Chlorine isotopic composition in seafloor serpentinites and high-pressure metaperidotites. Insights into oceanic serpentinization and subduction processes

Bulk-rock chlorine content and isotopic composition (δ³⁷Cl) were determined in oceanic serpentinites, high-pressure metaperidotites and metasediments in order to gain constraints on the global chlorine cycle associated with hydrothermal alteration and subduction of oceanic lithosphere. The distribution of insoluble chlorine in oceanic serpentinites was also investigated by electron microprobe. The hydrothermally-altered ultramafic samples were dredged along the South West Indian Ridge and the Mid-Atlantic Ridge. The high-pressure metamorphic samples were collected in the Western Alps: metaperidotites in the Erro-Tobbio unit and metasediments in the Schistes Lustrés nappe.Oceanic serpentinites show relatively large variations of bulk-rock Cl contents and δ³⁷Cl values with mean values of 1105 ± 596 ppm and −0.7 ± 0.4‰, respectively (n = 8; 1σ). Serpentines formed after olivine (meshes) show lower Cl content than those formed after orthopyroxene (bastites). In bastites of two different samples, Cl is positively correlated with Al₂O₃ and negatively correlated with SiO₂. These relationships are interpreted as reflecting preferential Cl-incorporation into the bastite structure distorted by Al (substituted for Si) rather than different alteration conditions between olivine and orthopyroxene minerals. High-pressure metaperidotites display relatively homogeneous Cl contents and δ³⁷Cl values with mean values of 467 ± 88 ppm and −1.4 ± 0.1‰, respectively (n = 7; 1σ). A macroscopic high-pressure olivine-bearing vein, formed from partial devolatilization of serpentinites at ∼2.5 GPa and 500-600 °C, shows a Cl content and a δ³⁷Cl value of 603 ppm and −1.6‰, respectively. Metasediments (n = 2) show low whole-rock Cl contents (<15 ppm Cl) that did not allow Cl isotope analyses to be obtained.The range of negative δ³⁷Cl values observed in oceanic serpentinites is likely to result from water-rock interaction with fluids that have negative δ³⁷Cl values. The homogeneity of δ³⁷Cl values from the high-pressure olivine-bearing vein and the metaperidotite samples implies that progressive loss of Cl inherited from oceanic alteration throughout subduction did not significantly fractionate Cl isotopes. Chlorine recycled in subduction zones via metaperidotites should thus show a range of δ³⁷Cl values similar to the range found in oceanic serpentinized peridotites.     

Mediterranean flash flood transfer through karstic area

Karstic aquifers influence flash floods propagation in Mediterranean countries. Near Montpellier, Southern France, discharge data are recorded on the Coulazou River upstream and downstream of the Aumelas Causse. Two gauging stations are used to describe the hydrodynamics of this binary karstic system. The first station characterizes the non-karstic catchment area. The second one is representative of the karstic part of the watershed. Records since April 2004 are used to understand how the river interacts with a karstic aquifer. Hydrograph analysis of three flash flood events is described. Corresponding discharge time series recorded at the two gauging stations are used to describe the modification of the hydrographs by auto- and crosscorrelations analyses. Finally, linear system analyses are used to provide the transfer functions of this binary karstic system according to the three flood events characteristics (initial conditions, volume, spatial distribution of rainfall, etc.). Theses functions summarize the hydrodynamic behaviour of the system: their shapes are indicative of the dynamics of the storage, the release and the contribution to surface waters.

Turbulence,billows and gravity waves in a high shear region of the upper atmosphere

Measurements on a downleg trail of lithium in morning twilight show definite turbulent features and also a wave structure at 107 km which could be generated by the intense wind shear.     

Emplacement of a Debris Avalanche during the 1883 eruption of Krakatau (Sunda Straits,Indonesia)

