_TDIC analyses show that matrix exchange processes most likely occur for the less saline samples. (2) In the saline part of the aquifer (seawater contribution >20%), the intrusion induces SO₄ reduction which is confirmed by highly depleted δ¹³C_TDIC values (up to −19‰). The δ¹³C_TDIC also reveals that methanogenesis processes may occur in the most reductive part of the aquifer. Due to SO₄ reduction, the intrusion induces a shift in carbonate equilibrium leading to supersaturation with respect to dolomite and/or magnesian calcite. Thus carbonate precipitation may occur in the area strongly influenced by seawater.     

High‐frequency precipitation and stream water quality time series from Plynlimon,Wales: an openly accessible data resource spanning the periodic table

This scientific briefing announces the availability of a new multi‐element high‐frequency water quality data set that is openly accessible to the research community. The data set comprises up to 2 years of 7‐hourly water quality data for two streams and one rainfall site in the Upper Severn catchment at Plynlimon in Mid‐Wales. The measurements cover 50 analytes ranging from H⁺ to U and spanning six orders of magnitude in concentration, including major, minor and trace elements as well as nutrients, and they complement decades of weekly measurements of the same analytes at the Upper Severn. Together, the weekly and 7‐hourly time series provide a unique data set for studying both long‐term trends and short‐term dynamics. The data show complex behaviour over a wide range of timescales, challenging our understanding of catchment processes and informing future modelling efforts. Copyright © 2013 John Wiley & Sons, Ltd.     

Integration of airborne thematic mapper simulator (TMS) data and digitized aerial photography via an ISH transformation

Abstract

In water sampling it is very common to use human experience to determine sampling locations. We present results from a neural network analysis of multispectral imaging data from the Compact Airborne Spectrographic Imager (casi) to determine significant water sampling locations. In this study Lake Tegel in Berlin, Germany, was overflown on different days. The analysis of the remote sensing data results in a clustering of the overflown water body for each pass. The neural network clusters found for each pass have been related to each other. This procedure enables us to optimize the number and location of water sampling stations.     

From discrete to continuum modelling of boundary value problems in geomechanics: An integrated FEM-DEM approach

Double-scale numerical methods constitute an effective tool for simultaneously representing the complex nature of geomaterials and treating real-scale engineering problems such as a tunnel excavation or a pressuremetre at a reasonable numerical cost. This paper presents an approach coupling discrete elements (DEM) at the microscale with finite elements (FEM) at the macroscale. In this approach, a DEM-based numerical constitutive law is embedded into a standard FEM formulation. In this regard, an exhaustive discussion is presented on how a 2D/3D granular assembly can be used to generate, step by step along the overall computation process, a consistent Numerically Homogenised Law. The paper also focuses on some recent developments including a comprehensive discussion of the efficiency of Newton-like operators, the introduction of a regularisation technique at the macroscale by means of a second gradient framework, and the development of parallelisation techniques to alleviate the computational cost of the proposed approach. Some real-scale problems taking into account the material spatial variability are illustrated, proving the numerical efficiency of the proposed approach and the benefit of a particle-based strategy.     

Ten‐year water table recovery after clearcutting and draining boreal forested wetlands of eastern Canada

In boreal forested wetlands, the observed increase in the water table level after clearcutting (watering‐up) is often a threat to sustained ecosystem productivity. Hydrologic recovery refers to the processes by which a water table progressively drops back to its initial level after the cut. In eastern Canada, drainage is used operationally after clearcutting wet sites in order to lower the water table level and accelerate hydrologic recovery. The objective of this study was to evaluate the duration of the watering‐up caused by timber harvesting and the extent to which drainage affected the water table recovery on five peatlands and three hydromorphic mineral sites located in the St. Lawrence Lowlands of Québec (Canada). The mixed wood stands studied are dominated by balsam fir (Abies balsamea (L.) Mill.), eastern white cedar (Thuja occidentalis L.), and red maple (Acer rubrum L). Results indicate that, 10 years after clearcutting, water table levels in undrained plots are still 5 to 7 cm higher than the pre‐cut levels. The slight recovery in water table level plateaued after the third year. Rainfall interception by vegetation was also monitored, and after 10 years had reached nearly 50% of the pre‐cut rate. The immediate water table drawdown following drainage mitigated watering‐up within 40 m of a ditch. The persistent watering‐up observed in this study should encourage using sylvicultural systems adapted to boreal forested wetlands in order to prevent productivity loss and stand conversion. Copyright © 2008 John Wiley & Sons, Ltd.