Conclusion The data collected during the Mentawai cruise help to clarify understanding of the 1883 eruption of Krakatau. We have previously discussed the weaknesses of the interpretation of Williams (1941) and others (Self and Rampino 1981) and emphasized that only a Mount St. Helens-type collapse during the course of the eruption could account for all the characteristics of the eruption and of the related deposits.The discovery on land of deposits attributable to a debris-avalanche, in the stratigraphic position where they were expected, is a strong argument for the validity of our scenario.Marine surveys confirm that the sea bottom around Krakatau is covered by a thick ignimbritic deposit. But the presence of this deposit does not invalidate the presence of a debris-avalanche deposit under the ignimbrites. The hummocky morphology favours this hypothesis.Flank-failure of volcanoes is generally considered as a very efficient mechanism for triggering tsunamis (Kienle et al. 1987; Siebert et al. 1987). However, the majority of the volcanoes where flank-failure has been described are tall and bulky and the collapse of a broad edifice like Krakatau may be surprising. However the geological evidence shows that such a mechanism can act at various scales; for example the flank collapse of Mayu Yama volcano (height 700 m, volume 0,3 km³), a parasitic cone of Unzen volcano (Japan), triggered a debris-avalanche into the sea that was 1 km long, with a characteristic hummocky surface; the resulting tsunami killed 9528 people (Katayama 1974). In the same way, a partial collapse of Iliwerung volcano, Indonesia (50 × 10⁶ m³) in July 1979, triggered a tsunami which killed several hundred people (McClelland et al. 1989). At Krakatau, the main summit was 822 m asl; the collapse took place along the edge of the prehistoric caldera and this structural unconformity probably facilitated the triggering of the process.     

Dating in the Craven Dales

The Craven Dales of North Yorkshire contain some of the finest examples of limestone geology and landscape in the UK. The extensive limestone pavements with their clints, grikes and other water‐worn features, are a key attraction for both scientists and recreational visitors. Likewise the cave systems attract attention with their remarkable sediment accumulations, some of which are in excess of 500 000 years old and others contain the bones of mammals that are either extinct or no longer present in the British Isles. The glacial erratic boulders at Norber and the loessic sediments that, in places, mask the limestone have also provided stimulus for investigation. Summarized below are the findings of several recent studies that focussed on establishing the age of various features. Whilst the reports answer some long‐standing questions, they also demonstrate that there is still much that can be learned about this seemingly familiar territory.     

Carbon and suspended sediment transport in an impounded alpine river (Isère,France)

Carbon and total suspended sediment (TSS) loads were investigated from April 2006 to March 2008 in the mountainous watershed of the Isère River, French Alps (5570 km²). The river bed has been highly impounded for hydroelectricity production during the last century. Hydraulic flushes are managed every year to prevent TSS storage within upstream dams. The Isère River has been instrumented for high‐frequency monitoring of water, TSS by turbidity and carbon (organic, inorganic, dissolved and particulate) in order to evaluate the impact of natural floods and hydraulic flushes on annual loads. Annual TSS load which was estimated between 1.3 and 2.3 MT y^?1 (i.e. 233 to 413 T km^?2 y^?1) highlighted the high erodibility of the Isère watershed. Annual carbon load was estimated between 173 10³ T y^?1 and 199 10³ T y^?1 (i.e 31 to 36 T km^?2 y^?1). About 80% of the annual carbon loads were inorganic. The impact of hydraulic flushes on annual loads appeared limited (less than 3% for annual TSS load and about 1.5% for annual carbon load), whereas the most important natural flood event contributed to 20% of the annual TSS load and 10% of the annual carbon load. Copyright © 2012 John Wiley & Sons, Ltd.     

Palaeoenvironments of early hominins in temperate and Mediterranean Eurasia: new palaeobotanical data from Palaeolithic key-sites and synchronous natural sequences

The present study focuses on new palaeobotanical data (pollen, phytoliths and fruits) from three of the oldest Early Palaeolithic sites in Eurasia (Dmanisi in Georgia, Ca’ Belvedere di Monte Poggiolo in Italy and Pont-de-Lavaud in France). The main aim is to examine the ecological factors associated with the first human dispersals out of Africa into Eurasia. The palaeoecological data are discussed with regards to chronology and geographical location of the settlements. The vegetation pattern of each site consists of temperate Eurasian and Mediterranean taxa, subtropical trees being more or less recorded depending on climatic and geographic features. The new palaeobotanical data show that different vegetation structures occurred between the first human dispersal in Caucasus and the later dispersals in western Eurasia. However, in all cases hominins seemed to be adapted to temperate ecosystems. In Caucasus, human occupation took place at 1.7 Ma in a forest-steppe environment, while at ca 1 Ma human populations occupied various settings such as open landscapes or dense forests. These data suggest that during the Early Pleistocene, human populations evolved and dispersed in western Eurasia, gradually increasing their degree of adaptation to diversified environments.